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Free-standing,curled and partially reduced graphene oxide network as sulfur host for high-performance lithium–sulfur batteries

引用

Chinese Physics B 2018年第6期27卷 461-467页

作者： Hui-Liang Chen Zhuo-Jian Xiao Nan Zhang Shi-Qi Xiao Xiao-Gang Xia Wei Xi Yan-Chun Wang Wei-Ya Zhou Si-Shen Xie Beijing National Laboratory for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences Beijing 100190 China Beijing Key Laboratory for Advanced Functional Materials and Structure Research Beijing 100190 China School of Physical Sciences University of Chinese Academy of Sciences Beijing 100049 China

Lithium–sulfur（Li–S） batteries have received more and more attention because of higher specific capacity and energy density of sulfur than current lithium–ion batteries. However, the low electrical conductivity of sulfur and its discharge product, and also the high dissolution of polysulfides restrict the Li–S battery practical applications. To improve their performances, in this work, we fabricate a novel free-standing, curled and partially reduced graphene oxide（CPrGO for short） network and combine it with sulfur to form a CPrGO–S composite as a cathode for Li–S battery. With sulfur content of 60 wt%, the free-standing CPrGO–S composite network delievers an initial capacity of 988.9 m Ah·g^（-1）. After 200 cycles,it shows a stable capacity of 841.4 m Ah·g^（-1） at 0.2 C, retaining about 85% of the initial value. The high electrochemical performance demonstrates that the CPrGO–S network has great potential applications in energy storage system. Such improved properties can be ascribed to the unique free-standing and continous CPrGO–S network which has high specific surface area and good electrical conductivity. In addition, oxygen-containing groups on the partially reduced graphene oxide are beneficial to preventing the polysulfides from dissolving into electrolyte and can mitigate the ＂shuttle effect＂.

关键词： lithium-sulfur batteries sulfur cathode curled reduced graphene oxide

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