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Rare Metals 2022年第6期41卷 2055-2062页

作者： Jing-Jing Chen Shuai Gu Rui Hao Zhen-Yu Wang Mu-Qing Li Zhi-Qiang Li Kun Liu Ke-Meng Liao Zhi-Qiang Wang He Huang Ying-Zhi Li Kai-Li Zhang Zhou-Guang Lu Department of Materials Science and Engineering Guangdong Provincial Key Laboratory of Energy Materials for Electric PowerShenzhen Key Laboratory of Interfacial Science and Engineering of MaterialsSouthern University of Science and TechnologyShenzhen 518055China Department of Mechanical Engineering City University of Hong KongHong Kong 999077China

Diminishing the size of active sites in catalysts is promis-ing to improve the kinetics of oxygen reduction reaction(ORR)and reduce the cost of metal-air batteries.However,the facile preparation of high-performance catalysts with nanoscale active sites still suffers from great challenge.Herein,we report a facile template-free strategy to fabri-cate Co single atoms and nanoparticles dispersed on porous N-doped carbon nanotube(Co-NCNT)by the pyrolysis of the composites of metal-organic complexes and porous carbon nanotube.Different from the conventional strategy,the precursor metal-organic complexes in this work were prepared under mild conditions and used without complex purification procedures.Compared with the pristine carbon nanotube,N-doped carbon nanotube with abundant meso-pores contribute to the formation of nanoscale Co sites.

关键词： nanoparticles composites carbon

Impact of Accelerated Ultraviolet Weathering on Polymeric Composite Insulators Under High Voltage DC Stress

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CSEE Journal of Power and Energy Systems 2022年第3期8卷 922-932页

作者： Israr Ullah Muhammad Amin Haider Hussain M.Tariq Nazir Faculty of Electrical Engineering Ghulam Ishaq Khan Institute of Engineering Sciences and TechnologyTopiSwabiKPK23460Pakistan School of Mechanical and Manufacturing Engineering University of New South Wales SydneyNSW 2052Australia School of Electrical Engineering and Telecommunications University of New South Wales SydneyNSW 2052Australia

This study investigates the weatherability of room temperature vulcanized(RTV)silicone rubber(SiR)and epoxybased material specimens with a composition of different nano and micro fillers against the collegial effects of high voltage DC,UV and temperature stresses.Bulk power transmission over long distances via HVDC is considered an economic option these days,so to ensure the system reliability,it is also critical to investigate these insulators under DC stress along with other environmental stresses(especially UV and temperature).For experimentation,composite samples i.***.neat epoxy(NE),epoxy with 15%micro SiO_(2)(EMS),epoxy with 5%nano SiO_(2)(ENS),neat SiR(NS),SiR with 15%micro SiO_(2)(SMS)and SiR with 5%nano SiO_(2)(SNS)are fabricated and subjected to accelerated aging in a weather chamber for 3,360 hours.Results reveal that SMS and SNS offer better hydrophobic behavior followed by EMS.However noticeable surface discoloration in the form of whitish shade with minor blackish spots is found in the case of SMS,while remaining samples also showed considerable color fading.Scanning electron microscopy(SEM)and Fourier Transform Infrared Spectroscopy(FTIR)results showed that SNS and SMS presented quite excellent resistance to the exposure of fillers.Hardness and weight of all specimens are evaluated throughout the experiment and particularly for the water immersion test.Moreover,leakage current analysis indicated that SNS and SMS revealed high leakage current suppression compare to other samples.Findings indicate that SNS and SMS showed enhanced resistance against UV weathering under high voltage direct current stress.

关键词： Aging composites DC stress epoxy insulator UV SiR

Fabricating titanium dioxide/N-doped carbon nanofibers as advanced interlayer for improving cycling reversibility of lithium-sulfur batteries

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Chinese Journal of Chemical Engineering 2022年第12期52卷 88-94页

作者： Xingmei Guo Jinfeng Xie Jing Wang Shangqing Sun Feng Zhang Fu Cao Yuanjun Liu Xiangjun Zheng Junhao Zhang Qinghong Kong School of Environmental and Chemical Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province Yancheng Institute of TechnologyYancheng 224051China School of the Environment and Safety Engineering Jiangsu UniversityZhenjiang 212013China

"Shuttle effect" is detrimental for maintaining the high capacity and cycling reversibility of lithium-sulfur batteries(LSBs).To inhibit polysulfide migration,N-doped carbon nanofibers(N-CNFs) membrane comprising TiO_(2)nanoparticles(TiO_(2)/N-CNFs) is fabricated using an electrospinning-calcination method and further applied as interlayer in LSBs.The TiO_(2)/N-CNFs interlayer helps the battery to deliver a high specific capacity of 1155.2 mA·h·g^(-1)at 0.2 C with high Coulombic efficiency,good rate capability and stability.When cycling at 0.5 C,a capacity retention rate of 62.4% is achieved over 300 cycles,which is higher than that of CNFs and TiO_(2)/CNFs counterparts.The excellent performance should mainly be attributed to the alleviated "shuttle effect" deriving from high polysulfide trapping ability of TiO_(2)nanoparticles and N heteroatoms in interwoven CNFs.

关键词： TiO_(2)/N-CNFs interlayer composites Microstructure Adsorption Lithium-sulfur battery Shuttle effect

Hierarchical micro-nanostructures from polyoxometalates and polydopamine:Characterization,electrochemical and intrinsic peroxidase-like properties

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Particuology 2022年第5期20卷 178-185页

作者： Ruijuan Lv Xinming Zhang Ruimeng Sun Lixia Chen Yang Zhang Rongtian Sheng Ting Du Yuhan Li Yanfei Qi School of Public Health Jilin UniversityJilin 130021China

Hybrid composite materials with hierarchical structures have attracted continuing attention for their enhanced features and various applications.The new hybrid composites XW_(9)@PDA(XW_(9) means Na_(8)H[α-PW_(9)O_(34)],Na_(10)[α-SiW_(9)O_(34)]and Na_(10)[α-GeW_(9)O_(34)];PDA means polydopamine)have been synthesized for potential sensing applications.The effect of polyoxometalates on the formation of the hybrid composites was investigated.Scanning electron microscopy(SEM)supported the obtained XW_(9)@PDA were hierarchical microsphere.By monitoring the reaction of classical peroxidase substrate o-phenylenediamine(OPD)to form yellow 2,3-diaminophenazine(DAB)in the presence of H_(2)O_(2),the peroxidase-like activity of XW_(9)@PDA was calculated.The results showed that XW_(9)@PDA still keep the peroxidase-like activity and have 505.98%,208.58%and 582.78%enhancement in intrinsic catalytic activity for PW_(9)@PDA,SiW_(9)@PDA and GeW_(9)@PDA.Among the three composites,PW_(9)@PDA showed the highest peroxidase-like activity.Therefore,PW_(9)@PDA was applicable to the colorimetric and electrochemical sensing for H_(2)O_(2).

关键词： Polyoxometalates composites Dopamine Electrochemical Peroxidase-like activity

Tailoring the separation performance of a carbon nanotube-based mixed matrix membrane decorated with metal–organic framework

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Chinese Journal of Chemical Engineering 2023年第12期64卷 87-95页

作者： Hui-Yong Wu Hong-Xin Fu Yu Liu Xiao-Sa Zhang Wen-Ze Li Jian Luan College of Science Shenyang University of Chemical TechnologyShenyang 110142China College of Sciences Northeastern UniversityShenyang 110819China

Synthesis of mixed matrix membranes(MMM)using carbon nanotubes(CNTs)has shown great prospects for achieving excellent selective separation because of its special structure.Nevertheless,the preparation of highly selective MMM faces challenges,which is attributed to the obstacles encountered by CNTs dispersion in polymer matrix and elimination of interface defects.A novel CNT-based composite decorated with metal–organic framework(MOF)was synthesized and applied to the preparation of MMM.MOF was post modified,and then carboxyl groups were inserted on the outer surface of CNTs.The synthetic MMM(Cu-MOF-en@MWCNT)not only has selective adsorption on dyes,but also has selective photodegradation on dyes.The method of using CNTs to wrap the outside of MOF has great potential in dye separation.The performance of MMM was further improved by decorating MOF on the filler to improve the selectivity to the designated dye.

关键词： composites Carbon nanotube Metal-organic framework Organic crosslinking Selectivity Adsorbents

Smart superabsorbent alginate/carboxymethyl chitosan composite hydrogel beads as efficient biosorbents for methylene blue dye removal

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Journal of Materials Science & Technology 2023年第28期159卷 81-90页

作者： Zhen Zhang Noureddine Abidi Lucian Lucia Department of Forest Biomaterials NC State UniversityRaleighNCUSA Fiber and Biopolymer Research Institute Department of Plant and Soil ScienceTexas Tech UniversityLubbockTXUSA Department of Chemistry NC State UniversityRaleighNCUSA

The presence of toxic dyes in the aqueous medium has threatened environmental safety, and thereby re- moving them from wastewater in an efficient way is highly desired. Herein, the efficient biosorbents were successfully fabricated via a facile physical gelation process of sodium alginate (SA) and carboxymethyl chitosan (CMCTS) in an acidic aqueous solution. The as-prepared hydrogel beads not only displayed water superabsorbent properties and pH-responsive swelling characters but also exhibited excellent methylene blue (MB) adsorption capacity removal efficiency with experimental maximum MB adsorption capacity of 2518 and 1005 mg g -1 , which are comparable with most reported lignocellulosic and alginate-based hydrogels. The MB adsorption process fitted well in different kinetic and isotherm models and became more heterogeneous in concentrated MB solutions as verified by principal component analysis results. The adsorption mechanism was proposed, and the high dye absorbency was attributed to the strong electro- static forces between adsorbents and adsorbates. Our current study provides a promising and sustainable composite hydrogels platform targeted to dye decontamination.

关键词： Hydrogel Dye adsorption composites Superabsorbent Sodium alginate Carboxymethyl chitosan

Electrophoretic deposition of chitosan-bioglass^(■)-hydroxyapatite-halloysite nanotube composite coating

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Rare Metals 2022年第11期41卷 3850-3857页

作者： Arman Molaei MardAli Yousefpour Department of Materials Engineering Tehran Science and Research BranchIslamic Azad UniversityTehran***Iran Faculty of Materials Science and Metallurgical Engineering Semnan UniversitySemnan***Iran

The composite coatings of chitosan(CS)-bioglass^(■)(BG)-hydroxyapatite(HA)-halloysite nanotube(HNT)were investigated and produced via electrophoretic deposition(EPD)technique.The utilization of CS as a dispersing,blending and charging agent for ceramic particles,including BG,HA and HNT,allowed the formation of CS-BG/HA/HNT composite,functionally graded composite(FGC)and bilayer film containing different layers.The results of scanning electron microscopy(SEM),energy-dispersive spectrometry(EDS),X-ray diffraction(XRD)and Fourier transform infrared spectroscopy(FTIR)illustrate the composite in the form of the optimum distribution of ceramic components in the CS matrix with thickness of 28μm on titanium(Ti)substrate.Electrochemical impedance spectroscopy(EIS)and potentiodynamic polarization tests indicate that the corrosion resistance of the coated sample increases in corrected simulated body fluid(C-SBF)at 37℃.Finally,the apatiteinducing ability of CS-BG-HA-HNT is proved by the formation of carbonated hydroxyapatite particles on composite coating in C-SBF.

关键词： Four-component coating composites Biomaterials Electrophoretic deposition Corrosion

Multimaterial Embedded 3D Printing of Composite Reinforced Soft Actuators

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Research 2023年第4期2023卷 727-737页

作者： Zhenhua Wang Boyu Zhang Qu He Hao Chen Jizhe Wang Yuan Yao Nanjia Zhou Weicheng Cui Key Laboratory of Coastal Environment and Resources of Zhejiang Province School of EngineeringWestlake UniversityHangzhouZhejiang ProvinceChina Institute of Advanced Technology Westlake Institute for Advanced StudyHangzhouZhejiang ProvinceChina Research Center for Industries of the Future and Key Laboratory of 3D Micro/Nano Fabrication and Characterization of Zhejiang ProvinceSchool of EngineeringWestlake UniversityHangzhouZhejiang ProvinceChina

Soft pneumatic actuators(SPAs)have attracted enormous attention in the growing field of robotics.Among different SPAs,composite reinforced actuators(CRAs)are widely used because of their simple structure and high controllability.However,multistep molding,a time-consuming method,is still the predominant fabrication method.Here,we propose a multimaterial embedded printing method(ME3P)to fabricate CRAs.In comparison with other 3-dimensional printing methods,our method improves fabrication flexibility greatly.Via the design and fabrication of the reinforced composites’patterns and different geometries of the soft body,we demonstrate actuators with programmable responses(elongation,contraction,twisting,bending,and helical and omnidirectional bending).Finite element analysis is employed for the prediction of pneumatic responses and the inverse design of actuators based on specific actuation needs.Lastly,we use tube-crawling robots as a model system to demonstrate our ability to fabricate complex soft robots for practical applications.This work demonstrates the versatility of ME3P for the future manufacturing of CRA-based soft robots.

关键词： composites composite printing

Design of a graphene oxide@melamine foam/polyaniline@erythritol composite phase change material for thermal energy storage

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Chinese Journal of Chemical Engineering 2023年第6期58卷 282-290页

作者： Jianhui Zhou Xin Lai Jianfeng Hu Haijie Qi Shan Liu Zhengguo Zhang State Key Laboratory of Advance Power Transmission Technology(State Grid Smart Grid Research Institute Co.Ltd.) Beijing 102209China School of Chemistry and Chemical Engineering South China University of TechnologyGuangzhou 510640China

At present,only a single modification method is adopted to improve the shortcomings of erythritol(ET)as a phase change material(PCM).Compared with a single modification method,the synergistic effect of multiple modification methods can endow ET with comprehensive performance to meet the purpose of package,supercooling reduction,and enhancement of thermal conductivity.In this work,we innovatively combine graphene oxide(GO)nanosheet modified melamine foam(MF)and polyaniline(PANI)to construct a novel ET-based PCM by blending and porous material adsorption modification.PANI as the nucleation center can enhance the crystallization rate,thereby reducing the supercooling of ET.Meanwhile,GO@MF foam can not only be used as a porous support material to encapsulate ET but also as a heat conduction reinforcement to improve heat storage and release rate.As a result,the supercooling of GO@MF/PANI@ET(GMPET)composite PCM decreases from 91.2℃ of pure ET to 57.9℃ and its thermal conductivity(1.58 W·m^(-1)·K^(-1))is about three times higher than that of pure ET(0.57 W·m^(-1)·K^(-1)).Moreover,after being placed at 140℃ for 2 h,there is almost no ET leakage in the GMPET composite PCM,and the mass loss ratio is less than 0.75%.In addition,the GMPET composite PCM displays a high melting enthalpy of about 259 J·g^(-1) and a high initial mass loss temperature of about 198℃.Even after the 200th cycling test,the phase transition temperature and the latent heat storage capacity of the GMPET PCM all remain stable.This work offers an effective and promising strategy to design ET-based composite PCM for the field of energy storage.

关键词： composites Enthalpy Heat conduction Nucleation Phase change

COF-derived Co nanoparticles@N-doped carbon electrocatalysts for high performance Zn-air batteries

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Chinese Journal of Chemical Engineering 2023年第11期63卷 43-50页

作者： Jie Wei Chengcai Zhao Ming Chen Fengying Liu Limin Zhao Hui Zhao Zhong-Yong Yuan School of Materials Science and Engineering Liaocheng UniversityLiaocheng 252000China College of Chemistry and Chemical Engineering Xinyang Normal UniversityXinyang 464000China Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) School of Materials Science and EngineeringNankai UniversityTianjin 300350China

Precise modulation of the structure and composition of electrocatalysts is critical for promoting the kinetically sluggish process of oxygen reduction reaction(ORR)and oxygen evolution reaction(OER).Covalent organic frameworks(COF)offer a novel way to create highly efficient electrocatalysts due to their tunable composition,structure and surface area.Herein,we report a high-efficiency bifunctional electrocatalyst comprising Co nanoparticles embedded within N-doped carbons(Co@NCs)for Zn-air batteries(ZABs).The Co@NC is yielded via the coordination of a triazine COF with Co-containing precursors and subsequent calcination under inert atmosphere.The as-prepared Co@NC exhibits remarkable ORR/OER performance and great potential in rechargeable ZABs.The liquid ZAB constructed with Co@NC provides both high specific capacity and power density.Remarkably,the ZAB exhibits a voltage gap of 0.8 V during discharge and charge cycles and high stability for 220 h compared to the Pt/C-assembled battery.This strategy for regulating electrocatalytic activities of COF-derived carbon materials could be expanded for creating various carbon catalysts.

关键词： COF Co@NC composites Electrochemistry Catalysis Zn-air battery