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Third-order nonlinear optical properties of graphene composites:A review

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Chinese Physics B 2021年第8期30卷 120-131页

作者： Meng Shang Pei-Ling Li Yu-Hua Wang Jing-Wei Luo Hubei Province Key Laboratory of Science in Metallurgical Process Wuhan University of Science and TechnologyWuhan 430081 China

Graphene has excellent thirdorder nonlinear optical(NLO)properties due to its unique electronic band structure and wideband gap *** paper focuses on the research progress of graphene and its composite materials in nonlinear optics in recent *** this review,recent results on graphene(or graphene oxide)-metal nanoparticles(G-MNPs),graphene-metal-oxide nanoparticles(G-MONPs),graphene-metal sulfide nanoparticles(G-MSNPs),and graphene-organic molecular composites(G-OM)have been *** addition,the enhancement mechanism of nonlinear absorption(NLA)and optical limiting(OL)have also been covered.

关键词： graphene composites nonlinear optics optical limiting enhancement

A machine learning framework for damage mechanism identification from acoustic emissions in unidirectional SiC/SiC composites

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npj Computational Materials 2021年第1期7卷 1326-1335页

作者： C.Muir B.Swaminathan K.Fields A.S.Almansour K.Sevener C.Smith M.Presby J.D.Kiser T.M.Pollock S.Daly Materials University of California-Santa BarbaraSanta BarbaraCAUSA Mechanical Engineering University of California-Santa BarbaraSanta BarbaraCAUSA NASA Glenn Research Center ClevelandOHUSA Materials Science and Engineering University of Michigan-Ann ArborAnn ArborMIUSA

In this work,we demonstrate that damage mechanism identification from acoustic emission(AE)signals generated in minicomposites with elastically similar constituents is *** waveforms were generated by SiC/SiC ceramic matrix minicomposites(CMCs)loaded under uniaxial tension and recorded by four sensors(two models with each model placed at two ends).Signals were encoded with a modified partial power scheme and subsequently partitioned through spectral *** cracking and fiber failure were identified based on the frequency information contained in the AE event they produced,despite the similar constituent elastic properties of the matrix and ***,the resultant identification of AE events closely followed CMC damage chronology,wherein early matrix cracking is later followed by fiber breaks,even though the approach is fully domain-knowledge ***,the partitions were highly precise across both the model and location of the sensors,and the partitioning was *** presented approach is promising for CMCs and other composite systems with elastically similar constituents.

关键词： composites damage mechanism

Graphene oxide wrapped magnetic nanoparticle composites induced by SiO_(2) coating with excellent regenerability

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International Journal of Minerals,Metallurgy and Materials 2021年第12期28卷 2001-2007页

作者： Zhong-liang Hu Hou-quan Cui Yan-huai Ding Jing-ying Li Yi-rong Zhu Zhao-hui Li College of Metallurgy and Material Engineering Hunan University of TechnologyZhuzhou 412007China College of Chemistry Xiangtan UniversityXiangtan 411105China Institute of Fundamental Mechanics and Materials Engineering Xiangtan UniversityXiangtan 411105China

Graphene oxide(GO)wrapped Fe_(3)O_(4) nanoparticles(NPs)were prepared by coating the Fe_(3)O_(4) NPs with a SiO_(2) layer,and then modifying by amino groups,which interact with the GO nanosheets to form covalent *** SiO_(2) coating layer plays a key role in integrating the magnetic nanoparticles with the GO *** effect of the amount of SiO_(2) on the morphology,structure,adsorption,and regenerability of the composites was studied in *** appropriate SiO_(2) layer can effectively induce the GO nanosheets to completely wrap the Fe_(3)O_(4) NPs,forming a core-shell Fe_(3)O_(4)@SiO_(2)@GO composite where Fe_(3)O_(4)@SiO_(2) NPs are firmly encapsulated by GO *** optimized Fe_(3)O_(4)@SiO_(2)@GO sample exhibits a high saturated adsorption capacity of 253 mg·g^(-1) Pb(Ⅱ)cations from wastewater,and the adsorption process is well fitted by Langmuir adsorption ***,the composite displays excellent regeneration,maintaining a~90%adsorption capacity for five cycles,while other samples decrease their adsorption capacity *** work provides a theoretical guidance to improve the regeneration of the GO-based adsorbents.

关键词： composites composite coating

Microstructure and mechanical properties of aluminium metal matrix composites with addition of bamboo leaf ash by stir casting method

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Transactions of Nonferrous Metals Society of China 2017年第12期27卷 2555-2572页

作者： B.Praveen KUMAR Anil Kumar BIRRU Department of Mechanical Engineering National Institute of Technology Manipur 795004 India

Al-4.5%Cu alloy was used as a matrix at2%,4%and6%of bamboo leaf ash(BLA)which was extruded from agro waste and was used as *** composite which was fabricated by stir casting method possessed superior properties due to an effective bonding between matrix and reinforcement *** fabricated composite specimens were subjected to various tests to determine the mechanical properties such as density,porosity,hardness and tensile *** results were compared with basic matrix ***,the OM,SEM with EDAX and XRD analyses were carried out to analyze the dispersion of the reinforced particles in the selected matrix *** was observed that the homogeneous distribution of BLA particles in composites was intragranular in ***,it was also observed that BLA particles were well bonded with matrix alloy with clear *** was also found that the density decreased with increase in mass fraction of BLA particles and porosity increased with increase in mass fraction of BLA *** hardness and tensile strength were increased up to4%of BLA in the composite,with a further increase in BLA content the hardness and tensile strength decreased.

关键词： Al-4.5Cu alloy stir casting composites bamboo leaf ash density porosity

In situ reaction mechanism of MgAlON in Al–Al2O3–MgO composites at 1700°C under flowing N2

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International Journal of Minerals,Metallurgy and Materials 2017年第9期24卷 1061-1066页

作者： Shang-hao Tong Yong Li Ming-wei Yan Peng Jiang Jia-jia Ma Dan-dan Yue School of Materials Science and Engineering University of Science and Technology BeijingBeijing 100083China

The Al–AlO–MgO composites with added aluminum contents of approximately 0wt%, 5wt%, and 10wt%, named as M, M, and M, respectively, were prepared at 1700°C for 5 h under a flowing Natmosphere using the reaction sintering method. After sintering, the Al–AlO–MgO composites were characterized and analyzed by X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The results show that specimen Mwas composed of MgO and MgAlO. Compared with specimen M, specimens Mand Mpossessed MgAlON, and its production increased with increasing aluminum addition. Under an Natmosphere, MgO, AlO, and Al in the matrix of specimens Mand Mreacted to form MgAlON and AlN-polytypoids, which combined the particles and the matrix together and imparted the Al–AlO–MgO composites with a dense structure. The mechanism of MgAlON synthesis is described as follows. Under an Natmosphere, the partial pressure of oxygen is quite low; thus, when the Al–AlO–MgO composites were soaked at 580°C for an extended period, aluminum metal was transformed into AlN. With increasing temperature, AlOdiffused into AlN crystal lattices and formed AlN-polytypoids; however, MgO reacted with AlOto form MgAlO. When the temperature was greater than(1640 ± 10)°C, AlN diffused into AlOand formed spinel-structured AlON. In situ MgAlON was acquired through a solid-solution reaction between AlON and Mg AlOat high temperatures because of their similar spinel structures.

关键词： composites metal aluminum nitrogen atmosphere magnesium aluminum oxynitride reaction mechanism

Enhanced switching electric field and breakdown strength of epoxy composites with core-shell silicon carbide nanoparticles

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High Voltage 2023年第3期8卷 583-589页

作者： Yongsen Han Zi Wang Jian Sun Zhonghua Li Key Laboratory of Engineering Dielectrics and Its Application Ministry of EducationHarbin University of Science and TechnologyHarbinHeilongjiangChina

Silicon carbide(SiC)is widely used to improve the non-linear conductivity of non-linear resistive field grading *** this paper,the SiC nanoparticles are modified into core-shell nanoparticles with silica(SiO_(2))coating on the surface and are characterised by transmission electron microscopy and X-ray diffraction,*** 7 wt%SiC@SiO_(2)/epoxy nanocomposite is then prepared,and the pure epoxy and 7 wt%SiC/epoxy nanocomposite are prepared as a *** relative permittivity,thermally stimulated current,conductivity and breakdown strength are studied,*** presence of SiO_(2)shell around SiC nanoparticles has a great effect on the relative permittivity and trap *** epoxy nanocomposites show non-linear conductivity characteristics,compared with pure *** 7 wt%SiC@SiO_(2)/epoxy nanocomposite has higher switching electric field and breakdown strength than the 7 wt%SiC/epoxy nanocomposite,which is helpful for the application of non-linear resistive field grading composite in higher-voltage equipment or components.

关键词： nanoparticles composites composite

Effect of Different Reinforcing Fillers on Properties,Interfacial Compatibility and Weatherability of Wood-plastic composites

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Journal of Bionic Engineering 2019年第2期16卷 337-353页

作者： Xiaoqian Wang Zhiming Yu Armando G.McDonald MOE Key Laboratory of Wooden Material Science and Application Beijing Forestry UniversityQinghua East Road No.35Beijing 100083China Renewable Materials Program Department of ForestRangelandand Fire SciencesUniversity of Idaho875 Perimeter Drive MS 1133MoscowIdaho 83844-1133USA

Utilization of biochar in plastic based blends offers a sustainable way to renewable materials as well as value-added use of wood *** investigate the interfacial compatibility and weatherability properties of biochar composites,four types of Wood-Plastic composites(WPC)were prepared by an extrusion *** mechanical properties,water absorptions,thermal and viscoelastic properties,and rheological behavior of the composites were also *** decolorizing carbon(NA)composite melts showed the higher modulus and viscosity,indicating better melt *** NA composites performed the best in tensile properties(strength of 2&6 MPa and modulus of 3.4 GPa)and had strong interfacial interaction between particles and the *** degree of HDPE crystallinity in the biochar and carbon composites decreased relative to Douglas-fir(DF)composites,while the thermal properties of the composites improved compared with DF *** the water resistance,the DF composites displayed the highest water absorption(3.7%)and thickness swell(2.9%).During accelerated weathering tests,longer exposure time increased the color change and lightness,especially for DF *** and biochar composites resulted in improved *** study opens up a pathway to utilize effectively the renewable biochar as reinforcing filler in WPC in outdoor applications.

关键词： biochar interfacial compatibility accelerated weathering wood-plastic composites

Corrosion and tribocorrosion behavior of Ti6Al4V/xTiN composites for biomedical applications

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Transactions of Nonferrous Metals Society of China 2022年第2期32卷 540-558页

作者： J.CHÁVEZ O.JIMÉNEZ D.BRAVO-BARCENAS L.OLMOS F.ALVARADO-HERNÁNDEZ M.A.GONZÁLEZ A.BEDOLLA-JACUINDE M.FLORES Departamento de Ingeniería Mecánica Eléctrica CUCEIUniversidad de GuadalajaraBlvd.Marcelino García Barragán#1421GuadalajaraC.P.44430México Departamento de Ingeniería de Proyectos CUCEIUniversidad de GuadalajaraJoséGuadalupe Zuno#48Los BelenesZapopanC.P.45150México Departamento de Ingeniería de Proyectos CUCEIUniversidad de Guadalajara-CONACyTBlvd.Marcelino García Barragán#1421GuadalajaraC.P.44430México Instituto de Investigaciones en Ciencias de la Tierra INICITUniversidad Michoacana de San Nicolás de HidalgoAv.Francisco J.Mujica S/NCiudad UniversitariaMoreliaMichoacánC.P.58030México Unidad Académica de Ingeniería I Universidad Autónoma de ZacatecasAv.López Valverde 801ZacatecasZacatecasC.P.98060México Instituto de Investigaciones Metalúrgicas IIMMUniversidad Michoacana de San Nicolás de HidalgoEdificio‘‘U-5’’Ciudad UniversitariaMoreliaMichoacánC.P.58030México

The corrosion and tribocorrosion behavior of Ti6Al4V/xTiN(x=0,5,10 and 15,vol.%)composites fabricated by solid-state sintering and their relationship with the microstructure and microhardness were *** body conditions such as a temperature of 37℃ and a simulated body fluid were *** main results demonstrated a microstructural change caused by theα-Ti stabilization due to solid-solution of nitrogen(N)into the titanium(Ti)lattice,producing a maximum hardening effect up to 109%for the Ti64 matrix by using 15 vol.%*** potentials of composites changed to more noble values with the TiN particle addition,while corrosion current density of samples increased as an effect of the remaining porosity,decreasing the corrosion resistance of ***,changes to a less passive behavior were observed for samples with 15 vol.%*** non-passive behavior of composites resulted in the reduction of the potential drops during rubbing in tribocorrosion ***,an improvement of up to 88%of the wear rate of composites was seen from the solid-solution *** results allowed to understand the relationship between composition and sintering parameters with the improved tribocorrosion performance of materials.

关键词： Ti64 alloy composites powder metallurgy microstructure corrosion tribocorrosion

Cu-(B4C)p metal matrix composites processed by accumulative rollbonding

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Progress in Natural Science:Materials International 2016年第6期26卷 613-620页

作者： S.Mansourzadeh M.Hosseini E.Salahinejad A.H.Yaghtin Department of Materials Science and Engineering College of Chemical and Metallurgical EngineeringShiraz BranchIslamic Azad University Department of Materials Science and Engineering School of EngineeringShiraz University Faculty of Materials Science and Engineering K.N.Toosi University of Technology

In this study, Cu/B4C metal matrix composites were prepared by accumulative roll-bonding(ARB). The microstructure of the processed samples was characterized by TEM, SEM and optical microscopy. The microhardness, uniaxial tensile and four-point probe tests were carried out to evaluate the mechanical properties and electrical resistivity of the ARBed monolithic and composite samples. The results showed that the reinforcement distribution was improved by increasing ARB cycles, which was quantitatively confirmed by some models. Based on TEM observations, the formation of an ultrafine grained structure in the composite matrix was also approved. It was shown that with increasing ARB cycles, the microhardness and tensile strength of the monolithic Cu samples were enhanced up to the 3rd cycle and then saturated, but the microhardness and tensile strength of the composites showed an increasing trend to the last cycle. Apart from a substantial improvement in the mechanical properties of the Cu/B4C composites, a minor decrement in electrical conductivity was detected after six ARB cycles.

关键词： Electron microscopy Mechanical characterization composites