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Numerical Modeling of NO Formation during Packed-bed Combustion of coke Granules

International Journal of Minerals,metallurgy and Materials 2000年第4期14卷 261-268页

作者： Chunbao Xu, Shengli Wu, Daqiang Cang (metallurgy School, University of Science and Technology Beijing, Beijing 100083, China Institute for Chemical Reaction Science, Tohoku University, Japan) metallurgy School University of Science and Technology Beijing Beijing 100083 China Institute for Chemical Reaction Science Tohoku University Japan

A comprehensive kinetic model of NO formation during coke combustion in packed-bed in presence of noncombustible particles was developed. The detailed homogeneous gas-phase chemistry (including 102 chemical reactions), heterogeneous gas-solid chemistry (including 11 reactions) of coke combustion and NO formation, and the heat and mass transfer were taken into account in the present model. The governing equations which are strongly coupled, non-linear and unsteady with 26 unknowns in total, were dispersed into differential equations with the finite differential method. Meanwhile, all the differential equations were numerically solved to give the time-histories and space-distributions oftemperatures of the bed and gas phase as well as the concentrations of all the gaseous species. By comparison, the experimental data were explained well by the calculated results. Based on the kinetic and mathematical model, the effects of O2 content of inlet gas, the initial chemical analysis of coke, bed-temperature and local reductive atmosphere (CO/O2) on NO formation during packed-bed coke combustion were numerically discussed. It was found that coke samples with a higher initial content of [N] and volatile matters, combusted under a suitable O2-containing atmosphere produced less NO emission. The reactions between CO and NO, catalyzed by high temperature surface of coke particles may be responsible for efficient reduction of NO.

关键词： kinetic model NO formation combustion packed-bed coke metallurgy

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