检索结果-南通市图书馆

Co-conversion of methanol and n-hexane into aromatics using intergrown ZSM-5/ZSM-11 as a catalyst

Frontiers of Chemical Science and Engineering 2020年第5期14卷 783-792页

作者： Shumei Wei Yarong Xu Zhaoyang Jin Xuedong Zhu UNILAB State Key Laboratory of Chemical EngineeringEast China University of Science and TechnologyShanghai 200237China Research Institute of Urumqi Petrochemical Company Petrochina Company LimitedUrumqi 830019China

The conversion of n-hexane and methanol into value-added aromatic compounds is a promising method for their industrially relevant utilization.In this study,intergrown ZSM-5/ZSM-11 crystals were synthesized and their resulting catalytic performance was investigated and compared to those of the isolated ZSM-5 and ZSM-1I zeolites.The physicochemical properties of ZSM-5/ZSM-l1 intergrown zeolite were analyzed using X-ray diffrac-tion,N2 isothermal adsorption-desorption,the tempera-ture-programmed desorption of ammonium,scanning clectron microscopy,Fourier transform infrared spectra of adsorbed pyridine,and nuclear magnetic resonance of 27AI,and compared with those of the ZSM-5 and ZSM-11 zeolites.The catalytic performances of the materials were evaluated during the co-feeding reaction of methanol and n-hexane under the fixed bed conditions of 400℃,0.5 MPa(N2),methanol:n-hexane=7:3(mass ratio),and weight hourly space velocity=1 h 1(methanol).Com-pared to the ZSM-5 and ZSM-11 zeolites,the ZSM-5/ZSM-11 zeolite exhibited the largest specific surface area,a unique crystal structure,moderate acidity,and suitable Brensted/Lewis acid ratio.The evaluation results showed that ZSM-5/ZSM-11 catalyst exhibited better catalytic reactivity than the ZSM-5 and ZSM-11 catalysts in terms of methanol conversion rate,n-hexane conversion rate,and aromatic selectivity.The outstanding catalytic property of the intergrown ZSM-5/ZSM-11 was attributed to the enhanced diffusion associated with its unique crystal.structure.The benefit of using zeolite intergrowth in the co-conversion of methanol and alkanes offers a novel route for future catalyst development.

关键词： ZSM-5/ZSM-11 methanol w-hexane cofeeding aromatics

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：