检索结果-南通市图书馆

Antibiotic ciprofloxacin removal from aqueous solutions by electrochemically activated persulfate process:Optimization,degradation pathways,and toxicology assessment

引用

Journal of Environmental Sciences 2024年第9期143卷 85-98页

作者： Elif Yakamercan Ahmet Aygün Halis Simsek Environmental Engineering Department Bursa Technical UniversityBursaTurkey Agricultural and Biological Engineering Department Purdue UniversityWest LafayetteINUSA

ciprofloxacin(CIP)is a commonly used antibiotic in the fluoroquinolone group and is widely used in medical and veterinary medicine disciplines to treat bacterial infections.When CIP is discharged into the sewage system,it cannot be removed by a conventional wastewater treatment plant because of its recalcitrant characteristics.In this study,boron-doped diamond anode and persulfate were used to degrade CIP in an aquatic solution by creating an electrochemically activated persulfate(EAP)process.Ironwas added to the system as a coactivator and the process was called EAP+Fe.The effects of independent variables,including pH,Fe^(2+),persulfate concentration,and electrolysis time on the systemwere optimized using the response surface methodology.The results showed that the EAP+Fe process removed 94%of CIP under the following optimum conditions:A pH of 3,persulfate/Fe^(2+)concentration of 0.4 mmol/L,initial CIP concentration 30 mg/L,and electrolysis time of 12.64 min.CIP removal efficiency was increased from 65.10%to 94.35%by adding Fe^(2+)as a transition metal.CIP degradation products,7 pathways,and 78 intermediates of CIP were studied,and three of those intermediates(m/z 298,498,and 505)were reported.The toxicological analysis based on toxicity estimation software results indicated that some degradation products of CIP were toxic to targeted animals,including fathead minnow,Daphnia magna,Tetrahymena pyriformis,and rats.The optimumoperation costswere similar in EAP and EAP+Fe processes,approximately 0.54€/m^(3).

关键词： ciprofloxacin Response surface methodology Electrochemically activated persulfate Electrooxidation

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Effects of operating conditions on iron(hydr)oxides evolution and ciprofloxacin degradation in potassium ferrate-ozone stepwise oxidation system

引用

Journal of Environmental Sciences 2024年第1期135卷 367-378页

作者： Xiaochen Li Yifan Wang Ning Wang Mei Li Maomao Bai Jingtao Xu Hongbo Wang School of Municipal and Environmental Engineering Shandong Jianzhu UniversityJinan 250101China Resources and Environment Innovation Institute Shandong Jianzhu UniversityJinan 250101China

In this study,a stepwise oxidation system of potassium ferrate(K_(2)FeO_(4))combined with ozone(O+3)was used to degrade ciprofloxacin(CIP).The effects of pH and pre-oxidation time of K_(2)FeO_(4) on the evolution of K_(2)FeO_(4) reduction products(iron(hydr)oxides)and CIP degradation were investigated.It was found that in addition to its own oxidation capacity,K_(2)FeO_(4) can also influence the treatment effect of CIP by changing the catalyst content.The presence of iron(hydr)oxides effectively enhanced the mineralization rate of CIP by catalyzing ozonation.The pH value can influence the content and types of the components with catalytic ozonation effect in iron(hydr)oxides.The K_(2)FeO_(4) pre-oxidation stage can produce more iron(hydr)oxides with catalytic components for subsequent ozonation,but the evolution of iron(hydr)oxides components was influenced by O_(3) treatment.It can also avoid the waste of oxidation capacity owing to the oxidation of iron(hydr)oxides by O_(3) and free radicals.The intermediate degradation products were identified by Fourier transform ion cyclotron resonance mass spectrometry(FT-ICR-MS).Besides,the degradation pathways were proposed.Among the degradation products of CIP,the product with broken quinolone ring structure only appeared in the stepwise oxidation system.

关键词： Potassium ferrate reduction products Catalytic ozonation ciprofloxacin Potassium ferrate pre-oxidation time

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Cobalt-loaded carbon nanotubes boosted aerobic ciprofloxacin transformation driven by sulfide:A comprehensive mechanism investigation

引用

Chinese Chemical Letters 2024年第3期35卷 127-134页

作者： Han-Qing Zhao Peili Lu Fei Chen Chen-Xuan Li Rui Yan Yang Mu State Key Laboratory of Coal Mine Disaster Dynamics and Control Chongqing UniversityChongqing 400044China CAS Key Laboratory of Urban Pollutant Conversion Department of Environmental Science and EngineeringUniversity of Science and Technology of ChinaHefei 230026China Key Laboratory of the Three Gorges Reservoir Region's Eco-Environment College of Environment and EcologyChongqing UniversityChongqing 400045China College of Resources and Environmental Engineering Hefei University of TechnologyHefei 230009China

Sulfide oxidation under aerobic conditions can produce active oxygen for the transformation of organic pollutants in aquatic environments.However,the catalytic performance of transition metal-supported carbon material on this process is poor understood.This study found that Co-loaded carbon nanotubes(CNTs)was able to realize the efficient aerobic transformation of antibiotic ciprofloxacin(CIP)by sulfide,with the pseudo-first order reaction rate constant improved from 0.013 h^(-1)without catalyst to 0.44–0.71 h^(-1)with 100 mg/L Co-loaded CNTs.Singlet oxygen(^(1)O_(2))was the main active specie playing key roles in the process of CIP aerobic transformation with presence of Co-loaded CNTs.Mechanism studies indicated that the excellent electron transfer ability of Co-loaded CNTs might play an important role to promote the electron transfer and facilitate the formation of intermediate H_(2)O_(2)and^(1)O_(2).Additionally,the Co-loaded CNTs/sulfide system effectively reduced the acute toxicity of organic pollutant,and Co-loaded CNTs showed remarkable cycling stability and negligible leaching.This study gives a better understanding for the Co-loaded CNTs mediated aerobic antibiotics transformation by sulfide,and provide a reference for the application of Co-loaded carbon materials on organics aerobic transformation by sulfide.

关键词： ciprofloxacin Aerobic transformation Co-loaded carbon nanotubes Sulfide Singlet oxygen

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

A mechanistic study of ciprofloxacin adsorption by goethite in the presence of silver and titanium dioxide nanoparticles

引用

Journal of Environmental Sciences 2022年第8期34卷 46-56页

作者： Jie Tang Yun Wang Qiang Xue Fei Liu Kenneth CCarroll Xiaohua Lu Taogeng Zhou Dengjun Wang MOE Key Laboratory of Groundwater Circulation and Environmental Evolution China University of Geosciences(Beijing)Beijing 100083China Beijing Key Laboratory of Water Resources and Environmental Engineering School of Water Resources and EnvironmentChina University of Geosciences(Beijing)Beijing 100083China Water Science and Management Program New Mexico State UniversityMSC 3QUSA Plant&Environmental Science New Mexico State UniversityLas CrucesNM 88003USA National Institute of Metrology Beijing 100022China Beijing Institute of Technology Beijing 100081China School of Fisheries Aquaculture and Aquatic SciencesAuburn UniversityAuburnAL 36849USA

The adsorption behaviors of ciprofloxacin(CIP),a fluoroquinolone antibiotic,onto goethite(Gt)in the presence of silver and titanium dioxide nanoparticles(AgNPs and TiO_(2)NPs)were investigated.Results showed that CIP adsorption kinetics in Gt with or without NPs both followed the pseudo-second-order kinetic model.The presence of AgNPs or TiO_(2)NPs inhibited the adsorption of CIP by Gt.The amount of inhibition of CIP sorption due to AgNPs was decreased with an increase of solution pH from 5.0 to 9.0.In contrast,in the presence of TiO_(2)NPs,CIP adsorption by Gt was almost unchanged at pHs of 5.0∼6.5 but was decreased with an increase of pH from 6.5 to 9.0.The mechanisms of AgNPs and TiO_(2)NPs in inhibiting CIP adsorption by Gt were different,which was attributed to citrate coating of AgNPs resulting in competition with CIP for adsorption sites on Gt,while TiO_(2)NPs could compete with Gt for CIP adsorption.Additionally,CIP was adsorbed by Gt or TiO_(2)NPs through a tridentate complex involving the bidentate inner-sphere coordination of the deprotonated carboxylic group and hydrogen bonding through the adjacent carbonyl group on the quinoline ring.These findings advance our understanding of the environmental behavior and fate of fluoroquinolone antibiotics in the presence of NPs.

关键词： ciprofloxacin Goethite Silver nanoparticles Titanium dioxide nanoparticles Adsorption

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Effects of different carbon sources on the removal of ciprofloxacin and pollutants by activated sludge:Mechanism and biodegradation

引用

Journal of Environmental Sciences 2022年第1期34卷 240-248页

作者： Yixiang Cai Zhiyong Yan Yingjuan Ou Boshang Peng Lihua Zhang Jihai Shao Yiqing Lin Jiachao Zhang Hunan International Scientific and Technological Cooperation Base of Agricultural Typical Pollution Remediation and Wetland Protection Hunan Agricultural UniversityChangsha 410028China

This research investigated the effects of ciprofloxacin(CIP)(0.5,5,and 20 mg/L)on SBR systems under different carbon source conditions.Microbial community abundance and structure were determined by quantitative PCR and high-throughput sequencing,respectively.The biodegradation production of CIP and possible degradation mechanism were also studied.Results showed that CIP had adverse effects on the nutrient removal from wastewater.Compared with sodium acetate,glucose could be more effectively used by microorganisms,thus eliminating the negative effects of CIP.Glucose stimulated the microbial abundance and increased the removal rate of CIP by 18%–24%.The mechanism research indicated that Proteobacteria and Acidobacteria had a high tolerance for CIP.With sodium acetate as a carbon source,the abundance of nitrite-oxidizing bacterial communities decreased under CIP,resulting in the accumulation of nitrite and nitrate.Rhodanobacter and Microbacterium played a major role in nitrification and denitrification when using sodium acetate and glucose as carbon sources.Dyella and Microbacterium played positive roles in the degradation process of CIP and eliminated the negative effect of CIP on SBR,which was consistent with the improved removal efficiency of pollutants.

关键词： ciprofloxacin Microbial community Sequencing batch reactor Carbon source Biodegradation pathway

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Prior exposure to ciprofloxacin disrupts intestinal homeostasis and predisposes ayu(Plecoglossus altivelis)to subsequent Pseudomonas plecoglossicida-induced infection

引用

Zoological Research 2022年第4期43卷 648-665页

作者： Xiang-Yu Wu Jin-Bo Xiong Chen-Jie Fei Ting Dai Ting-Fang Zhu Zi-Yue Zhao Jing Pan Li Nie Jiong Chen State Key Laboratory for Managing Biotic and Chemical Threats to the Quality and Safety of Agro-Products Ningbo UniversityNingboZhejiang 315211China Laboratory of Biochemistry and Molecular Biology School of Marine SciencesMeishan CampusNingbo UniversityNingboZhejiang 315211China Collaborative Innovation Center for Zhejiang Marine High-Efficiency and Healthy Aquaculture School of Marine SciencesNingbo UniversityNingboZhejiang 315211China

With the rapid development of intensive farming,the aquaculture industry uses a great many antibiotics for the prevention and treatment of bacterial diseases.Despite their therapeutic functions,the overuse and accumulation of antibiotics also pose a threat to aquaculture organisms.In the present study,ayu(Plecoglossus altivelis)was used as a fish model to study the impacts of ciprofloxacin(CIP)overuse on intestinal homeostasis and immune response during subsequent Pseudomonas plecoglossicida infection.Based on 16S rRNA gene amplification and Illumina sequencing,we found that CIP pre-exposure caused significant variation in intestinal microbiota,including increased species richness,altered microbiota composition and interaction networks,and increased metabolic dysfunction.Furthermore,immunohistochemical analysis indicated that CIP pre-exposure resulted in severe mucosal layer damage,goblet cell reduction,and epithelial cell necrosis of the intestinal barrier in infected ayu.Quantitative real-time polymerase chain reaction(qRT-PCR)showed that disruption of intestinal homeostasis impaired systemic antiinfection immune responses in the intestine,gill,spleen,and head kidney,while inhibiting IL-1β,TNF-α,and IL-10 expression and promoting TGF-βexpression.Our findings indicated that CIP administration can directly affect intestinal microbiota composition and intestinal integrity in ayu fish.This perturbation of intestinal homeostasis is likely responsible for the lower survival rate of hosts following subsequent infection as the capacity to mount an effective immune response is compromised.This study also provides preliminary clues for understanding the effects of antibiotic overuse on higher vertebrates through trophic transfer.

关键词： ciprofloxacin Microbiota Intestinal barrier Immune responses Ayu

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

H_(3)PO_(4) activated biochars derived from different agricultural biomasses for the removal of ciprofloxacin from aqueous solution

引用

Particuology 2023年第4期75卷 217-227页

作者： Jinbo Ouyang Jian Chen Wenqian Chen Limin Zhou Di Cai Cong Ren Jiangxi Province Key Laboratory of Polymer Micro/Nano Manufacturing and Devices East China University of TechnologyNanchang330013China Department of Pharmacy National University of Singapore117544Singapore National Energy Research and Development Center for Biorefinery Beijing University of Chemical TechnologyBeijing100029China

Biochars were prepared by the pyrolysis of various H_(3)PO_(4) activated agricultural biomasses at 600℃and subsequently used as adsorbents for the removal of ciprofloxacin(CIP)from aqueous solution.Peanut shell-based biochar(PSBC),corncob-based biochar(CCBC)and cotton-based biochar(CTBC)had high surface areas(571.0-1006.3 m^(2)/g),well-developed pore structures(mesopores with large pore volumes)and available adsorption functional groups(C=C,C-N and C-O-C).The CIP adsorption onto the biochars was investigated by batch experiments(kinetics,isotherms,thermodynamics,pH,etc.).Thermodynamics calculations showed the spontaneous(ΔG^(θ)0)nature of the mechanism.In particular,CCBC exhibited high adsorption capacity(120.6 mg/g)of CIP in real lake water and it also had significant removal efficiency of other common pharmaceutical contaminants from real lake environ-ment,and even in a coexisting quintuple system.Finally,multiple interaction mechanisms of CIP adsorption onto aromatized biochar were explored combining characterization analysis and theoretical calculations.Elucidation of the mechanism of CIP adsorption onto biochar provides new insights into the assessment of the removal of pharmaceuticals from the aqueous environment.

关键词： Biochar Adsorption Pharmaceutical contaminants ciprofloxacin Water remediation

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

The combination of ciprofloxacin and indomethacin suppresses the level of inflammatory cytokines secreted by macrophages in vitro

引用

Chinese Journal of Traumatology 2022年第6期25卷 379-388页

作者： Ke Liu Jing Yu Yu Xia Lei-Ting Zhang Sui-Yan Li Jun Yan School of Life Science and Engineering Southwest Jiaotong UniversityChengdu 610031China State Key Laboratory of Trauma Burns and Combined InjuryResearch Institute of SurgeryDaping HospitalArmy Medical University(Third Military Medical University)Chongqing 400042China

Purpose:The combined use of antibiotics and anti-inflammatory medicine to manage bacterial endotoxin-induced inflammation following injuries or diseases is increasing.The cytokine level produced by macrophages plays an important role in this treatment course.ciprofloxacin and indomethacin,two typical representatives of antibiotics and anti-inflammatory medicine,are cost-effective and has been reported to show satisfactory effect.The current study aims to investigate the effect of ciprofloxacin along with indomethacin on the secretion of inflammatory cytokines by macrophagesin vitro.Methods:Primary murine peritoneal macrophages and RAW 264.7 cells were administrated with lipopolysaccharide(LPS)for 24 h.The related optimal dose and time point of ciprofloxacin or indomethacin in response to macrophage inflammatory response inflammation were determined via macrophage secretion induced by LPS.Then,the effects of ciprofloxacin and indomethacin on the secretory functions and viability of various macrophages were determined by enzyme-linked immunosorbent assay and flow cytometry analysis,especially for the levels of interleukin(IL)-1β,IL-6,IL-10,and tumor necrosis factor(TNF)-α.The optimal dose and time course of ciprofloxacin affecting macrophage inflammatory response were determined by testing the maximum inhibitory effect of the drugs on pro-inflammatory factors at each concentration or time point.Results:According to the levels of cytokines secreted by various macrophages(1.2×10^(6) cells/well)after administration of 1μg/mL LPS,the optimal dose and usage timing for ciprofloxacin alone were 80μg/mL and 24 h,respectively,and the optimal dose for indomethacin alone was 10μg/mL.Compared with the LPS-stimulated group,the combination of ciprofloxacin and indomethacin reduced the levels of IL-1β(pciprofloxacin or indomethacin was

关键词： ciprofloxacin Indomethacin Inflammatory cytokines In vitro Macrophages

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Efficient interfacial charge transfer of BiOCl-In_(2)O_(3) step-scheme heterojunction for boosted photocatalytic degradation of ciprofloxacin

引用

Journal of Materials Science & Technology 2022年第26期121卷 236-244页

作者： Kaiqiang Xu Jie Shen Shiying Zhang Difa Xu Xiaohua Chen College of Materials Science and Engineering Hunan UniversityChangsha 410082China Hunan Key Laboratory of Applied Environmental Photocatalysis Changsha UniversityChangsha 410005China

BiOCl as a representative layered bismuth-based photocatalyst with Sillén-structure has aroused wide public concern on photocatalytic degradation.However,the photocatalytic efficiency of pristine BiOCl is currently restricted by its low optical absorption and charge separation efficiency.Herein,step-scheme(S-scheme)heterojunctions of In_(2)O_(3) nanoparticle and BiOCl micron-sheet were constructed by a convenient molten salt method by using a LiNO_(3)-KNO_(3) system.The In_(2)O_(3)-BiOCl heterojunctions exhibit higher optical absorption performance from 380 nm to 700 nm than the pristine BiOCl and enhanced photocatalytic property toward ciprofloxacin(CIP)degradation under Xenon lamp illumination.The sample 20%In_(2)O_(3) -BiOCl showed the highest photodegradation efficiency,attaining 91%removal of CIP within 35 min,which was 39.6 times and 3.2 times higher than that of pristine In_(2)O_(3) and BiOCl,respectively.The improved photodegradation property mainly resulted from the novel S-scheme mechanism,which boosted highly efficient separation of the photo-induced carriers.The photoluminescence spectrometric test and transient photocurrent response results demonstrated that In_(2)O_(3)-BiOCl composite exhibited efficient separation of photo-generated charge carriers.This work would provide new insights into the design of novel S-scheme photocatalytic systems with applicability in photocatalytic water treatment.

关键词： Step-scheme photocatalyst In_(2)O_(3) BiOCl Photocatalytic activity ciprofloxacin

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

ZnFe_(2)O_(4)/BiVO_(4)Z-scheme heterojunction for efficient visible-light photocatalytic degradation of ciprofloxacin

引用

Frontiers of Chemical Science and Engineering 2023年第11期17卷 1728-1740页

作者： Beibei Wang Kejiang Qian Weiping Yang Wenjing An Lan-Lan Lou Shuangxi Liu Kai Yu MOE Key Laboratory of Pollution Processes and Environmental Criteria Tianjin Key Laboratory of Environmental Technology for Complex Transmedia PollutionCollege of Environmental Science and EngineeringNankai UniversityTianjin 300350China Institute of New Catalytic Materials Science School of Materials Science and EngineeringNational Institute of Advanced MaterialsNankai UniversityTianjin 300350Chin

A novel Z-scheme ZnFe_(2)O_(4)/BiVO_(4)heterojunction photocatalyst was successfully synthesized using a convenient solvothermal method and applied in the visible light photocatalytic degradation of ciprofloxacin,which is a typical antibiotic contaminant in wastewater.The heterostructure of as-synthesized catalysts was confirmed using X-ray diffraction,scanning electron microscopy,transmission electron microscopy and X-ray photoelectron spectroscopy characterizations.Compared with the singlephase counterparts,ZnFe_(2)O_(4)/BiVO_(4)demonstrated considerably enhanced photogenerated charge separation efficiencies because of the Z-scheme transfer mechanism of electrons between the composite photocatalysts.Consequently,the 30%ZnFe_(2)O_(4)/BiVO_(4)catalyst afforded a degradation rate of up to 97%of 20 mg/L ciprofloxacin under 30 min of visible light irradiation with a total organic carbon removal rate of 50%,which is an excellent activity compared with ever reported BiVO_(4)-based catalysts.In addition,the liquid chromatography-mass spectrometry and quantitative structure-activity relationships model analyses demonstrated that the toxicity of the intermediates was lower than that of the parent ciprofloxacin.Moreover,the as-synthesized ZnFe_(2)O_(4)/BiVO_(4)heterojunctions were quite stable and could be reused at least four times.This study thus provides a promising Z-scheme heterojunction photocatalyst for the efficient removal and detoxication of antibiotic pollutants from wastewater.

关键词： ZnFe_(2)O_(4)/BiVO_(4) Z-scheme heterojunction photocatalytic degradation ciprofloxacin

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：