检索结果-南通市图书馆

RuO_(2)/TiO_(2)/MXene with multi-heterojunctions coating on carbon cloth for high-activity chlorine evolution reaction at large current densities

引用

Nano Research 2024年第6期17卷 4764-4772页

作者： Yuhao Duan Liuxu Wei Chenyu Cai Junbao Mi Fuyuan Cao Jiaze Chen Xiaolong Li Xiujiang Pang Bin Li Lei Wang Key Laboratory of Eco-chemical Engineering Ministry of EducationInternational Science and Technology Cooperation Base of Eco-chemical Engineering and Green ManufacturingCollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042China College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042China College of Environment and Safety Engineering Qingdao University of Science and TechnologyQingdao 266042China

The chlorine evolution reaction(CER)is a crucial step in the production of chlorine gas and active chlorine by chlor-alkali ***,the endeavor to fabricate electrodes capable of yielding high current density at minimal overpotential remains a central challenge in advancing the realm of chlorine evolution ***,we grow TiO_(2)and RuO_(2)on MXene@carbon cloth(CC)through the favorable affinity and induced deposition effect between the surface functional groups of MXene and the metal.A self-supported electrode(RuTiO_(2)/MXene@CC)with strong binding at the electrocatalyst-support interface and weak adhesion at electrocatalyst-bubble interface is *** RuTiO_(2)/MXene@CC can reduce the electron density of RuO_(2)by regulating the electron redistribution at the heterogeneous interface,thus enhancing the adsorption of Cl−.RuTiO_(2)/MXene@CC could achieve a high current density of 1000 mA·cm^(−2)at a small overpotential of 220 mV,superior to commercial dimensionally stable anodes(DSA).This study provides a new strategy for constructing efficient CER catalysts at high current density.

关键词： chlorine evolution reaction high current density MXene TiO_(2) RuO_(2)

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Unveiling the geometric site dependent activity of spinel Co_(3)O_(4)for electrocatalytic chlorine evolution reaction

引用

Journal of Energy Chemistry 2024年第5期92卷 95-103页

作者： Linke Cai Yao Liu Jingfang Zhang Qiqi Jia Jiacheng Guan Hongwei Sun Yu Yu Yi Huang Key Laboratory of Pesticide&Chemical Biology of Ministry of Education Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction of Ministry of EducationCollege of ChemistryCentral China Normal UniversityWuhan 430079HubeiChina Key Laboratory of Green Chemical Engineering Process of Ministry of Education Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationHubei Key Laboratory of Novel Reactor and Green Chemical TechnologySchool of Chemical Engineering&PharmacyWuhan Institute of TechnologyWuhan 430205HubeiChina College of Materials Science and Engineering Fuzhou UniversityFuzhou 350108FujianChina School of Chemistry and Chemical Engineering Anhui UniversityHefei 230601AnhuiChina

Spinel cobalt oxide(Co_(3)O_(4)),consisting of tetrahedral Co^(2+)(CoTd)and octahedral Co^(3+)(CoOh),is considered as promising earth-abundant electrocatalyst for chlorine evolution reaction(CER).Identifying the catalytic contribution of geometric Co site in the electrocatalytic CER plays a pivotal role to precisely modulate electronic configuration of active Co sites to boost ***,combining density functional theory calculations and experiment results assisted with operando analysis,we found that the Co_(Oh) site acts as the main active site for CER in spinel Co_(3)O_(4),which shows better Cl^(-)adsorption and more moderate intermediate adsorption toward CER than CoTd site,and does not undergo redox transition under CER condition at applied *** by above findings,the oxygen vacancies were further introduced into the Co_(3)O_(4) to precisely manipulate the electronic configuration of Co_(Oh) to boost Cl^(-)adsorption and optimize the reaction path of CER and thus to enhance the intrinsic CER activity *** work figures out the importance of geometric configuration dependent CER activity,shedding light on the rational design of advanced electrocatalysts from geometric configuration optimization at the atomic level.

关键词： chlorine evolution reaction Geometry effects Active chlorine Electronic configuration optimization Spinel oxides

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Electrocatalytic seawater splitting for hydrogen production:Recent progress and future prospects

引用

Journal of Materials Science & Technology 2023年第31期162卷 203-226页

作者： Changrui Feng Meng Chen Ziyuan Yang Zhengkun Xie Xiumin Li Shasha Li Abuliti Abudula Guoqing Guan Graduate School of Science and Technology Hirosaki University3-BunkyochoHirosaki 036-8561Japan Energy Conversion Engineering Laboratory Institute of Regional InnovationHirosaki University3-BunkyochoHirosaki 036-8561Japan College of Chemistry Zhengzhou UniversityZhengzhou 450001China School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001China College of Chemical and Biological Engineering Taiyuan University of Science and TechnologyTaiyuan 030024China

Earth-abundant seawater resource has become an attractive candidate to produce hydrogen from electrolysis,which is of great significance to realize hydrogen economy and carbon ***,developing highly active and stable electrocatalysts to meet the needs of highly effective seawater splitting is still challenging for the sluggish oxygen evolution dynamics and the existed competitive reaction of chlorine evolution reaction(CER).To this end,some newly-developed electrocatalysts with superior performance,such as noble metals,alloy,transition metals,oxides,carbides,nitrides,phosphides,and so on,have been synthesized for the seawater splitting in recent *** review starts from the historical background and fundamental mechanisms,and summarizes the most recent progress in the development of seawater electrolysis *** existing issues in the process of seawater electrolysis are enumerated and the corresponded solutions are *** future of hydrogen production from seawater electrolysis,especially the design and synthesis of novel catalysts for seawater electrolysis,is prospected.

关键词： Seawater electrolysis Electrocatalysts Hydrogen production Oxygen evolution reaction chlorine evolution reaction Selectivity

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Study of engineering electronic structure modulated non-noble metal oxides for scaled-up alkaline blend seawater splitting

引用

Journal of Energy Chemistry 2023年第11期86卷 167-179,I0004页

作者： Natarajan Logeshwaran Subramanian Vijayapradeep Ae Rhan Kim Prabhakaran Sampath Shanmugam Ramakrishnan Milan Babu Poudel Do Hwan Kim Dong Jin Yoo Graduate School Department of Energy Storage/Conversion Engineering(BK21 FOUR)Hydrogen and Fuel Cell Research CenterJeonbuk National University567-Baekje-daeroDeokjin-guJeonju-siJeollabuk-do 54896Republic of Korea Department of Life Science Jeonbuk National University567-Baekje-daeroDeokjin-guJeonju-siJeollabuk-do 54896Republic of Korea Division of Science Education and Institute of Fusion Science Jeonbuk National University567-Baekje-daeroDeokjin-guJeonju-siJeollabuk-do 54896Republic of Korea Department of Nano Convergence Engineering Jeonbuk National University567-Baekje-daeroDeokjin-guJeonju-siJeollabuk-do 54896Republic of Korea School of Engineering Merz CourtNewcastle UniversityNE17RUUnited Kingdom

Scaled-up industrial water electrolysis equipment that can be used with abundant seawater is key for affordable hydrogen *** search for highly stable,dynamic,and economical electrocatalysts could have a significant impact on hydrogen ***,we prepared energy-efficient,scalable,and engineering electronic structure modulated Mn-Ni bimetal oxides(Mn_(0.25)Ni_(0.75)O)through simple hydrothermal followed by calcination ***-optimized Mn_(0.25)Ni_(0.75)O displayed enhanced oxygen and hydrogen evolution reaction(OER and HER)performance with overpotentials of 266 and115 mV at current densities of 10 mA cm^(-2)in alkaline KOH added seawater electrolyte ***,Mn-Ni oxide catalytic benefits were attributed to the calculated electronic configurations and Gibbs free energy for OER,and HER values were estimated using first principles *** real-time practical application,we mimicked industrial operating conditions with modified seawater electrolysis using Mn_(0.25)Ni_(0.75)O‖Mn_(0.25)Ni_(0.75)O under various temperature conditions,which performs superior to the commercial IrO_(2)‖Pt-C *** findings demonstrate an inexpensive and facile technique for feasible large-scale hydrogen production.

关键词： Waterel ectrolysis Mn-Ni oxide complex chlorine evolution reaction Industrial seawater operations Density functional theory calculations

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Recent progress in transition-metal-oxide-based electrocatalysts for the oxygen evolution reaction in natural seawater splitting: A critical review

引用

eScience 2023年第2期3卷 16-31页

作者： Meng Chen Nutthaphak Kitiphatpiboon Changrui Feng Abuliti Abudula Yufei Ma Guoqing Guan School of Science and Technology Hirosaki University1-BunkyochoHirosaki 036-8560Japan Energy Conversion Engineering Laboratory Institute of Regional Innovation(IRI)Hirosaki University3-BunkyochoHirosaki 036-8561Japan College of Chemistry and Materials Science Hebei Normal UniversityShijiazhuang 050025HebeiChina

Direct electrolytic splitting of seawater for the production of H2 using ocean energy is a promising technology that can help achieve carbon ***,owing to the high concentrations of chlorine ions in seawater,the chlorine evolution reaction always competes with the oxygen evolution reaction(OER)at the anode,and chloride corrosion occurs on both the anode and ***,effective electrocatalysts with high selectivity toward the OER and excellent resistance to chloride corrosion should be *** this critical review,we focus on the prospects of state-of-the-art metal-oxide electrocatalysts,including noble metal oxides,non-noble metal oxides and their compounds,and spinel-and perovskite-type oxides,for seawater *** elucidate their chemical properties,excellent OER selectivity,outstanding anti-chlorine-corrosion performance,and reaction *** particular,we review metal oxides that operate at high current densities,near industrial application levels,based on special catalyst design strategies.

关键词： Seawater splitting Hydrogen production Oxygen evolution reaction chlorine evolution reaction Metal-oxide-based catalysts High current density

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：