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Journal of Rare Earths 2006年第Z2期24卷 288-292页

作者：高文元孙俊才刘莎刘扬李长敏唐乃岭 Institute of materials and Technology Dalian Maritime University Department of Material Science and Engineering Dalian Institute of Light IndustryDalian 116034China Department of Material Science and Engineering Dalian Institute of Light Industry

In order to lower the raw materials cost and develop a novel cathode materials for intermediate temperature solid oxide fuel cell(ITSOFC), using mixed rare earth replacing the expensive pure La2O3 as the raw materials, the powders of Ln0.7Sr0.3-xCaxCo0.9Fe0.1O3-δ(Ln = the mixed rare earth, x =0.05, 0. 10, 0. 15) for the applications as the cathode materials were prepared by microwave sintering process. The crystal structure and the particles morphology of the obtained powders were characterized by XRD and SEM, the electrical conductivity of all samples sintered at 1200℃for 3 h was also measured as the function of the temperature from 100 to 800℃by DC four-probe method in air. The experimental results show that due to the influence of mixed rare earth the powders of Ln0.7Sr0.3-xCaxCo0.9Fe0.1O3-δsynthesized at 1200℃for 0.5 h with the mean particle size of 1 ~ 20μm was of perovskite and cubic fluorite phase as well a little SrO phase, the electrical conductivity of the samples decreases with the adding Ca2+ content, and are all higher than 100 S·cm -1from 500 to 700℃when x≤0.10. Ln0.7Sr0.3-xCaxCo0.9Fe0.1O3-δ. can meet the demand of the electrical properties for the cathode materials in ITSOFC.

关键词： microwave synthesis cathode materials electrical conductivity rare earths

Electrochemical Performance of Surface-Modified LiMn_2O_4 Prepared by a Melting Impregnation Method

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Journal of materials Science & Technology 2006年第4期22卷 433-436页

作者： Jian TU Xinbing ZHAO Gaoshao CAO Tiejun ZHU Dagao ZHUANG diangping TU State Key Laboratory of Silicon materials Zhejiang University Hangzhou 310027 China

The surface of as-prepared LiMn2O4 was modified with ZnO, Al2O3, CoO and LiCoO2 using a simple nitrate melting impregnation method. Transmission electron microscopy （TEM） studies indicated that oxide nano- particles in the range of 10～50 nm are coated on the surface of the spinel. The surface modified samples show better capacity retention than the unmodified LiMn2O4 spinel at both room temperature and 55℃. Among these samples, the ZnO-modified LiMn2O4 shows the best combination of a high capacity and a low capacity fading rate of 0.036% per cycle at room temperature and 0.064% per cycle at 55℃. The improvement for surface modified LiMn2O4 can be attributed to the inhibition of Mn dissolution and O losses on the surface.

关键词： LiMn2O4 spinel Surface modification Melting impregnation cathode materials Lithium-ion batteries

Preparation of Li[Ni_(1/3)Co_(1/3)Mn_(1/3)]O_2 powders for cathode material in secondary battery by solid-state method

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Rare Metals 2006年第Z2期25卷 184-188页

作者： PARK Sook Hee KANG Chan Hyoung Department of Advanced materials Engineering Korea Polytechnic University Shihung Kyonggi-do 429-793 Korea

Employing Li2CO3, NiO, Co3O4, and MnCO3 powders as starting materials, Li[Ni1/3Co1/3Mn1/3]O2 was synthesized by solid-state reaction method. Various grinding aids were applied during milling in order to optimize the synthesis process. After successive heat treatments at 650 and 950 ℃, the prepared powders were characterized by X-ray diffraction (XRD) analysis, scanning electron microscopy, and transmission electron microscopy. The powders prepared by adding salt (NaCl) as grinding aid exhibit a clear R3m layer structure. The powders by other grinding aids like heptane show some impurity peaks in the XRD pattern. The former powders show a uniform particle size distribution of less than 1 μm average size while the latter shows a wide distribution ranging from 1 to 10 μm. Energy dispersive X-ray (EDX) analysiss show that the ratio of Ni, Co, and Mn content in the powder is approximately 1/3, 1/3, and 1/3, respecively. The EDX data indicate no incorporation of sodium or chlorine into the powders. Charge-discharge tests gave an initial discharge capacity of 160 mAh·g-1 for the powders with NaCl addition while 70 mAh·g-1 for the powders with heptane.

关键词： lithium ion battery cathode materials layered structure solid-state method discharge density

A new candidate as the cathode material for intermediate and low temperature SOFCs

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Rare Metals 2006年第Z1期25卷 213-217页

作者： LI Song SUN Xueli WEN Zhongsheng SUN Juncai Institute of materials and Technology Dalian Maritme University Dalian 11606 China Institute of Materials and Technology Dalian Maritme University Dalian 11606 China Institute of Materials and Technology Dalian Maritme University Dalian 11606 China Institute of Materials and Technology Dalian Maritme University Dalian 11606 China

In order to develop the new cathode materials suitable for intermediate and low temperature solid oxide fuel cells (IT/LTSOFCs), LaNi1-xFexO3 (x=0.4-0.8) (LNF) materials were synthesized using coprecipitation method. Their structures and morphologies were investigated by XRD and SEM, and their electronic conductivities at different temperatures were measured by dc four terminal method. Fuel cells were fabricated to evaluate the electrochemical properties of the LNF materials as cathodes at different temperatures. The performance of 450-497 mW·cm-2 was obtained in the temperature region of 580-650 ℃ for the LaNi0.2Fe0.8O3 cathode, and of 209-227 mW·cm-2 at 400-500 ℃ for the LaNi0.4Fe0.6O3. The excellent fuel cell performances indicate that the LNF materials are good cathodes for IT/LTSOFCs.

关键词： LaNi1-xFexO3 cathode materials coprecipitation method IT/LTSOFC

Development prospects of metal-based two-dimensional nanomaterials in lithium-sulfur batteries

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Chinese Chemical Letters 2023年第1期34卷 102-113页

作者： Yuxue Mo Liling Liao Dongyang Li Rongwu Pan Yanhong Deng Yanliang Tan Haiqing Zhou College of Physics and Electronic Engineering Hengyang Normal UniversityHengyang 421002China Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of Ministry of Education Key Laboratory for Matter Microstructure and Function of Hunan ProvinceDepartment of Physics and Synergetic Innovation Center for Quantum Effects and ApplicationsHunan Normal UniversityChangsha 410081China Hunan Joint International Laboratory of Advanced materials and Technology for Clean Energy Changsha 410082China Hunan Shengli High-tech Energy Technology Co. Ltd.Yongzhou 425000China Hunan Provincial Key Laboratory of Intelligent Information Processing and Application Hengyang 421002China

A lithium-sulfur(Li-S)system is an important candidate for future lithium-ion system due to its low cost and high specific theoretical capacity(1675 m Ah/g,2600 Wh/kg),which is greatly hindered by the poor conductivity of sulfur,large volume change and dissolution of lithium ***-dimensional(2D)materials with monolayers or few-layers usually have peculiar structures and physical/chemical properties,which can resolve the critical issues in Li-S ***,the metal-based 2D nanomaterials,including ferrum,cobalt or other metal-based composites with various anions,can provide high conductivity,large surface area and abundant reaction sites for restraining the diffusion for lithium *** this mini-review,we will present an overview of recent developments on metal-based 2D nanomaterials with various anions as the electrode materials for Li-S *** the main bottleneck for the Li-S system is the shuttle of polysulfides,emphasis is placed on the structure and components,physical/chemical interaction and interaction mechanisms of the 2D ***,the challenges and prospects of metal-based 2D nanomaterials for Li-S batteries are discussed and proposed.

关键词： Lithium-sulfur battery Two-dimensional materials cathode materials Anode materials Anode protection

Quest for carbon and vanadium oxide based rechargeable magnesium-ion batteries

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Journal of Magnesium and Alloys 2020年第2期8卷 364-373页

作者： Muhammad Rashad Muhammad Asif Iftikhar Ahmed Zhen He Li Yin Zhou Xiao Wei Yuxin Wang School of materials Science and Engineering Jiangsu University of Science and TechnologyZhenjiang212003 JiangsuChina Department of materials Science and Engineering College of EngineeringPeking UniversityBeijing 100871China Faculty of Science Jiangsu UniversityZhenjiang212013 JiangsuChina

Rechargeable magnesium ion batteries are potential candidates to replace the lithium ion batteries due to their high volumetric energy density,dendrite free cycling,and low *** present work,we have critically reviewed the recent advances made in the field of cathode materials development to achieve the high reversible capacities and working *** first part,carbon-based cathodes such as fluorinedoped graphene nanosheets and graphite fluoride(CF0.8)are discussed in terms of compatibilities of pos让ive electrode materials and electrolyte solutions for rechargeable magnesium-ion ***,the second part of this review focuses on crystal structure of vanadium oxide and its capability to accommodate the Mg^2+***,electrochemical performance of selected vanadium oxide based cathodes including VO2(B),FeVO4.0.9H2(X Mc)2.5+yVO9+δ,RFC/V2O5 and V2O5/Graphene composite,are discussed at different *** support the future research on magnesium ion batteries,particularly positive electrode material developments,several innovative research directions are proposed.

关键词： Magnesium-ion battery Energy storage cathode materials Electrolytes Vanadium oxide Electrochemical properties

Rare Earth Elements-Doped LiCoO_2 cathode Material for Lithium-Ion Batteries

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Journal of Rare Earths 2003年第4期21卷 466-468页

作者：魏进平曹晓燕潘桂玲叶茂阎杰 Institute of New Energy Material Chemistry College of Chemistry and Chemical Engineering State Key Laboratory of Functional Polymer materials for Adsorption and Separation

Some compounds of LiCo 1- x RE x O 2 (RE=rare earth elements and x =0.01～0.03) were prepared by doping rare earth elements to LiCoO 2 via solid state synthesis. The microstructure characteristics of the LiCo 1- x RE x O 2 were investigated by XRD. It was found that the lattice parameters c are increased and the lattice volumes are enlarged compared to that of LiCoO 2. Moreover, the performance of LiCo 1- x RE x O 2 as the cathode material in lithium ion battery is improved, especially LiCo 1- x Y x O 2 and LiCo 1- x La x O 2. The initial charge/discharge capacities of LiCo 0.99 Y 0.01 O 2 and LiCo 0.99 La 0.01 O 2 are 174/154 (mAh·g -1 ) and 159/149 (mAh·g -1 ) respectively, while those for LiCoO 2 working in the same way are only 139/131 (mAh·g -1 ).

关键词： metallic material lithium ion battery doping cathode materials LiCoO 2 rare earths

Spinel Phases LiRE_xMn_(2-x)O_4(RE=Nd, Ce) as cathode for Rechargeable Lithium Batteries

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Journal of Rare Earths 2000年第2期18卷 115-119页

作者：彭正顺江泱金增媛 Dept. of Chem. Capital Normal Univ. Beijing 100037 China

Several series of LiRE x Mn 2-x O 4(RE=Ce, Nd) samples prepared at different contents and in different rare earth metals substitution were studied in order to further understand the dependence of the electrochemical performance on the doping rare earth metals. These cathodes were more tolerant to repeat lithium extraction and insertion than a standard LiMn 2O 4 spinel electrode in spite of a small reduction in the initial capacity. X ray photoelectron spectroscopy results show that the Mn 4+ contents for spinel LiMn 2O 4 directly affected the initial capacity and cyclability of LiMn 2O 4.

关键词： rare earths lithium manganese oxide cathode materials lithium ion battery doping

Synthesis and Characterization of Mg_3(PO_4)_2-coated Li_(1.05)Ni_(1/3)Mn_(1/3)Co_(1/3)O_2 cathode Material for Li-ion Battery

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Journal of Wuhan University of Technology(materials Science) 2009年第3期24卷 347-353页

作者：陈玉红 Department of Chemical and Environmental Engineering Hebei Chemical & Pharmaceutical Vocational Technology Colege

Mg3（PO4）2-coated Li1.05Ni1/3Mn1/33Co1/3O2 cathode materials were synthesized via co-precipitation method. The morphology, structure, electrochemical performance and thermal stability were characterized by scanning electron microscopy （SEM）, X-ray diffraction （XRD）, cyclic voltammetry（CV）, electrochemical impedance spectroscopy（EIS）, charge/discharge cycling and differential scanning calorimeter （DSC）. SEM analysis shows that Mg3（PO4）2-coating changes the morphologies of their particles and increases the grains size. XRD and CV results show that Mg3（PO4）2-coating powder is homogeneous and has better layered structure than the bare one. Mg3（PO4）2-coating improved high rate discharge capacity and cycle-life performance. The reason why the cycling performance of Mg3（PO4）2-coated sample at 55 ℃ was better than that of room temperature was the increasing of lithium-ion diffusion rate and charge transfer rate with temperature rising. Mg3（PO4）2-coating improved the cathode thermal stability, and the result was consistent with thermal abuse tests using Li-ion cells： the Mg3（PO4）2 coated Li1.05Ni1/3Mn1/3Co1/3O2 cathode did not exhibit thermal runaway with smoke and explosion, in contrast to the cells containing the bare Li1.05Ni1/3Mn1/3Co1/3O2.

关键词： lithium-ion batteries cathode materials Li1.05Ni1/3Mn1/3Co1/3O2 co-precipitation

Formation of Na_(1+x)V_3O_8 Nanoribbon Thin Film from V_2O_5 Xerogel on Sodium Silicate Glass Substrate

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Chemical Research in Chinese Universities 2007年第4期23卷 381-383页

作者： GUO Yi XU Jin-jie LI Jun YANG Wen-sheng College of Chemistry Jilin University Changchun 130012 P. R. China

Na1＋xV3O8 nanoribbon thin film was successfully fabricated by annealing the V2O5 xerogel film on sodium sili-cate glass substrate at 450℃. It has been identified that the amount of sodium ions diffused into the V2O5 xerogel film increases with the high temperature of annealing treatment. The sodium glass substrate serves as a limited sodium source to induce the transformation from V2O5 to Na1＋xV3O8.

关键词： Vanadium pentoxide Sodium silicate glass Nanoribbon cathode materials