检索结果-南通市图书馆

Recent Advances in Organic Electrochemical C-H Functionalization

Chinese Journal of Chemistry 2018年第4期36卷 338-352页

作者： qi-Liang Yang Ping Fan Tian-Sheng Mei State Key Laboratory of Organometallic Chemistry Center for Excellence in Molecular Synthesis Shanghai Institute of Organic Chemistry Chinese Academy of Sciences 345 Lingling Lu Shanghai 200032 China Key Laboratory for Advanced Materials and Institute of Fine Chemicals School of Chemistry & Molecular Engineering East China University of Science and Technology 130 Meilong Road Shanghai 200237 China

Organic electrochemistry has a rich history in organic synthesis and has been considered as a promising alternative to traditional chemical oxidants and reductants because it obviates the use of stoichiometric amount of dangerous and toxic reagents. In particular, the electrochemical C-H bonds functionalization is one of the most desirable approaches for the construction of carbon-carbon （C-C） and carbon-heteroatom （C-X） bonds. This review summarizes the substantial progress made in the last few years in C-H functionalization via organic electrochemistry. It is divided into sections on C-C, C-N, C-O, C-S, C-Halogen and C-P bond formation.

关键词： organic electrochemistry C-H functionalization carbon-carbon bond formation carbon-heteroatom bond formation

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Transition-metal catalyzed asymmetric reactions under continuous flow from 2015 to early 2020

Green Synthesis and Catalysis

引用

Green Synthesis and Catalysis 2020年第2期1卷 121-133页

作者： Jingyuan Liao Shilong Zhang Zesheng Wang Xiao Song Dongliang Zhang Ravi Kumar Jian Jin Peng Ren Hengzhi You Fen-Er Chen School of Science Harbin Institute of Technology(Shenzhen)Shenzhen 518055China Green Pharmaceutical Engineering Research Center Harbin Institute of Technology(Shenzhen)Shenzhen 518055China Engineering Center of Catalysis and Synthesis for Chiral Molecules Department of ChemistryFudan UniversityShanghai 200433China

During last two decades,transition-metal catalyzed asymmetric reactions under continuous flow system have attracted a widespread attention.With its prominent advantages including higher safety and efficiency,precise control,better heat/mass transfer,easier scale-up and better sustainability,it has impressed both the academia and related industries.However,comparing with the prosperous development of transition-metal catalyzed asymmetric reactions in batch,utilization of this type of chemistry under continuous flow is still at an early stage.To inspire more potential industrial application and further studies of this chemistry in flow,this review sum-marized the recent advances of transition-metal catalyzed asymmetric reactions under continuous flow.Moreover,we further discussed the encountered challenges including reactor engineering,catalyst design,catalyst deacti-vation,pressure drop,clogging,side reactions etc.,as well as their corresponding solutions and achievements in this mini-review.

关键词： Transition-metal catalyst Asymmetric Continuous flow carbon-carbon bond formation Hydrogenation carbon-heteroatom bond formation Oxidation

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：