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Microporous metal-organic framework materials for efficient capture and separation of greenhouse gases

Science China Chemistry 2023年第8期66卷 2181-2203页

作者： Shan-Qing Yang Tong-Liang Hu Banglin Chen School of Materials Science and Engineering National Institute for Advanced MaterialsNankai UniversityTianjin300350China Department of Chemistry University of Texas at San AntonioSan AntonioTexas78249-0698USA

The release of anthropogenic greenhouse gases into the atmosphere poses serious risks to the environment and human health,and is a global threat of growing concern.In order to ameliorate the greenhouse gas emission problems,the efficient capture and separation of these greenhouse gases are greatly meaningful.Metal-organic framework(MOF)materials,a relatively new kind of organic-inorganic hybrid porous materials with unique framework features,tunable pore environment and high surface areas,have been widely studied as regards their applicability to this implementation.And the well-defined structures of MOF materials greatly promote the understanding of structure-property relationships.In this review,we intend to provide a profound account of significant progress in the field of capture and separation of greenhouse gases using MOFs as adsorbents,including carbon dioxide,methane,nitrous oxide and fluorocompounds(such as perfluorocarbons,sulfur hexafluoride,hydrochlorocarbons,and hydrofluocarbons).The strategies used to realize the efficient capture and separation of greenhouse gases have been summarized,and the relationships between the frameworks,their capture and separation performances and mechanisms are discussed.Furthermore,the existing challenges and perspectives with regard to the development of MOF materials for the capture and separation of greenhouse gases and industrial practical application are outlined to further promote this very significant and active emerging topic.

关键词： porous materials metal-organic frameworks greenhouse gases capture and separation structure-property relationship

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Semi-clathrate hydrate based carbon dioxide capture and separation techniques

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Frontiers of Environmental Science & Engineering 2023年第12期17卷 1-29页

作者： Lijuan Gu Hailong Lu Beijing International Center for Gas Hydrate School of Earth and Space SciencesPeking UniversityBeijing 100871China National Engineering Research Center for Gas Hydrate Exploration and Development Guangzhou 511466China

CO_(2)is considered as the main contributor to global warming,and hydrate enclathration is an efficient way for carbon capture and separation(CCS).Semi-clathrate hydrate(SCH)is a type of clathrate hydrate capable of encaging CO_(2)molecules under mild temperature and pressure conditions.SCH has numerous unique advantages,including high thermal stability,selective absorption of gas molecules with proper size and recyclable,making it a promising candidate for CCS.While SCH based CCS technology is in the developing stage and great efforts have to be conducted to improve the performance that is determined by their thermodynamical and structural properties.This review summarizes and compares the thermodynamic and structural properties of SCH and quaternary salt hydrates with gas mixtures to be captured and separated.Based on the description of the physical properties of SCH and hydrate of quaternary salts with gas mixture,the CO_(2)capture and separation from fuel gas,flue gas and biogas with SCH are reviewed.The review focuses on the use of tetra-nbutyl ammonium halide and tetra-n-butyl phosphonium halide,which are the current application hotspots.This review aims to provide guidance for the future applications of SCH.

关键词： Semi-clathrate hydrate Tetra-n-butyl ammonium halide Tetra-n-butyl phosphonium halide Structure Thermodynamical properties CO_(2) capture and separation

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Immobilization of carbonic anhydrase for facilitated CO2 capture and separation

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Chinese Journal of Chemical Engineering 2020年第11期28卷 2817-2831页

作者： Zhenhua Wu Yan Nan Yang Zhao Xueying Wang Shouying Huang Jiafu Shi Key Laboratory for Green Chemical Technology of Ministry of Education School of Chemical Engineering&TechnologyTianjin UniversityTianjin 300072China School of Environmental Science&Engineering Tianjin UniversityTianjin 300072China Collaborative Innovation Center of Chemical Science and Engineering Tianjin 300072China

Carbonic anhydrase(CA)as a typical metalloenzyme in biological system can accelerate the hydration/dehydration of carbon dioxide(CO2,the major components of greenhouse gases),which performer with high selectivity,environmental friendliness and superior efficiency.However,the free form of CA is quite expensive(~RMB 3000/100 mg),unstable,and non-reusable as the free form of CA is not easy for recovery from the reaction environment,which severely limits its large-scale industrial applications.The immobilization may solve these problems at the same time.In this context,many efforts have been devoted to improving the chemical and thermal stabilities of CA through immobilization strategy.Very recently,a wide range of available inorganic,organic and hybrid compounds have been explored as carrier materials for CA immobilization,which could not only improve the tolerance of CA in hazardous environments,but also improve the efficiency and recovery to reduce the cost of large-scale application of CA.Several excellent reviews about immobilization methods and application potential of CA have been published.By contrast,in our review,we stressed on the way to better retain the biocatalytic activity of immobilized CA system based on different carrier materials and to solve the problems facing in practical operations well.The concluding remarks are presented with a perspective on constructing efficient CO2 conversion systems through rational combining CA and advanced carrier materials.

关键词： Carbon dioxide Carbonic anhydrase Enzyme immobilization capture and separation Carrier materials

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