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Evaluation of Novel Chitosan Based composites Coating on Wettability for Pure Titanium Implants

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Journal of Renewable Materials 2023年第4期11卷 1601-1612页

作者： Qahtan A.Hamad Hanaa A.Al-Kaisy Mohanad N.Al-Shroofy Noor K.Faheed Materials Engineering Department University of TechnologyBaghdadIraq Petroleum Engineering Department University of MisanAmaraIraq

This work aims to prepare chitosan(CS)-based coated layers,CS(10 wt%nanosilver/90 wt%CS,10 wt%biotin/90 wt%CS,and 5 wt%nanosilver–5 wt%biotin)/90 wt%CS coatings are prepared,onto pure Ti *** surface morphology of the novel CS composite coating was studied using field emission scanning electron microscopy,atomic force microscopy(AFM),Fourier transforms infrared(FTIR)and wettability *** show that the addition of(biotin,nanosilver)5 Vol.%improves the properties of composite *** different particles’scale size aid in improving the combinations in the alginate,producing a dual effect on film *** surface roughness decreased in the chitosan-based biocomposite with preferable homogeneity and crack-free coating layers,as confirmed by *** increase in surface roughness ensured substitution,which enhanced the surface *** high wettability of the CS-based coating layers was due to the presence of nanoparticles,and the composite coatings with CS,nanosilver,or biotin had excellent wettability because of the good hydrophilic nature of the CS matrix combined with reinforced *** FTIR results showed that peaks of the blending of CS plus nanoparticles,CS plus biotin,or CS plus nanosilver plus biotin were excellent matching with no changes in the structure of the matrix.

关键词： Nano silver biotin chitosan coating bio-composite implants titanium

Research Achievements and Trends in Forest Products Science in Indonesia

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Journal of Agricultural Science and Technology(B) 2012年第1期2卷 1-14页

作者： Yusuf Sudo Hadi Faculty of Forestry Bogor Agricultural University Bogor 16680 Indonesia

The supply of logs for wood industries during the period 2004-2008 was 13.5-32 million cubic meters per year. Logs from plantation forest reached about 65%, which was exploited from industrial plantation forest, Perum Perhutani, as a government enterprise, community forest and estate. The changing log supply from natural forest to plantation forest implies changing of wood species, cutting cycle, log diameter and wood properties. Research concerning the utilization of fast growing species, small log diameter, lesser used species and other llignocellulosic material have been intensively done by some research institutes and universities, and were related to wood properties, wood properties enhancement, wood chemistry, bio-composite, wood engineering, and also non-timber forest products.

关键词： Wood properties wood properties enhancement wood chemistry bio-composite wood engineering non-timber forest products.

Optimization of Extrusion Process Parameters of Recycled High-Density Polyethylene-Thermoplastic Starch composite for Fused Filament Fabrication

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Open Journal of composite Materials 2023年第4期13卷 69-86页

作者： Grace Njeri Wamuti James Wamai Mwangi Samuel Kabini Karanja Leif Micke Henning Zeidler Pan African University Institute of Basic Sciences Technology and Innovation Nairobi Republic of Kenya Department of Mechatronic Engineering Jomo Kenyatta University of Agriculture and Technology Nairobi Republic of Kenya Chair of Additive Manufacturing Technische Universit&aumlt Bergakademie Freiberg Freiberg Germany

High-density poly-ethylene (HDPE) is a nonbiodegradable recyclable plastic which is widely utilized in single use packaging applications. Consequently, it constitutes a significant amount of plastic waste found in landfills. From literature, it has been shown that parts produced using composites of HDPE with carbohydrate-based polymers, such as thermoplastic starch (TPS), experience mechanical degradation through hydrolytic degradation process. The possible utilization of recycled-HDPE (rHDPE) and TPS composite in nonconventional manufacturing processes such as Fused filament fabrication (FFF) has however not been explored. This study explores the potential application of rHDPE and TPS composites in FFF and optimizes the extrusion process parameters used in rHDPE-TPS filament production process. Taguchi method was utilized to analyze the extrusion process. The extrusion process parameters studied were the spooling speed, extrusion speed and the extrusion temperatures. The response variable studied was the filament diameter. In this research, the maximum TPS content achieved during filament production was 40 wt%. This filament was however challenging to use in FFF printers due to frequent nozzle clogging. Printing was therefore done with filaments that contained 0 - 30 wt% TPS. The experimental results showed that the most significant parameter in extrusion process was the spooling speed, followed by extrusion speed. Extrusion temperature had the least significant influence on the filament diameter. It was observed that increase in TPS content resulted in reduced warping and increased rate of hydrolytic degradation. Mechanical properties of printed parts were investigated and the results showed that increasing TPS content resulted in reduction in tensile strength, reduction in compression strength and increase in stiffness. The findings of this research provide valuable insights to plastic recycling industries and researchers regarding the utilization of recycled HDP

关键词： Additive Manufacturing (AM) Fused Filament Fabrication (FFF) High Density Polyethylene (HDPE) Thermoplastic Starch (TPS) bio-composite

The Thermal and Crystallization Studies of Luffa Fiber Reinforced Poly Lactic Acid composites

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Open Journal of composite Materials 2016年第1期6卷 1-7页

作者： Chhatrapati Parida Sarat Kumar Dash Pinaki Chaterjee Department of Physics Orissa University of Agriculture and Technology Bhubaneswar India Department of Education in Science and Mathematics National Council of Educational Research and Training Bhubaneswar India Laboratory for Advanced Research in Polymeric Materials (LARPM) CIPET Bhubaneswar India

Poly lactic acid (PLA)—chemically treated fiber of Luffa cylindrica (LC) composites were fabricated by micro-compounding followed by injection molding method. Before reinforcement, LC fibers were exposed to chemical treatment like alkali treatment, bleaching and acid hydrolysis. The chemically treated LC fibers were then modified with Ca salts to explore their uses in bio medical industries. Thermal stability of chemically extracted cellulose fibers of LC and PLA composites reinforced with 2 wt%, 5 wt% and 10 wt% LC fibers were studied by thermo gravimetric analysis (TGA) in the temperature range from 30℃ to 700℃. Better interfacial bonding between fiber and matrix was evidenced by increased thermal stability of composites due to incorporation of fiber. Crystallization and melting behavior of PLA composites were studied in the temperature range from 30℃ to 170℃ at heating rate of 10°/minute. The crystallization temperature and crystallization enthalpy increased up to 2 wt% of LC fiber content and gradually decreased with further increase of fiber content in the composites. Double melting peaks were observed for all composite samples and possible explanations were suggested on the basis of different crystalline structure of PLA and melt crystallization phenomena.

关键词： bio-composite Crystallization Nucleation Multiple Melting