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First binary mixture Ionic Liquids Containing EMIMBr and IM

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Chinese Chemical Letters 2003年第6期14卷 634-636页

作者： Li Yi DAI Chun Yan HUA Sheng Rong YE Yong Kui SHAN Ming Yuan HE Center for the Chemistry of Ionic Liquid East China Normal UniversityShanghai 200062

A new series of binary mixture ionic liquids comprising 1-ethyl-3-methylimidozalium bromide (EMIMBr) and imidazole (IM) have been synthesized. The melting points of the ionic liquids vary with the different content of IM while they still keep satisfactory conductivity and viscosity. According to the analysis of its phase diagram, the eutectic point is about 16.5C with the mass percentage of IM 29%.

关键词： Ionic liquid binary mixture phase diagram.

Investigation of the segregation of a binary particle mixture in a square circulating fluidized bed with air staging

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Particuology 2019年第6期17卷 70-76页

作者： Mingkun Du Shuai Wang Guangdong Institute of Special Equipment Inspection and Research Zhuhai Inspection InstituteZhuhai 519002China School of Energy Science and Engineering Harbin Institute of TechnologyHarbin 150001China

To further understand the segregation characteristics of a binary particle mixture in a riser,the flow behaviors of particles with different sizes were experimentally and numerically investigated in a cold square circulating fluidized *** impact of the gas velocity,solid circulation rate,initial coarse particle fraction,and air staging on the coarse particle fraction and axial pressure drop were *** experimental results show that air staging can significantly promote the pressure drop of a binary mixture at the bottom of the bed compared with that of monosized ***,the segregation of the binary mixture at the bottom is *** was also found that there was clear radial segregation owing to a higher coarse particle fraction near the wall compared with the bed's center and its corner.

关键词： Circulating fluidized bed binary mixture Segregation Air staging

Boosting kinetic separation of ethylene and ethane on microporous materials via crystal size control

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Chinese Journal of Chemical Engineering 2024年第1期65卷 85-91页

作者： Yixuan Ma Cong Yu Lifeng Yang Rimin You Yawen Bo Qihan Gong Huabin Xing Xili Cui Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological EngineeringZhejiang UniversityHangzhou 310012China Fundamental Science&Advanced Technology Lab PetroChina Petrochemical Research InstituteChina National Petroleum CorporationBeijing 102200China ZJU-Hangzhou Global Scientific and Technological Innovation Center Zhejiang UniversityHangzhou 311200China Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering Hangzhou 310027China

The adsorptive separation of C_(2)H_(4)and C_(2)H_(6),as an alternative to distillation units consuming high energy,is a promising yet challenging *** great similarity in the molecular size of C_(2)H_(4)and C_(2)H_(6)brings challenges to the regulation of adsorbents to realize efficient dynamic ***,we reported the enhancement of the kinetic separation of C_(2)H_(4)/C_(2)H_(6)by controlling the crystal size of ZnAtzPO_(4)(Atz=3-amino-1,2,4-triazole)to amplify the diffusion difference of C_(2)H_(4)and C_(2)H_(6).Through adjusting the synthesis temperature,reactant concentration,and ligands/metal ions molar ratio,ZnAtzPO4 crystals with different sizes were *** single-component kinetic adsorption tests and binary-component dynamic breakthrough experiments confirmed the enhancement of the dynamic separation of C_(2)H_(4)/C_(2)H_(6)with the increase in the crystal size of ZnAtzPO_(4).The separation selectivity of C_(2)H_(4)/C_(2)H_(6)increased from 1.3 to 98.5 with the increase in the crystal size of ZnAtzPO_(4).This work demonstrated the role of morphology and size control of adsorbent crystals in the improvement of the C_(2)H_(4)/C_(2)H_(6)kinetic separation performance.

关键词： Adsorption Adsorbent Ethylene binary mixture Crystal size control Kinetic separation

A model for predicting the segregation directions of binary Geldart B particle mixtures in bubbling fluidized beds

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Particuology 2024年第7期90卷 340-349页

作者： Chenmin Liu Yuemin Zhao Yanjiao Li Yuqing Feng Chenlong Duan Chenyang Zhou Liang Dong Key Laboratory of Coal Processing and Efficient Utilization Ministry of EducationChina University of Mining and TechnologyXuzhou221116China School of Chemical Engineering and Technology China University of Mining and TechnologyXuzhou221116China Mineral Resources Business Unit CSIROClaytonVIC 3169Australia

In gas fluidization processes involving different types of particles,the mixing or segregation behavior of the solid mixture is crucial to the overall outcome of the *** study develops a model to predict the segregation directions of binary mixtures of Geldart B particles with density and size differences in bubbling fluidized *** proposed model was established by combining the particle segregation model,a previous particle segregation model,with a derived bed voidage equation of the bubbling fluidization based on the two-phase *** model was then analyzed with different function graphs of the model equations under various *** results indicated that an increase in gas velocity or volume fraction of larger particles would strengthen size segregation,causing the larger and less dense components to *** validate the model,42 sets of data collected from 6 independent literature sources were compared with the predictions of the *** the gas velocities were below 3.2 times the minimum gas velocity,the predictions were consistent with experimental *** study has shed new light on the mechanisms of particle segregation in binary fluidized systems and provides a theoretical foundation for designing and manipulating gas-solid fluidized reactors.

关键词： Particle segregation binary mixture Bubbling fluidization Geldart B particles Two-phase theory

Modeling of Leachate Propagation in a Municipal Solid Waste Landfill Foundation

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Fluid Dynamics & Materials Processing 2024年第6期20卷 1407-1424页

作者： Nadezhda Zubova Andrey Ivantsov Institute of Continuous Media Mechanics of the Ural Branch Russian Academy of SciencePerm614013Russia

The study deals with the numerical modeling of leachate distribution in the porous medium located under a municipal solid waste disposal landfill(MSWLF).The considered three-layer system is based on geological data obtained from field *** simplicity,the problem is investigated by assuming a two-component ***,the heat produced by landfills due to biological and chemical processes and the thermal diffusion mechanism contributing to pollution transport are taken into *** numerical modeling of the propagation of leachate in the considered layered porous medium is implemented for parameters corresponding to natural soil and for the case where disruption of the porous medium structure is due to cracks formation or *** latter is accompanied by an increase in rock *** this case,the emergence of multi-vortex flow in the layer of high permeability is observed to substantially influence the bottom layers and cause intensification of the leachate *** effects should be taken into account when estimating the parameters and properties of materials required for the construction of solid waste disposal facilities.

关键词： Three-layer porous medium binary mixture diffusion thermal diffusion

CFD-DEM modelling of mixing and segregation of binary mixtures of ellipsoidal particles in liquid fluidizations

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Journal of Hydrodynamics 2019年第6期31卷 1190-1203页

作者： Esmaeil Abbaszadeh Molaei Aibing Yu Zongyan Zhou Laboratory for Simulation and Modelling of Particulate Systems Department of Chemical EngineeringMonash UniversityClaytonVic 3800Australia

Solid-liquid fluidized beds of binary mixtures are widely used in many *** segregation may occur as particles can differ in size,density,or *** studies have been conducted in the past to understand the effects of particlesize and density on the mixing and segregation,but the effect of particle shape has not been well ***,in the present work,CFD-DEM approach is employed to perform a numerical analysis of the effect of particle shape on the particle mixing and segregation phenomenon in liquid fluidization *** particle shapes from oblate to prolate are produced by varying aspect ratio of ellipsoids from 0.25 to 3,and eight binary mixtures of spheres and ellipsoids are *** results show that when oblate or prolate particles are added to spheres,the segregation takes *** segregation degree increases with particle aspect ratio diverging from 1.0 and also liquid superficial *** relationship of mixing index with aspect ratio under different liquid velocities is established,and a detailed explanation is *** is revealed that increasing the projected area and hence the drag force results in the separation of ellipsoidal particles from spheres.

关键词： Mixing segregation binary mixture ellipsoids liquid fluidization CFD-DEM

Effects of volumetric fraction and included angle of composite particles on the discharge of binary mixtures in hoppers

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Particuology 2020年第4期18卷 80-90页

作者： Liange Ge Nan Gui Xingtuan Yang Jiyuan Tu Shengyao Jiang Institute of Nuclear and New Energy Technology Collaborative Innovation Center of Advanced Nuclear Energy TechnologyKey Laboratory of Advanced Reactor Engineering and SafetyMinistry of EducationTsinghua UniversityBeijing 100084China School of Engineering RMIT UniversityMelbourneVIC 3083Australia

The discharge behavior of particles is important in many industrial applications,such as in the core of a pebble bed reactor,which uses a hopper bed filled with many large *** this work,a mixture composed of two particle types,freely discharged from a pebble bed,is simulated using the discreteelement *** is a spherical pebble of diameter equal to that of the fuel pebble of the *** other is a composite particle comprising three spherical pebbles bonded *** included angleαof the three pebbles characterized the particle conformation,which may affect the discharge behavior of the *** effects of volume fraction of the multi-sphere x(equivalent to the number fraction)on the discharge are also *** patterns,number flow rate,discharge velocity,and mean force of the mixture are computed to help in revealing discharge *** results show that increasing eitherαor x reduces the discharge flow *** and correlations give a quantitative evaluation of the independent effects ofαand *** analysis of velocity and force explains the mechanism relevant to the main influencing factorsαand *** results are helpful in gaining a better understanding of the discharge feature of binary mixtures and in providing a quantitative evaluation of the discharge behavior of the reactor core,especially adverse failure conditions.

关键词： Pebble flow Particle flow Discharge flow Hopper bed binary mixture Discrete element method

Joint effects of heavy metal binary mixtures on seed germination,root and shoot growth,bacterial bioluminescence,and gene mutation

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Journal of Environmental Sciences 2013年第5期25卷 889-894页

作者： In Chul Kong Department of Environmental Engineering Yeungnam UniversityKyungbuk 712-749Korea

This investigation was to assess the joint effects of metal binary mixtures on seed germination,root and shoot growth,bacterial bioluminescence,and gene mutation based on the one toxic unit（1 TU）*** sensitivities and orders of toxicity of metal mixtures were observed among the *** general,mostly additive or antagonistic effects were observed,while almost no synergistic effects by the binary metal mixtures in all ***,the combined effects of heavy metals in the different bioassays were difficult to generalize since they were dependent on both chemical type and the organism used in each ***, these results indicate that a battery of bioassays with mixture chemicals as opposed to just a single assay with single metal is a better strategy for the bioassessment of environmental pollutants.

关键词： binary mixture bioluminescence heavy metal revertant mutation seed germination toxicity

Densities, Ultrasonic Speeds, Viscosities and Refractive Indices of binary mixtures of Benzene with Benzyl Alcohol,Benzonitrile, Benzoyl Chloride and Chlorobenzene at 303.15 K

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Chinese Journal of Chemistry 2005年第4期23卷 377-385页

作者： ALI,A. PANDEY,J.D. SONI,N.K. NAIN,A.K. LAL,B. CHAND,D. DepartmentofChemistry JamiaMilliaIslamia(CentralUniversity)NewDelhi110025India DepartmentofChemistry UniversityofAllahabadAllahabad211002U.P.India

Densities, ρ, ultrasonic speeds, u , viscosities, η , and refractive indices, n , of pure benzene, benzyl alcohol (BA), benzonitrile (BN), benzoyl chloride (BC), chlorobenzene (CB) and their thirty six binary mixtures, with benzene as common component, were measured at 303.15 K over the entire mole fraction range. From these experimental data the values of deviations in ultrasonic speed, Δ u , isentropic compressibility, Δk s , excess acoustic impedance, Z E , deviation in viscosity, Δη, and excess Gibbs free energy of activation of viscous flow, G *E , and partial molar isentropic compressibility, of BA, BN, BC and CB in benzene were computed. The variation of these derived functions with composition of the mixtures suggested the increased cohesion (molecular order) in the solution and that interaction (A‐B)>(A‐A) or (B‐B). Moreover, theoretical prediction of ultrasonic speed, viscosity and refractive index of all the four binary mixtures was made on the basis of empirical and semi‐empirical relations by using the experimental values of the pure components. Comparison of theoretical results with the experimental values was made in order to assess the suitability of these relations in reproducing the experimental values of u , η and n . Also, molecular radii of pure liquids and the average molecular radii of binary mixtures were evaluated using the corresponding refractive indices of pure liquids and binary mixtures. The average molecular radii of binary mixtures were found to be additive with respect to mole fraction of the pure component.

关键词： binary mixture excess function density ultrasonic speed viscosity refractive index