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Water gas shift activity of Co-Mo/MgO-Al_2O_3 catalysts presulfided with ammonium sulfide

Journal of Natural Gas Chemistry 2010年第1期19卷 61-66页

作者： Yixin Lian, Huifang Wang, Weiping Fang, Yiquan Yang Department of Chemistry, College of Chemistry and Chemical Engineering, National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, Xiamen University, Xiamen 361005, Fujian, China Department of Chemistry College of Chemistry and Chemical Engineering National Engineering Laboratory for Green Chemical Productions of Alcohols Ethers and Esters Xiamen University Xiamen 361005 Fujian China

Co-Mo/MgO-Al2O3 catalyst was presulfided with ammonium sulfide in aqueous solution and activated with synthesis gas for water gas shift reaction. The assay results indicate that the presulfided Co-Mo/MgO-Al2O3 catalyst exhibits an excellent catalytic activity and stability. XRD and EPR characterization results show that the O-S exchange might occur during the impregnation, leading to the formation of （NH4）2MoS4 （or （NH4）zMoxSy） precursor, which was then thermally decomposed and reduced to MoS2. The higher catalytic performance is attributed to an optimization formation of active Co-Mo sulfides, consisting of well dispersed MoS2 and Co-Mo-S phase due to the redispersion of Co sulfide particles over the edges of newly formed MoS2 crystallites.

关键词： Co-Mo-based catalyst ammonium sulfide presulfidation water-gas shift

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Stabilizing the MAPbI3 perovksite via the in-situ formed lead sulfide layer for efficient and robust solar cells

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Journal of Energy Chemistry 2020年第8期29卷 62-65,I0003页

作者： Lujia Xie Taiyang Zhang Yixin Zhao China-UK Low Carbon College Shanghai Jiao Tong University3 Yinlian Rd.Shanghai 201306China School of Environmental Science and Engineering Shanghai Jiao Tong University800 Dongchuan Rd.Shanghai 200240China

Surface passivation via post-treatment with organic reagents is a popular strategy to improve the stability and efficiency of perovskite solar cell. However, organic passivation still suffers from the weak bonding between organic chemicals and perovskite layers. Here we reported a facile inorganic layer passivating method containing strong Pb–S bonding by using ammonium sulfide treatment. A compact PbS_x layer was in-situ formed on the top surface of the perovskite film, which could passivate and protect the perovskite surface to enhance the performance and stability. Our novel inorganic passivation layer strategy demonstrates great potential for the development of high efficiency hybrid and robust perovskite optoelectronics.

关键词： Inorganic surface passivation MAPbI3 ammonium sulfide Perovskite solar cells

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