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Development of aluminum-doped ZnO films for a-Si:H/μc-Si:H solar cell applications

Journal of Semiconductors 2013年第6期34卷 32-37页

作者：雷志芳陈光羽谷士斌代玲玲杨荣孟原郭铁李立伟 ENN Solar Energy Co. Ltd.

This study deals with the optimization of direct current（DC） sputtered aluminum-doped zinc oxide （AZO） thin films and their incorporation into a-Si：H/μc-Si：H tandem junction thin film solar cells aiming for high conversion efficiency.Electrical and optical properties of AZO films,i.***.mobility,carrier density,resistivity, and transmittance,were comprehensively characterized and analyzed by varying sputtering deposition conditions, including chamber pressure,substrate temperature,and sputtering power.The correlations between sputtering processes and AZO thin film properties were first investigated.Then,the AZO films were textured by diluted hydrochloric acid wet etching.Through optimization of deposition and texturing processes,AZO films yield excellent electrical and optical properties with a high transmittance above 81%over the 380-1100 nm wavelength range,lowsheet resistance of 11Ω/□and high haze ratio of 41.3%.In preliminary experiments,the AZO films were applied to a-Si：H/μc-Si：H tandem thin film solar cells as front contact electrodes,resulting in an initial conversion efficiency of 12.5%with good current matching between subcells.

关键词： aluminum-doped zinc oxide magnetron sputtering tandem silicon thin film solar cell

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Highly stable Al-doped ZnO by ligand-free synthesis as general thickness-insensitive interlayers for organic solar cells

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Science China Chemistry 2018年第1期61卷 127-134页

作者： Yilin Wang Zhongyou Peng Shuqin Xiao Jia Yang Huanyu Zhou Liqiang Huang Lulu Sun Yinhua Zhou Licheng Tan Yiwang Chen College of Chemistry Nanchang University Jiangxi Provincial Key Laboratory of New Energy Chemistry Institute of Polymers Nanchang University Wuhan National Laboratory for Optoelectronics School of Optical and Electronic Information Huazhong University of Science and Technology

Highly conductive and dispersible Al-doped ZnO(AZO) nanoparticles(NPs) have been successfully prepared by ligand-free colloidal synthesis at low temperature and stabilization by surfactant-aid including ethanolamine(EA), ethylenediamine(EDA),diethylenetriamine(DETA) and triethylenetetramine(TETA). Due to the strong intermolecular hydrogen-bonding interactions between AZO NPs and the amino groups from surfactants, the inevitable aggregation was suppressed and the surface defect sites were passivated obviously. The existence of electron transfer from the nitrogen of the amino groups to the zinc of AZO,led to a dramatic increase in electrical conductivity. A homogeneous current intensity value up to ~2200 pA for AZO tread by DETA was characterized by conductive atomic force microscopy(C-AFM), which was more superior than that of the reported sol-gel synthesized AZO with the assistance of EA surfactant(refer to 170.7 pA). Furthermore, non-fullerenes solar cells based on PBDB-T:ITIC with AZO-DETA(80 nm) yielded a best device efficiency of 10.7% and kept up prominent PCE exceeding 10%even with more thicker interlayer(95 nm).

关键词： aluminum-doped zinc oxide organic solar cells conductivity dispersibility nanoparticles

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Lossy mode resonance-based uniform core tapered fiber optic sensor for sensitivity enhancement

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Communications in Theoretical Physics 2020年第9期72卷 104-110页

作者： Vikas Keshav Walia R K Verma Department of Physics Central University of RajasthanNH-8 BandarsindriAjmer-305817RajasthanIndia Department of Physics DAV UniversityJalandhar-144012PunjabIndia

A lossy mode resonance(LMR)-supported fiber optic sensor in which a uniform fiber core is placed among two identical tapered regions, is investigated numerically. Indium tin oxide(ITO)and aluminum-doped zinc oxide(AZO) are considered as LMR active materials used to excite several lossy modes and gold and silver are used as surface plasmon resonance(SPR) active materials. In this probe design, a central uniform core coated with ITO/AZO is the active sensing region, whereas tapered regions are meant for bringing the incident angle close to the critical angle. The sensitivity of the present fiber optic bio-sensor is evaluated for first two LMRs utilizing both ITO and AZO separately, along with its variation with the taper ratio(TR). For ITO, the maximum sensitivity values are observed to be 18.425 μm RIU^(-1)(refractive index unit)and 0.825 μm RIU^(-1), corresponding to the first and second LMRs, respectively, at a TR of 1.6 and for AZO, equivalent values are 0.79 μm RIU^(-1) and 0.35 μm RIU^(-1), respectively, at a TR of2.0. The results illustrate that the first LMR is more sensitive than the second LMR and the ITOcoated probe possesses greater sensitivity than the AZO-coated probe for both LMRs. Similarly,for the fiber optic SPR sensor, the maximum value of sensitivity is 5.6425 μm RIU^(-1), in the case of gold and 5.0615 μm RIU^(-1) in the case of silver, at a TR of 1.6. Hence, the result shows that the sensor with the present fiber optic probe design has around a 3-fold enhancement in sensitivity compared with conventional SPR sensors. This study will have applications in many sensing schemes where the requirement of large sensitivity is vital.

关键词： fiber optic sensors lossy modes surface plasmons indium tin oxide aluminum-doped zinc oxide sensitivity

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