检索结果-南通市图书馆

Effects of Flexible Conjugation-Break Spacers of Non-Conjugated polymer Acceptors on Photovoltaic and Mechanical Properties of all-polymer solar cells

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Nano-Micro Letters 2022年第10期14卷 164-177页

作者： Qiaonan Chen Yung Hee Han Leandro R.Franco Cleber F.N.Marchiori Zewdneh Genene CMoyses Araujo Jin-Woo Lee Tan Ngoc-Lan Phan Jingnan Wu Donghong Yu Dong Jun Kim Taek-Soo Kim Lintao Hou Bumjoon J.Kim Ergang Wang Siyuan Laboratory Guangzhou Key Laboratory of Vacuum Coating Technologies and New Energy MaterialsDepartment of PhysicsJinan UniversityGuangzhou 510632People’s Republic of China Department of Chemistry and Chemical Engineering Chalmers University of TechnologySE-41296GöteborgSweden Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology(KAIST)Daejeon 34141Republic of Korea Department of Engineering and Physics Karlstad University65188 KarlstadSweden Department of Chemistry and Bioscience Aalborg University9220 AalborgDenmark Department of Mechanical Engineering Korea Advanced Institute of Science and Technology(KAIST)Daejeon 34141Republic of Korea Materials Theory Division Department of Physics and AstronomyUppsala University75120 UppsalaSweden Sino-Danish Center for Education and Research 8000 AarhusDenmark School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001People’s Republic of China

all-polymer solar cells(all-PSCs)possess attractive merits including superior thermal stability and mechanical flexibility for large-area roll-to-roll processing.Introducing flexible conjugation-break spacers(FCBSs)into backbones of polymer donor(P_(D))or polymer acceptor(P_(A))has been demonstrated as an efficient approach to enhance both the photovoltaic(PV)and mechanical properties of the all-PSCs.However,length dependency of FCBS on certain all-PSC related properties has not been systematically explored.In this regard,we report a series of new non-conjugated P_(A)s by incorporating FCBS with various lengths(2,4,and 8 carbon atoms in thioalkyl segments).Unlike com-mon studies on so-called side-chain engineering,where longer side chains would lead to better solubility of those resulting polymers,in this work,we observe that the solubilities and the resulting photovoltaic/mechanical properties are optimized by a proper FCBS length(i.e.,C2)in P_(A) named PYTS-C2.Its all-PSC achieves a high efficiency of 11.37%,and excellent mechanical robustness with a crack onset strain of 12.39%,significantly superior to those of the other P_(A)s.These results firstly demonstrate the effects of FCBS lengths on the PV performance and mechanical properties of the all-PSCs,providing an effective strategy to fine-tune the structures of P_(A)s for highly efficient and mechanically robust PSCs.

关键词： all-polymer solar cells Flexible conjugation-break spacers Mechanical robustness polymer acceptors Stretchability

Low-cost polymer acceptors with noncovalently fused-ring backbones for efficient all-polymer solar cells

在线全文

学校读者我要写书评

暂无评论

Science China Chemistry 2022年第5期65卷 926-933页

作者： Xiaobin Gu Yanan Wei Xingzheng Liu Na Yu Laiyang Li Ziyang Han Jinhua Gao Congqi Li Zhixiang Wei Zheng Tang Xin Zhang Hui Huang College of Materials Science and Opto-Electronic Technology Center of Materials Science and Optoelectronics EngineeringCAS Center for Excellence in Topological Quantum ComputationCAS Key Laboratory of Vacuum PhysicsUniversity of Chinese Academy of SciencesBeijing 100049China Center for Advanced Low-dimension Materials State Key Laboratory for Modification of Chemical Fibers and Polymer MaterialsCollege of Materials Science and EngineeringDonghua UniversityShanghai 201620China CAS Key Laboratory of Nanosystem and Hierarchical Fabrication CAS Center for Excellence in NanoscienceNational Center for Nanoscience and TechnologyBeijing 100190China

The polymerization of fused-ring acceptors(FRAs) to afford their corresponding polymeric acceptors for high-performance all-polymer solar cells(all-PSCs) has achieved remarkable progress in the past few years.However,due to the high degree of synthetic complexity for the monomer,the high-cost of these polymeric acceptors may limit their commercial applications.Thus,it is urgent to develop inexpensive and high-performance polymeric acceptors for all-PSCs.Herein,two novel polymeric acceptors(PBTzO and PBTzO-2F) have been designed and synthesized by copolymerization of noncovalently fused ring acceptors(NFRAs),which were employed in all-PSCs for the first time.Upon introducing the “noncovalently conformational locks(NoCLs)” in the backbone and selective fluorination of the end-group,photophysical and electrical properties,and solidstate packing properties of the NFRAs have been rationally tuned.As a result,the PBDB-T:PBTzO-2F based devices presented an excellent power conversion efficiency(PCE) of 11.04%,much higher than that of PBTzO based ones due to the increased charge generation and extraction,improved hole transfer and carrier mobilities,and reduced energy loss.More importantly,PBTzO-2F exhibited a much lower synthetic complexity(SC) index and higher figure-of-merit(FOM) values than the high-performance fused-ring acceptor based polymer acceptors(FRA-PAs) due to the simpler structures and more effective synthesis.This contribution provided a novel idea to achieve low-cost and high-performance all-PSCs.

关键词： all-polymer solar cells low-cost polymer acceptors noncovalently fused-ring backbones figure-of-merit values

Printable and stable all-polymer solar cells based on non-conjugated polymer acceptors with excellent mechanical robustness

在线全文

学校读者我要写书评

暂无评论

Science China Chemistry 2022年第1期65卷 182-189页

作者： Dong Chen Siqi Liu Xiaotian Hu Feiyan Wu Jiabin Liu Kangkang Zhou Long Ye Lie Chen Yiwang Chen College of Chemistry/Institute of polymers and Energy Chemistry(IPEC) Nanchang UniversityNanchang 330031China Institute of Advanced Scientific Research(iASR) Key Laboratory of Functional Organic Small Molecules for Ministry of EducationJiangxi Normal UniversityNanchang 330022China Tianjin Key Laboratory of Molecular Optoelectronic Science Tianjin UniversityCollaborative Innovation Center of Chemical Science and Engineering(Tianjin)Tianjin 300072China

all-polymer solar cells(all-PSCs)trigger enormous commercial applications,and great progress has been made in recent years.However,from small-area devices to large-area modules,the poor adaption of the materials for printing methods and the large efficiency loss are still great challenges.Herein,three novel non-conjugated polymer acceptors(PTH-Y,PTClm-Yand PTClo-Y)are developed for all-PSCs.It can be found that non-conjugated polymer acceptors can effectively minimize the technique and efficiency gaps between small-area spin-coating and large-area blade-printing method,which can facilitate the preparation of large-area flexible device.By directly inheriting the spin-coating condition,the blade-coating processed device based on PTCloY achieves an impressive power conversion efficiency(PCE)of 12.42%,comparable to the spin-coating processed one(12.74%).Such a non-conjugated polymer system also can well tolerate large-scale preparation and flexible substrate.Notable PCE of 11.94%for large-area rigid device and 11.56%for large-area flexible device are obtained,which is the highest value for large-area flexible all-PSCs fabricated by blade-coating.In addition,the non-conjugated PTClo-Y-based devices show excellent thermal stability and mechanical robustness.These results demonstrate that the non-conjugated polymer acceptors are potential candidates for the fabrication of highly-efficient,large-area and robust flexible all-PSCs by printing methods.

关键词： all-polymer solar cells non-conjugated polymer acceptor lager-area device printing mechanical robustness

Advances in Green-Solvent-Processable all-polymer solar cells

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of polymer Science 2022年第8期40卷 846-860,I0006页

作者： Qingqing Bai Huiliang Sun Xugang Guo Li Niu Center for Advanced Analytical Science School of Chemistry and Chemical EngineeringGuangzhou UniversityGuangzhou510006China Department of Materials Science and Engineering Southern University of Science and TechnologyShenzhen518055China Institute of polymer Optoelectronic Materials and Devices State Key Laboratory of Luminescent Materials and DevicesSouth China University of TechnologyGuangzhou510640China

all-polymer solar cells(all-PSCs)have significantly improved long-term stability and mechanical stretchability.The power conversion efficiency(PCE)of all-PSCs has been rapidly improved from∼1%to now over∼17%,driven by rational molecular design,blend morphology optimization,and device engineering.However,most all-PSCs are generally processed with halogenated solvents,hazardous for human health and the global environment.Achieving high-performance all-PSCs with halogen-free solvent processing remains a challenge.This feature article presents recent advances in green-solvent-processable all-PSCs from the material design and morphological control perspective,and further reviews progress in using more environmentally friendly solvents(i.e.,water or alcohol)to achieve genuinely sustainable and environmentally friendly manufacturing all-PSCs.Finally,we provide an outlook on the challenges and opportunities for large-scale manufacturing of green-solvent-processable all-PSCs.

关键词： all-polymer solar cells Green solvent Molecular design Morphology control

polymerizing Ladder-type Heteroheptacene-Cored Small-Molecule Acceptors for Efficient all-polymer solar cells

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of polymer Science 2023年第7期41卷 1018-1026页

作者： Peng Wang Yu-Hang Zhu Hong-Xin Tao Yun-Long Ma Dong-Dong Cai Qi-Sheng Tu Ruo-Chuan Liao Qing-Dong Zheng State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou350002China School of Physical Science and Technology ShanghaiTech UniversityShanghai201210China State Key Laboratory of Coordination Chemistry College of Engineering and Applied SciencesNanjing UniversityNanjing210023China

One important subject in the field of all-polymer solar cells (all-PSCs) is the exploration of electron-deficient building blocks with optimized physicochemical properties to promote the performance of polymer acceptors. Here, two ladder-type heteroheptacene-containing small-molecule acceptors with branched 2-octyldodecyl or 2-hexyldecyl side-chains are synthesized and polymerized with the thiophene co-monomer to afford polymer acceptors (PW-OD and PW-HD) with strong near-infrared absorption. Experimental results reveal that the alkyl chain length has a large impact on the molecular packing behavior of the resulting polymers, which in turn affects their light-absorbing and charge transport properties, and thus the photovoltaic performance of the final devices. When blended with the polymer donor PM6, PW-HD-based all-PSCs deliver a higher power conversion efficiency (PCE) of 9.12% compared to the PCE of 6.47% for the PW-OD-based all-PSCs, mainly due to its more ordered inter-chain packing and more favorable blend morphology. This work provides a promising building block for the development of high-performance narrow-bandgap polymer acceptors and highlights the importance of side-chain substitution in optimizing the photovoltaic performance of polymer acceptors.

关键词： all-polymer solar cells polymer acceptors Ladder-type heteroheptacene Power conversion efficiency

Chlorinated polymerized small molecule acceptor enabling ternary all-polymer solar cells with over 16.6% efficiency

在线全文

学校读者我要写书评

暂无评论

Science China Chemistry 2022年第5期65卷 954-963页

作者： Ke Hu Jiaqi Du Can Zhu Wenbin Lai Jing Li Jingming Xin Wei Ma Zhanjun Zhang Jinyuan Zhang Lei Meng Yongfang Li School of Chemical Science University of Chinese Academy of SciencesBeijing 100049China Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Organic SolidsInstitute of ChemistryChinese Academy of SciencesBeijing 100190China Key Laboratory of Photochemical Conversion and Optoelectronic Materials Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China State Key Laboratory for Mechanical Behavior of Materials Xi’an Jiaotong UniversityXi’an 710049China Laboratory of Advanced Optoelectronic Materials Suzhou Key Laboratory of Novel Semiconductor-optoelectronics Materials and DevicesCollege of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123China

Recently,all-polymer solar cells(all-PSCs) based on polymerized small molecule acceptors(PSMAs) have achieved significant progress.Ternary blending has proven to be an effective strategy to further boost the power conversion efficiency(PCE) of the all-PSCs.Herein,a new A-DA′D-A small-molecule acceptor-based PSMA(named as PYCl-T) was designed and synthesized,which possesses similar polymer backbone with the widely used PY-IT,but with chlorine substitution on the A-end groups in the A-DA′D-A structure.PYCl-T was then employed as the third component into the PM6:PY-IT system and the ternary all-PSCs based on PM6:PY-IT:PYCl-T demonstrated a high PCE of 16.62%(certified value of 16.3%).Moreover,the PCE of 15.52% was realized in the enlarged ternary all-PSCs with effective area of 1 cm^(2),indicating the great potential in large-scale applications.Moreover,the optimized ternary blend films of PM6:PY-IT:PYCl-T show excellent thermal stability at 150 ℃.This work demonstrates that the utilization of a ternary blend system involving two well-compatible PSMA polymer acceptors is an effective strategy to boost the performance of the all-PSCs.

关键词： all-polymer solar cells polymerized small molecular acceptors chlorine substitution ternary all polymer solar cells stability

15%Efficiency all-polymer solar cells Based on a polymer Acceptor Containing B←N Unit

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of polymer Science 2022年第8期40卷 989-995,I0011页

作者： Ying-Ze Zhang Ning Wang Ying-Hui Wang Jun-Hui Miao Jun Liu Li-Xiang Wang State Key Laboratory of polymer Physics and Chemistry Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun130022China School of Applied Chemistry and Engineering University of Science and Technology of ChinaHefei230026China

The development of new polymer acceptors strongly paves the power conversion efficiency(PCE)improvement of all polymer solar cells(all-PSCs).Herein,we develop a new polymer acceptor PBN26,which is the alternating copolymer of 2,2′-((2Z,2′Z)-((12,13-bis(2-octyldodecyl)-3,9-diundecyl-12,13-dihydro-[1,2,5]thiadiazolo[3,4-e]thieno[2″,3″:4′,5′]thieno[2′,3′:4,5]pyrrolo[3,2-g]thieno[2′,3′:4,5]thieno[3,2-b]indole-2,10-diyl)bis(methanylylidene))bis(3-oxo-2,3-dihydro-1 H-indene-2,1-diylidene))dimalononitrile and B←N bridged thienylthiazole(BNTT).The optimized all-PSCs device based on PBN26 exhibits a PCE of 15.09%,which is the highest value of the all-PSCs based on B←N-based polymer acceptors at present.Moreover,we also fabricate an all-PSC module with active area of 10 cm2 by blade coating,which exhibits a PCE of 8.78%.These results prove that polymer acceptors containing B←N units are promising for all-PSC device applications.

关键词： Organic photovoltaic all-polymer solar cells polymer acceptors Boron-nitrogen coordination bond

16.3%Efficiency binary all-polymer solar cells enabled by a novel polymer acceptor with an asymmetrical selenophene-fused backbone

在线全文

学校读者我要写书评

暂无评论

Science China Chemistry 2022年第2期65卷 309-317页

作者： Huiting Fu Qunping Fan Wei Gao Jiyeon Oh Yuxiang Li Francis Lin Feng Qi Changduk Yang Tobin J.Marks Alex K.-Y.Jen Department of Materials Science and Engineering City University of Hong KongKowloon 999077Hong KongChina Department of Chemistry City University of Hong KongKowloon 999077Hong KongChina Department of Energy Engineering School of Energy and Chemical EngineeringPerovtronics Research CenterLow Dimensional Carbon Materials CenterUlsan National Institute of Science and Technology(UNIST)50 UNIST-gilUlju-gunUlsan 44919Republic of Korea Department of Materials Science and Engineering University of WashingtonSeattleWashington 98195-2120USA Department of Chemistry and the Materials Research Center Northwestern UniversityEvanstonIL60208USA Institute for Advanced Studies City University of Hong KongKowloon 999077Hong KongChina

Despite the significant progress made recently in all-polymer solar cells(all-PSCs),it is still quite challenging to achieve high open-circuit voltage(V_(oc))and short-circuit current density(J_(sc))simultaneously in order to further improve their performance.The recent strategy of using selenophene to replace thiophene on the Y6 based polymer acceptors has resulted in significantly improved J_(sc)s of the resulting all-PSCs.However,such modifications have also depressed V_(oc),which compromises the overall performance of the devices.Herein,we present the design and synthesis of a novel polymer acceptor,PYT-1S1Se,created by inserting an asymmetrical selenophene-fused framework to precisely manipulate optical absorption and electronic properties.Compared with the selenium-free analog,PYT-2S,and symmetrical selenium-fused analog,PYT-2Se,the PYT-1S1Se derived all-PSCs not only deliver optimized J_(sc)(24.1 mA cm^(−2))and V_(oc)(0.926 V)metrics,but also exhibit a relatively low energy loss of 0.502 eV.Consequently,these devices obtain a record-high power conversion efficiency(PCE)of 16.3%in binary all-PSCs.This work demonstrates an effective molecular design strategy for balancing the trade-off between V_(oc) and J_(sc) to achieve highefficiency all-PSCs.

关键词： all-polymer solar cells polymer acceptors asymmetrical selenophene-fused backbone power conversion efficiencies stability

8.30%Efficiency P3HT-based all-polymer solar cells enabled by a miscible polymer acceptor with high energy levels and efficient electron transport

在线全文

学校读者我要写书评

暂无评论

Science China Chemistry 2023年第1期66卷 216-227页

作者： Ziqi Liang Jiangting He Bin Zhao Mengyuan Gao Yu Chen Long Ye Miaomiao Li Yanhou Geng School of Materials Science and Engineering and Tianjin Key Laboratory of Molecular Optoelectronic ScienceTianjin UniversityTianjin 300072China Joint School of National University of Singapore and Tianjin University International Campus of Tianjin UniversityBinhai New CityFuzhou 350207China Collaborative Innovation Center of Chemical Science and Engineering(Tianjin) Tianjin 300072China Institute of High Energy Physics Chinese Academy of SciencesBeijing 100049China

P3HT stands out from numerous polymer donors owing to the merits of low cost and high scalability of synthesis.However,the photovoltaic performance of P3HT-based blends lags significantly behind the state-of-the-art systems,especially for all-polymer solar cells(APSCs) that generally show efficiency of around 3%–4% due to the lack of matched polymer acceptors.Herein,a polymer acceptor,named IDTBTC8-CN,was designed and synthesized with indacenodithiophene(IDT) and mono-cyano(CN)-substituted benzothiadiazole(BT-CN) as building blocks.Introducing a CN group endowed the polymer with decreased bandgap,and apparent n-type charge transport character despite the relatively high energy levels.Additionally,IDTBTC8-CN showed largely improved miscibility with P3HT,compared with that of BT-based control polymer IDTBTC8.The high miscibility between P3HT and IDTBTC8-CN as well as the amorphous aggregation behavior of IDTBTC8-CN enabled a broad manipulation room for the blend film to acquire favorable morphology.Eventually,a champion efficiency of 8.30% was achieved,in sharp contrast to that of the IDTBTC8-based system(1.21%).Such efficiency is a new record for P3HT-based APSCs reported so far.Moreover,P3HT:IDTBTC8-CN blend film also exhibited excellent mechanical robustness.This study implies the guidance of molecular design of the polymer acceptors and morphology control for P3HT-based APSCs.

关键词： all-polymer solar cells poly(3-hexylthiophene) polymer acceptors energy levels film morphology