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Liquid-liquid interfacial tension of equilibrated mixtures of ionic liquids and hydrocarbons

Science China Chemistry 2012年第8期55卷 1519-1524页

作者： RODRíGUEZ Héctor ARCE Alberto SOTO Ana Department of Chemical Engineering University of Santiago de Compostela E-15782 Santiago de Compostela Spain

Ionic liquids are possible alternative solvents for the separation of aromatic and aliphatic hydrocarbons by liquid-liquid extrac- tion. Interfacial tension is an important property to consider in the design of liquid-liquid extraction processes. In this work, the liquid-liquid interfacial tension and the mutual solubility at 25 ℃ have been measured for a series of biphasic, equilibrated mixtures of an ionic liquid and a hydrocarbon. In particular, the ionic liquids 1-alkyl-3-methylimidazolium bis（trifluorome- thanesulfonyl）imide （with the alkyl substituent being ethyl, hexyl or decyl）, 1-ethyl-3-methylimidazolium ethylsulfate, and 1-ethyl-3-methylimidazolium methanesulfonate have been selected, as well as the hydrocarbons benzene, hexane, ethylben- zene, and octane. The selected sets of ionic liquids and hydrocarbons allow the analysis of the influence of a series of effects on the interfacial tension. For example, the interfacial tension decreases with an increase in the length of the alkyl substituent chain of the cation or with an increase of the degree of charge delocalisation in the anion of the ionic liquid. Also, the interfa- cial tension with the aromatic hydrocarbons is markedly lower than that with the aliphatic hydrocarbons. A smaller effect is caused by variation of the size of the hydrocarbon. Some of the observed trends can be explained from the mutual solubility of the hydrocarbon and the ionic liquid.

关键词： ionic liquid aromatic hydrocarbon aliphatic hydrocarbon interfacial tension liquid-liquid equilibrium

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Highly selective extraction of aromatics from aliphatics by using metal chloride-based ionic liquids

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Chinese Journal of Chemical Engineering 2024年第1期65卷 222-229页

作者： Hui Yu Xiaojia Wu Chuanqi Geng Xinyu Li Chencan Du Zhiyong Zhou Zhongqi Ren State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing 100029China

The separation of aromatics from aliphatics is essential for achieving maximum exploitation of oil resources in the petrochemical *** this study,a series of metal chloride-based ionic liquids were prepared and their performances in the separation of 1,2,3,4-tetrahydronaphthalene(tetralin)/dodecane and tetralin/decalin systems were *** these ionic liquids,1-ethyl-3-methylimidazolium tetrachloroferrate([EMIM][FeCl_(4)])with the highest selectivity was used as the *** functional theory calculations showed that[EMIM][FeCl_(4)]interacted more strongly with tetralin than with dodecane and *** decomposition analysis of[EMIM][FeCl_(4)]-tetralin indicated that electrostatics and dispersion played essential roles,and induction cannot be *** van der Waals forces was a main effect in[EMIM][FeCl_(4)]-tetralin by independent gradient model *** tetralin distribution coefficient and selectivity were 0.8 and 110,respectively,with 10%(mol)tetralin in the initial tetralin/dodecane system,and 0.67 and 19.5,respectively,with 10%(mol)tetralin in the initial tetralin/decalin *** selectivity increased with decreasing alkyl chain length of the *** influence of the extraction temperature,extractant dosage,and initial concentrations of the system components on the separation performance were *** experiments showed that the regenerated[EMIM][FeCl_(4)]could be used repeatedly.

关键词： Ionic liquid Aromatic hydrocarbon aliphatic hydrocarbon Extraction

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