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Chinese Journal of Chemical Engineering 2020年第7期28卷 1911-1917页

作者： Rongzong Li Zhaoyang Li Qian Jiang Zhaoxiang Zhong Ming Zhou Weihong Xing State Key Laboratory of Materials-Oriented Chemical Engineering National Engineering Research Center for Special Separation MembraneNanjing Tech UniversityNanjing 210009China

Treatment to crystallization mother liquor containing high concentration of organic and inorganic substances is a challenge in zero liquid discharge of industrial *** precipitation coupled membrane-dispersion advanced oxidation process(MAOP)was proposed for organics degradation before salt crystallization by *** acid-MAOP treatment CODCrin mother liquor of pulping wastewater was eliminated by 55.2%from ultrahigh initial concentration up to 12,500 mg·L^-*** decolorization rate was 96.5%.Recovered salt was mainly NaCl(83.3 wt%)having whiteness 50 brighter than industrial baysalt of whiteness *** oxidation conditions were optimized as CO3=0.11 g·L^-1 and CH2O2=2.0 g·L^-1 with dispersing rate 0.53 ml·min^-1 for 100 min reaction toward acidified liquor of p H=*** has notably improved evaporation efficiency during *** of H2O2 made through membrane dispersion has eliminated hydroxyl radical"quench effect"and enhanced the degradation capacity,in particular,the breakage of carbon-chloride bonds(of both aliphatic and aromatic).As a result,the proposed coupling method has improved organic pollutant reduction so as the purity of salt from the wastewater mixture which can facilitate water and salt recycling in industry.

关键词： advanced oxidation process Crystallization mother liquor Ceramic membrane dispersion Pulping wastewater

Preparation of Co/S co-doped carbon catalysts for excellent methylene blue degradation

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 169-181页

作者： Haixu Li Haobo He Tiannan Jiang Yunfei Du Zhichen Wu Liang Xu Xinjie Wang Xiaoguang Liu Wanhua Yu Wendong Xue School of Materials Science and Engineering University of Science and Technology BeijingBeijing 100083China Beijing Jinyu Tongda Refractory Technologies Co. Ltd.Beijing 100085China

S and Co co-doped carbon catalysts were prepared via pyrolysis of MOF-71 and thiourea mixtures at 800℃at a mass ratio of MOF-71 to thiourea of 1:0.1 to effectively activate peroxymonosulfate(PMS)for methylene blue(MB)*** effects of two different mixing routes were identified on the MB degradation ***,the catalyst obtained by the alcohol solvent evaporation(MOF-AEP)mixing route could degrade 95.60%MB(50 mg/L)within 4 min(degradation rate:K=0.78 min^(-1)),which was faster than that derived from the direct grinding method(MOF-DGP,80.97%,K=0.39 min^(-1)).X-ray photoelectron spectroscopy revealed that the Co-S content of MOF-AEP(43.39at%)was less than that of MOF-DGP(54.73at%),and the proportion of C-S-C in MOF-AEP(13.56at%)was higher than that of MOF-DGP(10.67at%).Density functional theory calculations revealed that the adsorption energy of Co for PMS was -2.94 eV when sulfur was doped as C-S-C on the carbon skeleton,which was higher than that when sulfur was doped next to cobalt in the form of Co-S bond(-2.86 eV).Thus,the C-S-C sites might provide more contributions to activate PMS compared with ***,the degradation parameters,including pH and MOF-AEP dosage,were ***,radical quenching experiments and electron paramagnetic resonance(EPR)measurements revealed that ^(1)O_(2)might be the primary catalytic species,whereas·O~(2-)might be the secondary one in degrading MB.

关键词： advanced oxidation process alcohol solvent evaporation hydrogen bond S and Co co-doped carbon catalysts wastewater remediation

Manganese oxide and derivative-modified materials in advanced oxidation processes:A review of modification enhancement and activation mechanisms

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Chinese Chemical Letters 2024年第3期35卷 40-51页

作者： Si Sun Shuang Song Shuai Yang Yong-Li He Yang Shi Peng Zhou Zhao-kun Xiong Yang Liu Heng Zhang Ye Du Chuan-Shu He Bo Lai State Key Laboratory of Hydraulics and Mountain River Engineering College of Architecture and EnvironmentSichuan UniversityChengdu 610065China Sino-German Centre for Water and Health Research Sichuan UniversityChengdu 610065China Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaSichuanChengdu 610054China

Manganese oxides(MNO_(x)),as low-toxicity and high-abundance catalysts,have been demonstrated to hold great promise for application in advanced oxidation processes(AOPs).However,further application of this material is restricted due to its unsatisfactory oxidant activation ***,recently remarkable research on deep activation mechanisms and modification of MNO_(x)have been undertaken to improve its ***,modification enhancement mechanisms of MNO_(x)to efficiently degrade various organic contaminants were discussed and highlighted,including metal doping,coupling with other metal oxides,composite with carbonaceous material,and compounding with other *** activation mechanisms of different MNO_(x)and derivative-modified material(such as doped MNO_(x),metal oxide-MNO_(x)hybrids,and MNO_(x)-carbonaceous material hybrids)were summarized in great details,which was specifically categorized into both radical and non-radical *** effects of pH,inorganic ions,and natural organic matter on degradation reactions are also ***,future research directions and perspectives are presented to provide a clear interpretation on the MNO_(x)initiated AOPs.

关键词： Manganese oxide Derivative-modified materials Modification enhancement mechanisms advanced oxidation process Activation mechanism

advanced oxidation processes of decomposing dichloroacetic acid and trichloroacetic acid in water

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Journal of Chongqing University 2008年第3期7卷 171-178页

作者：汪昆平 JUNJI Hirotsuji Key Laboratory of the Three Gorges Reservoir Region's Eco-Environment Under the Ministry of Education Chongqing University advanced Technology R&D Center Mitsubishi Electric CorporationHyogo 661-8661Japan

We studied the decomposition of two haloacetic acids (HAAs),dichloroacetic acid (DCAA) and trichloroacetic acid (TCAA),in water by single oxidants ozone (O3) and ultraviolet radiation (UV) and the advanced oxidation processes (AOPs) constituted by the combinations of O3/UV,H2O2/UV,O3 /H2O2,and O3/H2O2/UV. The concentrations of HAAs were analyzed at specified time intervals to track their decomposition. Except for O3 and UV,the four combined oxidation processes remarkably enhance the decomposition of DCAA and TCAA owing to the generated very reactive hydroxyl radicals. The fastest decomposition process is O3/H2O2/UV,closely followed by O3/UV. DCAA is much easier to decompose than TCAA. The kinetics of HAA decomposition by O3/UV can be described well by a pseudo first-order reaction model under a constant initial dissolved O3 concentration and fixed UV radiation. Humic acids and HCO3-in the reaction system both decrease the decomposition rate constants for DCAA and TCAA. The amount of H2O2 accumulates in the presence of humic acids in the O3/UV process.

关键词： ozonization ultraviolet radiation ozone advanced oxidation process haloacetic acid

Effects of advanced oxidation processes on the Decomposition Properties of Organic Compounds with Different Molecular Structures in Water

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Journal of Water Resource and Protection 2016年第9期8卷 823-834页

作者： Harufumi Suzuki Shoichi Yamagiwa Sadao Araki Hideki Yamamoto Department of Chemical Energy and Environmental Engineering Faculty of Environmental and Urban Engineering Kansai University Osaka Japan

Studies to decompose persistent organic pollutants in wastewater from chemical factories by using advanced oxidation processes (AOPs) have recently been performed. oxidation reactions involving ozone and •OH radicals and cleavage caused by UV are the main decomposition reactions that occur in AOPs using ozone and UV. The mechanisms through which organic compounds are decomposed in AOPs are complicated and difficult to understand because various decomposition reactions occur simultaneously. The Total Organic Carbon (TOC) removal efficiencies achieved in several different AOPs were evaluated in this study. The TOC removal efficiencies were different for organic compounds with different chemical structures. The TOC was more effectively removed when aromatic compounds were treated using the O3-UV-TiO2 process than when using the other AOPs, and the TOC was removed more effectively by the O3-UV process than by the UV-TiO2 process. However, the TOC was removed more effectively when open-chain compounds were treated using the UV-TiO2 process than using the O3-UV process, and the UV-TiO2 and O3-UV-TiO2 processes resulted in similar TOC removal efficiencies. Therefore, it is necessary to use the O3-UV-TiO2 process to decompose aromatic compounds as quickly as possible. On the other hand, the UV-TiO2 process degraded the open-chain compounds most effectively, and the O3-UV-TiO2 process did not need to decompose open-chain compounds. Moreover, the TOC of aromatic compounds was removed more slowly than that of open-chain compounds. The TOC removal efficiency increased with decreasing the number of carbon atoms in the molecule. The TOC removal efficiencies increased in order of the organic compounds containing methyl groups, aldehyde groups and carboxyl groups. The removal of the TOC when organic compounds were treated usi

关键词： advanced oxidation process Ozone Hydroxyl Radical Decomposition Efficiency Water Treatment

CeO_(2)-Nb_(2)O_(5)photocatalysts for degradation of organic pollutants in water

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Rare Metals 2020年第3期39卷 230-240页

作者： Nathália Pereira Ferraz Andre Esteves Nogueira Francielle Candian Firmino Marcos Vanessa Aguiar Machado Rene Rojas Rocca Elisabete Moreira Assaf Yvan Jesus Olortiga Asencios Institute of Marine Science Federal University of Sao PauloSantosSP11030-100Brazil Brazilian Center for Research in Energy and Materials(CNPEM) CampinasSP13083-970Brazil Sao Carlos Institute of Chemistry University of Sao PauloSao CarlosSP13566-590Brazil

The photocatalytic properties of CeO2-Nb2O5 photocatalysts in heterogeneous photocatalysis(under ultraviolet and visible radiation)and in Fenton-like process were *** blue dye(MB)and phenol(Ph)were used as models of pollutant molecules for these reactions,and the photocatalysts were characterized by X-ray diffraction(XRD),diffuse reflectance spectroscopy(DRS),scanning electron microscopy(SEM),energy-dispersive X-ray spectroscopy(EDX)and thermally stimulated luminescence(TL).The results indicated that the addition of CeO2(0.3 wt%,1.0 wt%and 2.0 wt%)to Nb2O5 sensitized the resultant materials,increasing light absorption in the visible ***,there is a suitable formulation of CeO2-Nb2O5 photocatalysts to improve each photocatalytic *** heterogeneous photocatalysis,the addition of small CeO2 quantities to Nb2O5 was enough to improve the photocatalytic activity of CeO2-Nb2O5 photocatalysts(The best composition reported was CeO20.3 wt%.).The effectiveness of the catalyst was explained by the decrease in the number of trapping and luminescence centers in the conduction band of the material after the addition of CeO2 to Nb2O5,but a large amount of CeO2 decreased the number of trapping,luminescent and active centers to a large ***,in a Fenton-like process,the addition of CeO2 to Nb2O5 was favorable in all the proportions studied.(The best composition was 2.0 wt%CeO2.)In this case,the effectiveness was explained by the influence of the adsorption process(adsorption-triggered process),and the interactions between H2 O2 and Ce3+of the CeO2 in each photocatalyst thus formed surface peroxide species O22-,which induced the removal of the organic molecules under visible light.

关键词： advanced oxidation process Photocatalysts Nb_(2)O_(5) CeO_(2) Phenol Methylene blue

Evaluation of the technoeconomic feasibility of electrochemical hydrogen peroxide production for decentralized water treatment

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Frontiers of Environmental Science & Engineering 2021年第1期15卷 31-45页

作者： Yang Li Yixin Zhang Guangshen Xia Juhong Zhan Gang Yu Yujue Wang School of Environment State Key Joint Laboratory of Environmental Simulation and Pollution ControlBeijing Key Laboratory for Emerging Organic Contaminants ControlTsinghua UniversityBeijing 100084China

This study evaluated the feasibility of electrochemical hydrogen peroxide(H2O2)production with gas diffusion electrode(GDE)for decentralized water *** black-polytetrafluoroethylene GDEs were prepared and tested in a continuous flow electrochemical cell for H2O2 production from oxygen *** showed that because of the effective oxygen transfer in GDEs,the electrode maintained high apparent current efficiencies(ACEs,>80%)for H_(2)O_(2) production over a wide current density range of 5–400 mA/cm^(2),and H_(2)O_(2) production rates as high as~202 mg/h/cm^(2) could be ***-term stability test showed that the GDE maintained high ACEs(>85%)and low energy consumption(<10 kWh/kg H2O2)for H_(2)O_(2) production for 42 d(~1000 h).However,the ACEs then decreased to~70%in the following 4 days because water flooding of GDE pores considerably impeded oxygen transport at the late stage of the *** on an electrode lifetime of 46 days,the overall cost for H2O2 production was estimated to be~0.88$/kg H_(2)O_(2),including an electricity cost of 0.61$/kg and an electrode capital cost of 0.27$/*** a 9 cm^(2) GDE and 40 mA/cm^(2) current density,~2–4 mg/L of H2O2 could be produced on site for the electro-peroxone treatment of a 1.2 m^(3)/d groundwater flow,which considerably enhanced ibuprofen abatement compared with ozonation alone(~43%–59%vs.7%).These findings suggest that electrochemical H_(2)O_(2) production with GDEs holds great promise for the development of compact treatment technologies for decentralized water treatment at a household and community level.

关键词： advanced oxidation process Electro-peroxone Gas diffusion electrode Hydrogen peroxide Oxygen reduction

Surfactant-assisted removal of 2,4-dichlorophenol from soil by zero-valent Fe/Cu activated persulfate

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Chinese Journal of Chemical Engineering 2022年第4期35卷 447-455页

作者： Ling Xu Ji Li Wenbin Zeng Kai Liu Yibing Ma Liping Fang Chenlu Shi Faculty of Material Science and Chemistry China University of GeosciencesWuhan 430074China Guangdong Key Laboratory of Integrated Agro-environmental Pollution Control and Management Institute of Eco-environmental and Soil SciencesGuangdong Academy of SciencesGuangzhou 510650China National-Regional Joint Engineering Research Center for Soil Pollution Control and Remediation in South China Guangzhou 510650China Macao Environmental Research Institute Macao University of Science and TechnologyTaipaMacaoChina

The organic compounds contaminated soil substantially threatens the growth of plants and food *** this study,we synthesis zero-valent bimetallic Fe/Cu catalysts for the degradation of 2,4-dichlorophenol(DCP)in soils with persulfate(PS)in combination of organic surfactants and exploring the main environmental impact *** kinetic experiments show that the 5%(mass)dosage of Fe/Cu exhibits a higher degradation efficiency(86%)of DCP in soils,and the degradation efficiency of DCP increases with the increase of the initial PS *** conditions are favorable for the DCP degradation in *** importantly,the addition of Tween-80,and Triton-100 can obviously desorb DCP from the soil surface,which enhances the degradation efficiency of DCP in soils by Fe/Cu and PS reaction ***,the Quenching experiments demonstrate that SO_(4)^(-1)·and·OH are the predominant radicals for the degradation of DCP during the Fe/Cu and PS reaction system as well as non-radical also *** findings of this work provide an effective method for remediating DCP from soils.

关键词： Zero-valent iron and copper advanced oxidation process Persulfate Chlorinated organic pollutants Surfactant

Cobalt doping amount determines dominant reactive species in peroxymonosulfate activation via porous carbon catalysts co-doped by cobalt and nitrogen

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Journal of Environmental Sciences 2024年第4期138卷 212-226页

作者： Xiang Li Limeng Wu Aiqin Zhang Shaohua Wu Yan Lin Chunping Yang Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle Nanchang Hangkong UniversityNanchang 330063China Academy of Environmental and Resource Sciences School of Environmental Science and EngineeringGuangdong University of Petrochemical TechnologyMaoming 525000China College of Environmental Science and Engineering Hunan University and Key Laboratory of Environmental Biology and Pollution Control(Hunan University)Ministry of EducationChangsha 410082China

Switching the reaction routes in peroxymonosulfate(PMS)-based advanced oxidation processes have attracted much attention but remain ***,a series of Co-N/C catalysts with different compositions and structures were prepared by using bimetallic zeolitic imidazolate frameworks based on ZIF-8 and ZIF-67(x Zn/Co-ZIFs).Results show that Co doping amount could mediate the transformation of the activation pathway of PMS over CoN/*** Co doping amount was less than 10%,the constructed x Co-N/C/PMS system(x≤10%)was singlet oxygen-dominated reaction;however further increasing Co doping amount would lead to the generation and coexistence of sulfate radicals and high-valent cobalt,besides singlet ***,the nitrogen-coordinated Co(Co-NX)sites could serve as main catalytically active sites to generate singlet *** excess Co doping amount caused the formation of Co nanoparticles from which leached Co ions were responsible for the generation of sulfate radicals and high-valent *** to undoped N/C,Co doping could significantly enhance the catalytic *** 0.5%Co-N/C could achieve the optimum degradation(0.488 min^(-1))and mineralization abilities(78.4%)of sulfamethoxazole among the investigated Co-N/C catalysts,which was superior to most of previously reported *** addition,the application prospects of the two systems in different environmental scenarios(pH,inorganic anions and natural organic matter)were assessed and showed different degradation *** study provides a strategy to regulate the reactive species in PMS-based advanced oxidation process.

关键词： Peroxymonosulfate Sulfate radical Singlet oxygen Cobalt Zeolitic imidazolate framework advanced oxidation process

Boosting Peroxymonosulfate Activation via Co-Based LDH-Derived Magnetic Catalysts:A Dynamic and Static State Assessment of Efficient Radical-Assisted Electron Transfer processes

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Energy & Environmental Materials 2024年第5期7卷 301-312页

作者： Wenhan Yang Junming Xia Fanfan Shang Ge Ge Yang Bin Wang Hairui Cai Lingyun Jing Hao Zhu Shengchun Yang Chao Liang Guosheng Shao MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter School of PhysicsNational Innovation Platform(Center)for Industry-Education Integration of Energy Storage TechnologyXi'an Jiaotong UniversityXi'an 710000China State Key Laboratory of Organic Electronics and Information Displays&Institute of advanced Materials(1AM) Nanjing University of Posts&Telecommunications9 Wenyuan RoadNanjing 210023China College of Petroleum and Chemical Engineering Lanzhou University of TechnologyLanzhou 730050China Key Laboratory of Western China's Environmental Systems(Ministry of Education)and Gansu Engineering Research Center of Fine Particles Pollution Control Technology and Equipment College of Earth and Environmental SciencesLanzhou UniversityLanzhou 730000China State Center for International Cooperation on Designer Low-Carbon&Environmental Materials(CDLCEM) School of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001China

Heterogeneous catalysts promoting efficient production of reactive species and dynamically stabilized electron transfer mechanisms for peroxomonosulfates(PMS)still lack systematic ***,a more stable magnetic layered double oxides(CFLDO/N-C),was designed using self-polymerization and high temperature carbonization of *** CFLDO/N-C/PMS system effectively activated PMS to remove 99%(k=0.737 min^(-1))of tetracycline(TC)within 10 *** CFLDO/N-C/PMS system exhibited favorable resistance to inorganic anions and natural organics,as well as satisfactory suitability for multiple *** magnetic properties of the catalyst facilitated the separation of catalysts from the liquid phase,resulting in excellent reproducibility and effectively reducing the leaching of metal *** electronic bridge was constructed between cobalt(the active platform of the catalyst)and PMS,inducing PMS to break the O-O bond to generate the active *** combination of static analysis and dynamic evolution confirmed the effective adsorption of PMS on the catalyst surface as well as the strong radical-assisted electron transfer ***,we further identified the sites where the reactive species attacked the TC and evaluated the toxicity of the *** findings offer innovative insights into the rapid degradation of pollutants achieved by transition metals in SR-AOPs and its mechanistic elaboration.

关键词： advanced oxidation process degradation mechanisms electron transport layered double hydroxide reactive species