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High performance Zn-I_(2)battery with acetonitrile electrolyte working at low temperature

Nano Research 2022年第4期15卷 3170-3177页

作者： Chunlai Song Zongshuai Gong Chong Bai Fengshi Cai Zhihao Yuan Xizheng Liu School of Materials Science and Engineering Tianjin Key Laboratory of Photoelectric Materials&DevicesKey Laboratory of Display Materials and Photoelectric Devices of Ministry of EducationTianjin University of TechnologyNo.391 Binshuixi RoadTianjin 300384China

Large scale applications of metal-iodine batteries working at sub-zero degree have been challenged by the limited capacity and performance degradation.Herein,we firstly propose a Zn-I_(2)battery working at low temperature with a carbon composite material/iodine(CCM-I_(2))cathode,a Zn anode and an environmentally tolerable Zn(ClO4)2-ACN electrolyte.The CCM framework with hierarchical porous structure endows a powerful iodine-anchoring to overcome undesirable dissolution of iodine in organic electrolyte,and the Zn(ClO4)2-ACN electrolyte with low freezing point and high ionic conductivity enhances the low temperature performance.The synergies enable an efficiently reversible conversion of Zn-I_(2)battery even at-40℃.Therefore,the resultant Zn-I_(2)battery delivers a high specific capacity of 200 mAh·g^(-1),which is fairly approximate to the theoretical capacity of I_(2)(211 mAh·g^(-1))and a superior cycling stability with minimal capacity fading of 0.00043%per cycle over 7,000 times under 2C at-20℃.Furthermore,even at-40℃,this Zn-I_(2)battery still exhibits a good capacity retention of 68.7%compared to the capacity at 25℃ and a rapid capacity-recover ability with elevating temperature change.Our results distinctly indicate this Zn-I_(2)battery can be 1competent for the practical application under low temperature operation.

关键词： Zn-I_(2)battery low temperature acetonitrile electrolyte carbon composite material high performance

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A long-life and safe lithiated graphite-selenium cell with competitive gravimetric and volumetric energy densities

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Journal of Energy Chemistry 2021年第9期30卷 556-563页

作者： Xiaoqun Qi Qiang Jin Fengyi Yang Ruining Jiang Quan Sun Long Qie Yunhui Huang Institute of New Energy for Vehicles School of Materials Science and EngineeringTongji UniversityShanghai 201804China

Lithium-selenium(Li-Se) battery is a promising system with high theoretical gravimetric and volumetric energy densities, while its long-term cyclability is hard to realize, especially when a practical Se cathode with high Se content, high Se loading, and high density is employed. The main obstacles are the sluggish conversion kinetics of the dense Se cathodes and the continuous deterioration of the Li-metal anodes.Here, by introducing an acetonitrile(AN)-based electrolyte and replacing the Li electrode with a lithiated graphite, we successfully build a hybrid conversion-intercalation system using a high-content(80 wt%),decent-loading(3.0 mg cm^(-2)), and low-porosity(44%) Se cathode. The as-designed lithiated graphite||Se(LG||Se) cell demonstrated a high Se utilization(97.4%), a long cycle life(3000 cycles), and an ultrahigh average Coulombic efficiency(99.98%). The cell also works well under lean-electrolyte(2 l L mg^(-1)) condition and shows outstanding safety performance in the nail-penetrating test. The combination affords the competitive comprehensive performances, including high volumetric and gravimetric energy densities, long cycling life, and superb safety of the LG||Se cell. In addition, with a newly-designed threeelectrode pouch cell, the lithiation of the graphite anodes could be done with an in-situ lithiation process,indicating the high potential of the as-proposed LG||Se cell for the practical applications.

关键词： Conversion-intercalation acetonitrile electrolyte Se cathode Lithiated graphite Energy density

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