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Covalent Organic Framework with 3D Ordered Channel and Multi-Functional Groups Endows zn Anode with Superior Stability

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Nano-Micro Letters 2024年第4期16卷 350-363页

作者： Bin Li Pengchao Ruan Xieyu Xu Zhangxing He Xinyan Zhu Liang Pan Ziyu Peng Yangyang Liu Peng Zhou Bingan Lu Lei Dai Jiang Zhou School of Chemical Engineering North China University of Science and TechnologyTangshan 063009People’s Republic of China School of Materials Science and Engineering Central South UniversityChangsha 410083People’s Republic of China State Key Laboratory for Mechanical Behavior of Materials Xi’an Jiaotong UniversityXi’an 710049People’s Republic of China Hunan Provincial Key Defense Laboratory of High Temperature Wear‑Resisting Materials and Preparation Technology Hunan University of Science and TechnologyXiangtan 411201People’s Republic of China School of Physics and Electronics Hunan UniversityChangsha 410082People’s Republic of China

Achieving a highly robust zinc(zn)metal anode is extremely important for improving the performance of aqueous zn-ion batteries(AZIBs)for advancing“carbon neutrality”society,which is hampered by the uncontrollable growth of zn dendrite and severe side reactions including hydrogen evolution reaction,corrosion,and passivation,etc.Herein,an interlayer containing fluorinated zincophilic covalent organic framework with sulfonic acid groups(COF-S-F)is developed on zn metal(zn@COF-S-F)as the artificial solid electrolyte interface(SEI).Sulfonic acid group(-SO_(3)H)in COF-S-F can effectively ameliorate the desolvation process of hydrated zn ions,and the three-dimensional channel with fluoride group(-F)can provide interconnected channels for the favorable transport of zn ions with ion-confinement effects,endowing zn@COF-S-F with dendrite-free morphology and suppressed side reactions.Consequently,zn@COF-S-F symmetric cell can stably cycle for 1,000 h with low average hysteresis voltage(50.5 m V)at the current density of 1.5 m A cm^(-2).zn@COF-S-F|Mn O_(2)cell delivers the discharge specific capacity of 206.8 m Ah g^(-1)at the current density of 1.2 A g^(-1)after 800 cycles with high-capacity retention(87.9%).Enlightening,building artificial SEI on metallic zn surface with targeted design has been proved as the effective strategy to foster the practical application of high-performance AZIBs.

关键词： Aqueous zn ion batteries Covalent organic framework Interfacial modification zn ion flux regulation Desolvation effect

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