检索结果-南通市图书馆

Chinese Chemical Letters 2024年第4期35卷 409-413页

作者： Chaoqun Ma Yuebo Wang Ning Han Rongzhen Zhang Hui Liu Xiaofeng Sun Lingbao Xing School of Chemistry and Chemical Engineering Shandong University of TechnologyZibo 255000China Department of Materials Engineering KU LeuvenLeuven 3001Belgium

In this work, we designed and synthesized cationic carbon dots(CDs) with a size distribution of 1.6–3.7 nm, which exhibited dark blue fluorescence in the aqueous solution. Based on its excellent luminescence properties, we used it as an energy donor to construct a sequential artificial light-harvesting system(LHS) by employing the energy-matching dyes eosin Y disodium salt(EY) and sulforhodamine101(SR101), which could regulate the White light emission(Commission Internationale de l'Eclairage(CIE) coordinate:(0.30, 0.31)) with the energy transfer efficiency(ΦET) of 53.9% and 20.0%. Moreover, a single-step artificial LHS with White light emission(0.32, 0.28) can be constructed directly using CDs and dye solvent 43(SR) with ΦETand antenna effect(AE) of 48.8% and 6.5, respectively. More importantly,CDs-based artificial LHSs were firstly used in photocatalytic of α-bromoacetophenone, with a yield of90%. This work not only provides a new strategy for constructing CDs-based LHSs, but also opens up a new application for further applying the energy harvested in CDs-based LHSs to the field of the aqueous solution photocatalysis.

关键词： Carbon dots White light emission Energy transfer Antenna effect Artificial light-harvesting system Photocatalysis

Acid-induced tunable White light emission based on triphenylamine derivatives

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2021年第4期32卷 1537-1540页

作者： Xi Liu Yi Qin Junlong Zhu Xiaoli Zhao Tanyu Cheng Yanrong Jiang Haitao Sun Lin Xu Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular EngineeringEast China Normal UniversityShanghai 200062China Key Laboratory of Resource Chemistry of Ministry of Education.Shanghai Key Laboratory of Rare Earth Functional Materials.Shanghai Normal University Shanghai 200234China State Key Laboratory of Precision Spectroscopy East China Normal UniversityShanghai 200062China State Key Laboratory of Fine Chemicals Dalian University of TechnologyDalian 116024China

A series of triphe nylamine(TPA)derivatives with various substituent groups were prepared and showed different absorption and fluorescence characteristics due to the substituent effect.On account of the existence of pyridine units,these TPA derivatives exhibited acid-induced tunable multicolor fluorescence emission including White light emission.In addition,acid-induced fluorescence regulation of these compounds has been also realized in the solid state,which enable them to be successfully constructed the stimuli-responsive fluorescent films and fluorescent inks for inkjet printing.

关键词： Triphenylamine Fluorescence regulation White light emission Substituent effect Intramolecular charge transfer

White light emission of Eu^(3+)/Ag co-doped Y_2Si_2O_7

在线全文

学校读者我要写书评

暂无评论

Journal of Rare Earths 2014年第9期32卷 779-786页

作者：邓宇航宋文申董伟乐代如成王中平张增明丁泽军 Hefei National Laboratory for Physical Sciences at Microscale Department of Physics University of Science and Technology of China The Center of Physical Experiments University of Science and Technology of China

The Eu^3＋/Ag co-doped rare earth disilicate Y2Si2O7 microcrystal was synthesized by sol-gel method. Through controlling the thermal treatment process of YzSi2OT：EU3＋/Ag precursor, various phases （amorphous, α, β, γ, δ） were prepared. white light emis- sion was observed under UV light excitation in the samples heavily doped with Ag. The white light was realized by combining the intense red emission of Eu3＋, the green emission attributed to the very small molecule-like, non-plasmonic Ag particles （ML-Ag-particles）, and the blue emission due to Ag ions. Results demonstrated that Eu3＋/Ag co-doped Y2Si207 microcrystal could be potentially applied as White light emission phosphors for UV LED chips.

关键词： Y2Si2OT Eu^3＋ ion fluorescence ML-Ag-particle White light emission rare earths

White light emission from AIE-active luminescent organic materials

在线全文

学校读者我要写书评

暂无评论

Aggregate

Aggregate 2022年第5期3卷 159-171页

作者： Beena Kumari Rahul Dahiwadkar Sriram Kanvah Department of Chemistry Indian Institute of Technology GandhinagarGujaratIndia Center for Self-assembly and Complexity Institute for Basic Science(IBS)Pohang 37673Republic of Korea

Fluorescent organic materials that exhibit unique aggregation-induced emission have been utilized for various applications,including White light emission(WLE).The materials typically rely on composite designs involving a mixture of compounds emitting at different wavelengths of light.To overcome the limitations offered by the design of such composite mixtures,tremendous efforts were also emphasized in developing single-molecule substrates that emit white light.The white light by either method is typically controlled by the solvent polarity,energy and charge transfer,host-guest interactions,gelation,or embedding in the polymer or organic frameworks.This article briefly reviews various molecules exhibiting aggregation-induced emission behavior and emitting white light.

关键词： cyanostilbenes tetraphenylethylenes White light emission

High-performance CsPbBr_(3)@Cs_(4)PbBr_(6)/SiO_(2) nanocrystals via double coating layers for White light emission and visible light communication

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

eScience 2022年第6期2卷 646-654页

作者： Xianwen Li Wen Ma Dehai Liang Wensi Cai Shuangyi Zhao Zhigang Zang Key Laboratory of Optoelectronic Technology&Systems(Ministry of Education) Chongqing UniversityChongqing 400044China

Owing to their outstanding optoelectronic properties,all-inorganic CsPbBr_(3) perovskite nanocrystals(NCs)are regarded as excellent materials for various optoelectronic applications.Unfortunately,their practical applications are limited by poor stability against water,heat,and polar solvents.Here,we propose a facile synthesis strategy for CsPbBr_(3)@Cs_(4)PbBr_(6) NCs via tetraoctylammonium bromide ligand induction at room temperature.The resulting CsPbBr_(3)@Cs_(4)PbBr_(6) NCs show a high photoluminescence quantum yield of 94%.In order to prevent Cs4PbBr6 from being converted back to CsPbBr_(3) NCs when exposed to water,a second coating layer of SiO2 is formed on the surface of the CsPbBr_(3)@Cs_(4)PbBr_(6) NCs by the facile hydrolysis of tetramethoxysilane.The resulting CsPbBr_(3)@Cs_(4)PbBr_(6)/SiO_(2) NCs with their double coating structure have outstanding stability against not only a polar solvent(ethanol)but also water and heat.The as-prepared CsPbBr_(3)@Cs_(4)PbBr_(6)/SiO_(2) NCs serve as green emitters in efficient white light-emitting diodes(WLEDs)with a high color rendering index(CRI)of 91 and a high power efficiency 59.87 lm W−1.Furthermore,the use of these WLEDs in visible light communication(VLC)results in a maximum rate of 44.53 Mbps,suggesting the great potential of the reported methods and materials for solid-state illumination and VLC.

关键词： CsPbBr_(3)@Cs_(4)PbBr_(6)/SiO_(2)NCs Stability White light emission Visible light communication

Blue emitting exciplex for yellow and white organic light‑emitting diodes

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Frontiers of Optoelectronics 2023年第4期16卷 191-203页

作者： Kavya Rajeev C.K.Vipin Anjali K.Sajeev Atul Shukla Sarah K.M.McGregor Shih‑Chun Lo Ebinazar B.Namdas K.N.Narayanan Unni Centre for Sustainable Energy Technologies CSIR-National Institute for Interdisciplinary Science and TechnologyThiruvananthapuram 695019India Academy of Scientifc and Innovative Research(AcSIR) Ghaziabad 201002India Centre for Organic Photonics&Electronics The University of QueenslandBrisbaneQLD 4072Australia School of Mathematics and Physics The University of QueenslandBrisbaneQLD 4072Australia School of Chemistry and Molecular Biosciences The University of QueenslandBrisbaneQLD 4072Australia

white organic light-emitting diodes(WOLEDs)have several desirable features,but their commercialization is hindered by the poor stability of blue light emitters and high production costs due to complicated device structures.Herein,we investigate a standard blue emitting hole transporting material(HTM)N,N'-bis(naphthalen-1-yl)-N,N'-bis(phenyl)benzidine(NPB)and its exciplex emission upon combining with a suitable electron transporting material(ETM),3-(biphenyl-4-yl)-5-(4-tert-butylphenyl)-4-phenyl-4H-1,2,4-triazole(TAZ).Blue and yellow OLEDs with simple device structures are developed by using a blend layer,NPB:TAZ,as a blue emitter as well as a host for yellow phosphorescent dopant iridium(III)bis(4-phenylthieno[3,2-c]pyridinato-N,C2')acetylacetonate(PO-01).Strategic device design then exploits the ambipolar charge transport properties of tetracene as a spacer layer to connect these blue and yellow emitting units.The tetracene-linked device demonstrates more promising results compared to those using a conventional charge generation layer(CGL).Judicious choice of the spacer prevents exciton difusion from the blue emitter unit,yet facilitates charge carrier transport to the yellow emitter unit to enable additional exciplex formation.This complementary behavior of the spacer improves the blue emission properties concomitantly yielding reasonable yellow emission.The overall White light emission properties are enhanced,achieving CIE coordinates(0.36,0.39)and color temperature(4643 K)similar to daylight.Employing intermolecular exciplex emission in OLEDs simplifes the device architecture via its dual functionality as a host and as an emitter.

关键词： Organic light-emitting diodes Dual functional exciplex Spacers Device design strategy Blue exciplex Yellow OLEDs White light emission

基于冷却工程对环保型ZnSeTe基量子点的激发态调控

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Science China Materials 2022年第6期65卷 1569-1576页

作者：吴保强赵双易张明水黄志高陈晨臧志刚王跃 MIIT Key Laboratory of Advanced Display Materials and Devices Institute of Optoelectronics&NanomaterialsCollege of Materials Science and EngineeringNanjing University of Science and TechnologyNanjing 210094China Key Laboratory of Optoelectronic Technology&Systems(Ministry of Education) Chongqing UniversityChongqing 400044China School of Microelectronics and Communication Engineering Chongqing UniversityChongqing 400044China

由于材料内部存在高效的非辐射复合,这使得实现高质量的环保量子点仍然具有挑战性.本文中,我们探索了通过冷却工程调节激发态对实现高质量的ZnSeTe核壳量子点的影响.研究发现,超快热载流子俘获和带边载流子俘获是ZnSeTe量子点发射效率... 详细信息

由于材料内部存在高效的非辐射复合,这使得实现高质量的环保量子点仍然具有挑战性.本文中,我们探索了通过冷却工程调节激发态对实现高质量的ZnSeTe核壳量子点的影响.研究发现,超快热载流子俘获和带边载流子俘获是ZnSeTe量子点发射效率低下的主要原因.我们通过设计冷却工程抑制上述过程,并且结合电子和光谱表征分析了其潜在机制.经过冷却优化的ZnSeTe量子点表现出高量子发光效率(>90%)和稳定性,这可与经典的CdSe量子点相媲美.基于这种量子点的白光发光二极管(WLED)表现出优异的光学性能,包括高显色指数(80)和良好的相关色温(7391 K).此外,高性能的WLED还可以用作环保可见光通信.这些结果表明了环保量子点在实际应用中的可行性.

关键词： eco-friendly quantum dot ZnSeTe carrier dynamics White light emission visible light communication

Photoluminescence properties of Tm^(3+)/Tb^(3+)/Sm^(3+) tri-doped Na_(5)Y_(9)F_(32) single crystal with high thermal stability for white light-emitting diodes

在线全文

学校读者我要写书评

暂无评论

Journal of Rare Earths 2021年第5期39卷 512-519页

作者： Yang Qiao Xiong Zhou Jianli Zhang Haiping Xia Hongwei Song Baojiu Chen Key Laboratory of Photo-electronic Materials Ningbo UniversityNingbo 315211China State Key Laboratory on Integrated Optoelectronics College of Electronic Science and Engineering and College of PhysicsJilin UniversityChangchun 130012China Department of Physics Dalian Maritime UniversityDalian 116026China

A novel Tm^(3+)/Tb^(3+)/Sm^(3+)tri-doped Na_(5)Y_(9)F_(32)single crystal was synthesized by a modified Bridgman method for the propose of white light emitting diodes.The fluorescence spectra of various Sm^(3+)ion concentrations and fixed 0.4 mol%Tm^(3+)and 0.5 mol%Tb^(3+)were measured and studied systematically excited by near-ultraviolet light of 355 nm.The Sm3+ion concentration takes apparent effect on the relative intensity of peaks in the visible region and the color coordinate combining from these emission bands.A near pure White light emission with color coordinates(0.3295,0.3057)and color temperature(5657 K)can be obtained when the concentrations of Tm^(3+),Tb^(3+)and Sm^(3+)ions are 0.4 mol%,0.5 mol%and 0.8 mol%,respectively.Furthermore,the practical down-conversion internal quantum yield was measured by integrating spheres at about 14.39%.The tri-doped Na_(5)Y_(9)F_(32)single crystal shows a high thermal stability inferring from the temperature dependent emission in which the integrated emission intensities are reduced only by^3%with the increase of temperature from 280 to 450 K.The present results demonstrate that the Tm^(3+)/Tb^(3+)/Sm^(3+)tri-doped Na_(5)Y_(9)F_(32)single crystal may provide a promising candidate for white light-emitting diodes,luminescent materials and fluorescent display devices.

关键词： Na_(5)Y_(9)F_(32)single crystal Tm^(3+)/Tb^(3+)/Sm^(3+) Bridgman method White light emission Rare earths

Tunable light emission from carbon dots by controlling surface defects

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2021年第9期32卷 2887-2892页

作者： Huijun Li Sancan Han Bowen Lyu Ting Hong Shibo Zhi Ling Xu Fengfeng Xue Liman Sai Junhe Yang Xianying Wang Bin He School of Material Science&Engineering University of Shanghai for Science and TechnologyShanghai 200093China Department of Critical Care Medicine Shanghai Chest HospitalShanghai Jiao Tong UniversityShanghai 200030China School of Microelectronics Fudan UniversityShanghai 200093China Shanghai Key Laboratory of Molecular Imaging Shanghai University of Medicine and Health SciencesShanghai 201318China Department of Physics Shanghai Normal UniversityShanghai 200234China

Carbon dots(CDs)are metal-free fluorescent materials that can be used in optical and electronic devices,but few studies have focused on one-step synthesis routes for CDs with tunable color and high photoluminescence quantum yield(PLQY).Herein,CDs with tunable light emission were synthesized using a novel amide-assisted solvothermal approach.The as-prepared CDs were well dispersed and homogeneous,with average diameters of approximately 2.0–4.0 nm,depending on the dopants.Owing to the surface states with different ratios of nitrogen-and oxygen-related species,different CDs can exhibit blue,green,red,or white emission with relatively high PLQYs of 61.6%,41.3%,29.1%and 19.7%,respectively.XPS measurements,in conjunction with DFT calculations,indicate that nitrogen substitution(pyridinic/pyrrolic nitrogen)dominates the blue emission,while introducing oxygen functional groups lowered the LUMO energy level,which resulted in redder emission.In addition,the CDs are demonstrated as a bioimaging probe in both in vitro and in vivo assays,and the white light CDs have been demonstrated to be potential fluorescent materials for white-light-emitting diode(WLED).

关键词： Carbon dots Fluorescence Structural engineering Energy gap White light emission

Luminescent characteristics of Tm^(3+)/Tb^(3+)/Eu^(3+) tri-doped Na_(5)Y_(9)F_(32) single crystals for white emission with high thermal stability

在线全文

学校读者我要写书评

暂无评论

Chinese Physics B 2022年第12期31卷 544-549页

作者：方立志周雄赵志伟郑标夏海平王军宋宏伟陈宝玖 Key Laboratory of Photo-electronic Materials Ningbo UniversityNingbo 315211China Taizhou Special Equipment Inspection and Research Institute Taizhou 318000China Fujian Provincial Key Laboratory of Functional Marine Sensing Materials Center for Advanced Marine Sensing Materials and Smart SensorsMinjiang UniversityFuzhou 350108China State Key Laboratory on Integrated Optoelectronics College of Electronic Science and Engineering and College of PhysicsJilin UniversityChangchun 130012China Department of Physics Dalian Maritime UniversityDalian 116026China

By using an improved Bridgman method,0.3 mol%Tm^(3+)/0.6 mol%Tb^(3+)/y mol%Eu^(3+)(y=0,0.4,0.6,0.8)doped Na_(5)Y_(9)F_(32)single crystals were prepared.The x-ray diffraction,excitation spectra,emission spectra and fluorescence decay curves were used to explore the crystal structure and optical performance of the obtained samples.When excited by 362 nm light,the cool white emission was realized by Na_(5)Y_(9)F_(32)single crystal triply-doped with 0.3 mol%Tm^(3+)/0.6 mol%Tb^(3+)/0.8 mol%Eu^(3+),in which the Commission Internationale de l’Eclairage(CIE)chromaticity coordinate was(0.2995,0.3298)and the correlated color temperature(CCT)was 6586 K.The integrated normalized emission intensity of the tridoped single crystal at 448 K could keep 62%of that at 298 K.The internal quantum yield(QY)was calculated to be~15.16%by integrating spheres.These results suggested that the single crystals tri-doped with Tm^(3+),Tb^(3+)and Eu^(3+)ions have a promising potential application for white light-emitting diodes(w-LEDs).

关键词： Tm^(3+)/Tb^(3+)/Eu^(3+)triply-doped Na_(5)Y_(9)F_(32) White light emission energy transfer process thermal stability