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Comparison of Soil Samples from Selected Anthropogenic sites within Enugu Metropolis for Physicochemical Parameters and Heavy metal Levels Determination

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Journal of Environmental Protection 2020年第10期11卷 848-861页

作者： Onyeka Okeke Ernest Ezeh Harold Chinedu Okeke Charles Chukwubuikem Aniobi Cletus Ifeanyi Akagha Plastic Production Unit Scientific Equipment Development Institute Akwuke Nigeria Chemical Engineering Department Nnamdi Azikiwe University Awka Nigeria Department of Geological Sciences Nnamdi Azikwe University Awka Nigeria Department of Community Medicine University of Nigeria Enugu Campus Enugu Nigeria Chemistry Department Federal University of Technology Owerri Nigeria

This study compared the physicochemical parameters and heavy metal levels in soil samples from selected anthropogenic sites within Enugu metropolis, Enugu State, Nigeria using standard analytical methods. Soil samples at depths (0 - 20 cm) and (20 - 40 cm) were collected from waste dump sites, metal scrap dumps, fuel filling stations and auto-mechanic workshops and analyzed for physicochemical characteristics and heavy metal levels. Atomic absorption spectrophotometer was used for heavy metal determination while conventional analytical methods were employed for physicochemical parameters evaluation of the soil samples. At soil depths 0 - 20 cm and 20 - 40 cm the respective mean range of pH, electrical conductivity, organic matter and organic carbon contents in the soil samples were, 6.33 - 6.74, 101.46 - 123.21 μS/cm, 6.41% - 8.35% and 13.73% - 16.14% for auto-mechanic workshops;6.92 - 7.43, 56.46 - 60.02 μS/cm, 1.53% - 2.20% and 11.93% - 12.60% for fuel filling stations;7.14 - 7.84, 70.81 - 77.71 μS/cm, 3.81% - 4.12% and 8.57% - 9.24% for metal scrap dumps;6.54 - 6.81, 94.40 - 100.71 μS/cm, 8.83% - 10.75% and 18.26% - 20.81% for waste dump sites. The pH of the top soil samples from auto-mechanical workshop was below the WHO recommended limits for agricultural purposes. The physic-chemical characteristics of the soil samples decreased with soil depths indicating therefore that anthropogenic activities greatly influence the soil characteristics at the top soils than the sub-soils. The electrical conductivity values of top and sub-soil samples from the studied auto-mechanical workshops were above the recommended limits. At soil depths 0 - 20 cm and 20 - 40 cm, the respective mean range of Zn, Pb and Cd in the soil samples were 17.29 - 19.16 μg/g, 0.704 - 0.96 μg/g and 0.26 - 0.33 μg/g for auto-mechanic workshops;4.13 - 4.88 μg/g, 0.21 - 0.32 μg/g and 0.03 - 0.11 μg/g for fuel fil

关键词： Physicochemical Parameters Heavy metals Pollution Soils Auto-Mechanic Workshops Fuel Filling Stations waste dump sites and metal scrap dumps

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