检索结果-南通市图书馆

Hydrophobic long-chain two-dimensional perovskite scintillators for underwater X-ray imaging

Rare Metals 2024年第1期43卷 175-185页

作者： Jin-Xiao Zheng Zi-An Zhou Tiao Feng Hui Li Cheng-Hua Sun NüWang Yang Tian Yong Zhao Shu-Yun Zhou Key Laboratory of Photochemical Conversion and Optoelectronic Materials Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China Laboratory of Bioinspired Smart Interfacial Science and Technology of the Ministry of Education Beijing Key Laboratory of Bioinspired Energy Materials and DevicesSchool of ChemistryBeijing Advanced Innovation Center for Biomedical EngineeringBeihang UniversityBeijing 100191China Department of Engineering Physics Tsinghua University and Key Laboratory of Particle and Radiation Imaging Ministry of EducationTsinghua UniversityBeijing 100084China e-mail:yangt@***

The underwater X-ray imaging technology development is significant to subaqueous target reconnaissance/detection/identification, subfluvial archaeology,submerged resource exploration, etc. As the core of X-ray imaging detection, the scintillator has been plagued by inherent moisture absorption and decomposition, and strict requirements for seamless packaging and waterproofing.Here, we designed a manganese-doped two-dimensional(2D) perovskite scintillator modified by hydrophobic longchain organic amine through the combination of component and doping engineering. The modified perovskites show high water repellency that can be used as an underwater X-ray scintillator. X-ray images of aquatic organisms or other objects with a high spatial resolution of10 lp·mm^(-1) at a big view field(32 mm × 32 mm) were obtained by scintillation screen. This hydrophobic perovskite scintillator based on molecular design is of great promise in underwater X-ray nondestructive testing technology development.

关键词： two-dimensional perovskite Hydrophobic Scintillators Underwater X-ray imaging Underwater nondestructive testing technology

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Manipulating Emission Enhancement and Piezochromism in two-dimensional Organic–Inorganic Halide perovskite[(HO)(CH_(2))_(2)NH_(3)]_(2)PbI_(4)by High Pressure

引用

CCS Chemistry 2021年第8期3卷 2206-2213页

作者： Yuanyuan Fang Long Zhang Yishuai Yu Xinyi Yang Kai Wang Bo Zou State Key Laboratory of Superhard Materials College of PhysicsJilin UniversityChangchun 130012

two-dimensional(2D)organic–inorganic halide perovskites present remarkable stability and diversity and are promising alternatives to their three-dimensional(3D)counterparts.The 2D halide perovskite[(HO)(CH_(2))_(2)NH_(3)]_(2)PbI_(4)is regarded as a superior moisture-stabile“smooth”perovskite because of distinct hydrogen-bond networks that connect adjacent organic–inorganic layers.

关键词： two-dimensional perovskite emission enhancement piezochromism high pressure band gap red shift

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Ionic Liquid Assisted Imprint for Efficient and Stable Quasi-2D perovskite Solar Cells with Controlled Phase Distribution

引用

Nano-Micro Letters 2023年第7期15卷 1-15页

作者： Haibin Peng Dengxue Li Zongcai Li Zhi Xing Xiaotian Hu Ting Hu Yiwang Chen Department of Polymer Materials and Engineering School of Physics and Materials ScienceNanchang University999 Xuefu AvenueNanchang 330031People’s Republic of China College of Chemistry and Chemical Engineering Institute of Polymers and Energy Chemistry(IPEC)Nanchang University999 Xuefu AvenueNanchang 330031People’s Republic of China National Engineering Research Center for Carbohydrate Synthesis/Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of EducationJiangxi Normal University99 Ziyang AvenueNanchang 330022People’s Republic of China Peking University Yangtze Delta Institute of Optoelectronics Nantong 226010People’s Republic of China

Although two-dimensional perovskite devices are highly stable,they also lead to a number of challenges.For instance,the introduction of large organic amines makes crystallization process complicated,causing problems such as generally small grain size and blocked charge transfer.In this work,imprint assisted with methylamine acetate were used to improve the morphology of the film,optimize the internal phase distribution,and enhance the charge transfer of the perovskite film.Specifically,imprint promoted the dispersion of spacer cations in the recrystallization process with the assistance of methylamine acetate,thus inhibited the formation of low-n phase induced by the aggregation of spacer cations and facilitated the formation of 3D-like phase.In this case,the corresponding quasi-2D perovskite solar cells delivered improved efficiency and exhibited superior stability.Our work provides an effective strategy to obtain uniform phase distribution for quasi-2D perovskite.

关键词： Imprint two-dimensional perovskite Phase distribution Charge transfer Stability

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Brightening thiocyanate-anion layered perovskite through internal stress modulated nano phase segregation

引用

Nano Research 2023年第4期16卷 5533-5540页

作者： Yiming Li Jiangjian Shi Huijue Wu Yanhong Luo Dongmei Li Qingbo Meng Key Laboratory for Renewable Energy Chinese Academy of SciencesBeijing Key Laboratory for New Energy Materials and DevicesInstitute of PhysicsChinese Academy of SciencesBeijing 100190China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China Huairou Division Institute of PhysicsChinese Academy of SciencesBeijing 101400China Songshan Lake Materials Laboratory Dongguan 523808China

Thiocyanate-anion(SCN−)two-dimensional(2D)layered perovskite with internal stress-controlled nano phase segregation has been firstly demonstrated as a promising material system for luminescence applications.An interesting energy band structure is found as well as charge transfer process caused by nano phase segregation,which provide an alternative route to overcome the indirect-bandgap luminescence limit of SCN layered perovskites.It is revealed that,within the SCN layered framework,the segregated nano phases exist in a quantum well form,possessing much higher carrier localization and second-order radiative recombination abilities.With the help of internal stress modulation,these advantages can be significantly enhanced and finally contribute to high luminescence performances in visible-red regions.This work provides more potential opportunities for 2D layered perovskite materials in the future optoelectronic applications.

关键词： two-dimensional perovskite internal stress thiocyanate anion phase segregation luminescence

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

two‑dimensional Metal Halides for X‑Ray Detection Applications

引用

Nano-Micro Letters 2023年第8期15卷 405-422页

作者： Yumin Li Yutian Lei Haoxu Wang Zhiwen Jin School of Physical Science and Technology and Lanzhou Center for Theoretical Physics and Key Laboratory of Theoretical Physics of Gansu Province Lanzhou UniversityLanzhou 730000People’s Republic of China

Metal halide perovskites have recently emerged as promising candidates for the next generation of X-ray detectors due to their excellent optoelectronic properties.Especially,two-dimensional(2D)perovskites afford many distinct properties,including remarkable structural diversity,high generation energy,and balanced large exciton binding energy.With the advantages of 2D materials and perovskites,it successfully reduces the decomposition and phase transition of perovskite and effectively suppresses ion migration.Meanwhile,the existence of a high hydrophobic spacer can block water molecules,thus making 2D perovskite obtain excellent stability.All of these advantages have attracted much attention in the field of X-ray detection.This review introduces the classification of 2D halide perovskites,summarizes the synthesis technology and performance characteristics of 2D perovskite X-ray direct detector,and briefly discusses the application of 2D perovskite in scintillators.Finally,this review also emphasizes the key challenges faced by 2D perovskite X-ray detectors in practical application and presents our views on its future development.

关键词： two-dimensional perovskite High stability Ion migration Charge transport X-ray Detector

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Optical properties of two-dimensional perovskites

引用

Frontiers of physics 2023年第3期18卷 1-26页

作者： Junchao Hu Xinglin Wen Dehui Li School of Optical and Electronic Information Huazhong University of Science and TechnologyWuhan 430074China Wuhan National Laboratory for Optoelectronics Huazhong University of Science and TechnologyWuhan 430074China

The optical properties of two-dimensional(2D)perovskites recently receive numerous research focus thanks to the strong quantum and dielectric confinement effects.In addition to the strong excitonic effect at room temperature,2D perovskites also have appealing features that their optical properties can be flexibly tuned by alternating organic or inorganic layers.Particularly,2D chiral perovskites and 2D perovskites based heterostructures are emerging as new platforms to extend their functionalities.To optimize performance of 2D perovskites-based optoelectronic devices,it is critical to understand the fundamentals and explore the strategies to engineer their optical properties.This review begins with an introduction to the excitons and self-trapped excitons of 2D perovskites.Subsequently,inorganic/organic layer effects on optical properties and 2D perovskites based heterostructures are discussed.We also discussed the nonlinear optical properties of 2D perovskite.We are looking forward to that this review can stimulate more efforts to understand and optimize the optical properties of 2D perovskites.

关键词： optical properties two-dimensional perovskite heterostructures self-trapped excitons

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Giant enhancement of photoluminescence quantum yield in 2D perovskite thin microplates by graphene encapsulation

引用

Nano Research 2021年第6期14卷 1980-1984页

作者： Wancai Li Jiaqi Ma Xue Cheng Dehui Li School of Optical and Electronic Information Huazhong University of Science and TechnologyWuhan430074China Wuhan National Laboratory for Optoelectronics Huazhong University of Science and TechnologyWuhan430074China

The optoelectronic performances of the layered materials are strongly dependent on the thickness of the samples due to the surface effect.As the size of the samples decreases to few nanometers,the surface depletion field and surface defect density are prominent arising from the large surface to volume ratio.For instance,thin two-dimensional(2D)organic-inorganic hybrid perovskite microplates usually exhibit a rather low photoluminescence quantum yield(PLQY),owning to the strong surface effect.Here,we report that the PLQY can be enhanced as large as 28 times in(iso-BA)2Pbl4(BA=C4H9NH3)2D perovskite thin microplates encapsulated by graphene,resulting in that the PLQY is more than 18%for the microplate with a thickness of 6.7 nm at 78 K.As the thickness of the 2D perovskite microplate increases,the enhancement is gradually reduced and finally vanishes.This observation is in striking contrast to that in monolayer transition metal dichalcogenides(TMDs),when the PLQY is quenched by covering a layer of graphene due to the efficient charge transfer.The enhancement of PLQY in 2D perovskites can be mainly ascribed to the reduced quantum confined Stark effect(QCSE)due to the reduced surface depletion field after covering graphene flake,resulting in the enhanced radiative recombination efficiency.Our findings provide a cost-effective approach to enhance the luminescence,which may pave the way toward high performance light emitting devices based on 2D perovskites.

关键词： two-dimensional perovskite photoluminescence quantum yield quantum confinement surface depletion field

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Graded interface engineering of 3D/2D halide perovskite solar cells through ultrathin(PEA)_(2)PbI_(4) nanosheets

引用

Chinese Chemical Letters 2021年第7期32卷 2259-2262页

作者： Lijie Zhu Qipeng Lu Chunhai Li Yue Wang Zhenbo Deng Key Laboratory of Luminescence and Optical Information Ministry of EducationBeijing JiaoTong UniversityBeijing 100044China School of Instrument Science and Opto-Electronics Engineering Beijing Information Science and Technology UniversityBeijing 100192China School of Materials Science and Engineering University of Science and Technology BeijingBeijing 100083China

2D halide perovskites have emerged as promising materials because of their stability and passivation effect in perovskite solar cells(PSCs).However,the introduction of bulky organic ammonium cations from 2D halide perovskites would decrease the device performance generally compared to the traditional 3D MAPbI_(3).Incorporation of ultrathin 2D halide perovskite nanosheets(NSs)with 3D MAPbI_(3)could address this issue.Herein,we re port a rationally designed PSCs with dimensional graded 3D/2D MAPbI_(3)/(PEA)_(2)PbI_(4)heterojunction,in which 2D(PEA)_(2)PbI_(4)NSs were synthesized and incorporated between 3D MAPbI_(3)and hole-transporting layer.Besides the significantly improved stability,a notable increasement in power conversion efficiency(PCE)of 20%was obtained for the 3D/2D perovskite solar cells due to the favourable band alignment among(PEA)_(2)PbI_(4)NSs and the other components.The graded structure of MAPbI_(3)/(PEA)_(2)PbI_(4)would upshift the energy level continuously,which enhances the hole extraction efficiency thus reduces the interface charge recombination,leading to the increasements of VOC from1.04 V to 1.07 V,Jsc from 21.81 mA/cm^(2) to 23.15 mA/cm^(2) and the fill factor from 67.89% to 74.78%,and therefore an overall PCE of 18.53%.

关键词： Interface engineering perovskite solar cell two-dimensional perovskite Hole extraction layer Band alignment

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Long-term Stable 2D Dion-Jacobson Phase perovskite Photodiode with Low Dark Current and High On/off Ratio

引用

Chinese Journal of Structural Chemistry 2021年第12期40卷 1621-1630,1553页

作者：顾浩陈善慈郑庆东 College of Chemistry Fuzhou UniversityFuzhou 350000China State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China

A two-dimensional(2D)organic-inorganic hybrid perovskite(OIHP)material is considered as a promising candidate for a long-term stable photodetector owing to its outstanding phase and environmental stability.Herein,we demonstrate a perovskite photodiode based on the DJ phase 2D perovskite(PDA)(MA)_(n-1)Pb_(n)I_(3n+1)(where PDA is 1,3-propylenediamine,MA is methylamine,nominal n=4).The best-performance device exhibits a high detectivity of 4.57×10^(11) Jones,a responsivity of 0.25 A·W^(-1) at 480 nm,a low dark current density of 9.60×10^(-4) mA cm^(-2),and a remarkable on/off ratio of 3.10×10^(5).The unencapsulated device can maintain 95%of the initial photocurrent density after 90 days under an ambient atmosphere with relative humidity(RH)of 65%,demonstrating its improved stability than the 3D counterpart.The excellent stability of the photodiode based on 2D perovskite promises its bright commercial application ftiture.

关键词： two-dimensional perovskite Dion-Jacobson photodiode on/off ratio stability

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：