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Room-temperature sputtered electrocatalyst WSe2 nanomaterials for hydrogen evolution reaction

Journal of Energy Chemistry 2020年第8期29卷 107-111,I0004页

作者： Jae Hyeon Nam Myeong Je Jang Hye Yeon Jang Woojin Park Xiaolei Wang Sung Mook Choi Byungjin Cho Department of Advanced Material Engineering Chungbuk National UniversityChungdae-ro 1Seowon-GuCheongjuChungbuk 28644Republic of Korea Surface Technology Department Korea Institute of Materials Science797 ChangwonDaeroSungsan-guChangwon 51508Republic of Korea Advanced Materials Engineering Korea University of Science and Technology(UST)217 Gajeong-roYuseong-guDaejeon 34113Republic of Korea Department of Chemical and Materials Engineering University of Alberta9211116 Street NWEdmontonAlberta T6C 1H9Canada

The low-temperature physical vapor deposition process of atomically thin two-dimensional transition metal dichalcogenide(2D TMD) has been gaining attention owing to the cost-effective production of diverse electrochemical catalysts for hydrogen evolution reaction(HER) applications. We, herein, propose a simple route toward the cost-effective physical vapor deposition process of 2D WSe2 layered nanofilms as HER electrochemical catalysts using RF magnetron sputtering at room temperature(<27℃). By controlling the variable sputtering parameters, such as RF power and deposition time, the loading amount and electrochemical surface area(ECSA) of WSe2 films deposited on carbon paper can be carefully determined. The surface of the sputtered WSe2 films are partially oxidized, which may cause spherical-shaped particles. Regardless of the loading amount of WSe2, Tafel slopes of WSe2 electrodes in the HER test are narrowly distributed to be ~120–138 mV dec-1, which indicates the excellent reproducibility of intrinsic catalytic activity. By considering the trade-off between the loading amount and ECSA, the best HER performance is clearly observed in the 200 W-15 min sample with an overpotential of 220 mV at a current density of 10 mA cm-2. Such a simple sputtering method at low temperature can be easily expanded to other 2D TMD electrochemical catalysts, promising potentially practical electrocatalysts.

关键词： two dimensional nanomaterials Sputtering WSe2 nanofilm Electrocatalyst Hydrogen evolution reaction

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