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Electrochemical corrosion resistance of CeO_2-Cr/ti coatings on 304 stainless steel via pack cementation

Journal of Rare Earths 2015年第10期33卷 1122-1128页

作者：邢学刚韩志军王鹤峰卢盼娜 College of Mechanics Taiyuan University of Technology

The pack cementation was employed to improve the electrochemical corrosion resistance of 304 stainless steel via CeO2- Cr modified ti coatings. Continuous coatings were formed on 304 stainless steel surface by this method. A series of electrochemical experiments were carried out to investigate the corrosion resistance of 304 stainless steel, ti coating and CeO2-Cr/ti coatings. The sample surface was investigated by scanning electron microscopy （SEM）. The phases of sample surface were detected by X-ray diffraction （XRD）. It was concluded from all the outcomes that the Corrosion resistance of the samples could be sorted in the following sequence： CeO2-Cr/ti coatings〉ti coating〉304 stainless steel.

关键词： electrochemical corrosion resistance rare earths ti coating 304 stainless steel pack cementation

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Corrosion Investigation by Scanning Electrochemical Microscopy of AISI 446 and ti-Coated AISI 446 Ferritic Stainless Steel as Potential Material for Bipolar Plate in PEMWE

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Acta Metallurgica Sinica(English Letters) 2024年第4期37卷 607-619页

作者： Andrea Kellenberger Nicolae Vaszilcsin Mircea Laurentiu Dan Ion Mitelea Alexandru Adrian Geana Sigrid Lædre Corneliu M.Craciunescu Faculty of Industrial Chemistry and Environmental Engineering Politehnica University TimisoaraPiata Victoriei 2300006TimisoaraRomania Faculty of Mechanical Engineering Politehnica University TimisoaraPiata Victoriei 2300006TimisoaraRomania SINTEF Industry 7465TrondheimNorway

The components of proton exchange membrane water electrolysers frequently experience corrosion issues, especially at high anodic polarization, that restrict the use of more affordable alternatives to titanium. Here, we investigate localized corrosion processes of bare and ti-coated AISI 446 ferritic stainless steel under anodic polarization by scanning electrochemical microscopy (SECM) in sodium sulphate and potassium chloride solutions. SECM approach curves and area scans measured at open-circuit potential (OCP) of the samples in the feedback mode using a redox mediator evidence a negative feedback effect caused by the surface passive film. For the anodic polarization of the sample, the substrate generation-tip collection mode enables to observe local generation of iron (II) ions, as well as formation of molecular oxygen. For the uncoated AISI 446 sample, localized corrosion is detected in sodium sulphate solution simultaneously with oxygen formation at anodic potentials of 1.0 V vs. Ag/AgCl, whereas significant pitting corrosion is observed even at 0.2 V vs. Ag/AgCl in potassium chloride solution. The ti-coated AISI 446 sample reveals enhanced corrosion resistance in both test solutions, without any evidence of iron (II) ions generation at anodic potentials of 1.2 V vs. Ag/AgCl, where only oxygen formation is observed.

关键词： Ferritic stainless steel Corrosion ti coating Scanning electrochemical microscopy(SECM) Magnetron sputtering Proton exchange membrane water electrolysis(PEMWE)

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Pitting corrosion behavior and corrosion protection performance of cold sprayed double layered noble barrier coating on magnesium-based alloy in chloride containing solutions

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Journal of Magnesium and Alloys 2023年第9期11卷 3099-3119页

作者： M.Daroonparvar A.Helmer A.M.Ralls M.U.Farooq Khan A.K.Kasar R.K.Gupta M.Misra S.Shao P.L.Menezes N.Shamsaei National Center for Additive Manufacturing Excellence Auburn UniversityAuburnAL 36849USA Department of Mechanical Engineering Auburn UniversityAuburnAL 36849USA Department of Materials Science and Engineering College of EngineeringNorth Carolina State University911 Partners WayRaleighNC 27695USA Department of Mechanical Engineering University of Nevada RenoRenoNV 89501USA Department of Nuclear Engineering and Radiological Sciences University of MichiganAnn ArborMI 48105 USA Department of Chemical and Materials Engineering University of Nevada RenoNV 89501USA

Nitrogen processed, cold sprayed commercially pure(CP)-Al coatings on Mg-based alloys mostly lack acceptable hardness, wear resistance and most importantly are highly susceptible to localized corrosion in chloride containing solutions. In this research, commercially pure α-ti top coating having good pitting potential(~1293 mV_(SCE)), high microhardness(HV_(0.025): 263.03) and low wear rate was applied on a CP-Al coated Mg-based alloy using high pressure cold spray technology. Potentiodynamic polarization(PDP) curves indicated that the probability of transition from metastable pits to the stable pits for cold spayed(CS) Al coating is considerably higher compared to that with the CS ti top coating(for ti/Al/Mg system). In addition, CS ti top coating was in the passivation region in most pH ranges even after 48 h immersion in 3.5 wt% NaCl solution. The stored energy in the CS ti top coating(as a passive metal) was presumed to be responsible for the easy passivation. Immersion tests indicated no obvious pits formation on the intact CS ti top coating surface and revealed effective corrosion protection performance of the CS double layered noble barrier coatings on Mg alloys in 3.5 wt% NaCl solution even after 264 h.

关键词： ti coating Mg alloys Localized corrosion Passivity Dislocation density Crystallite size

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coating titanium on carbon steel by in-situ electrochemical reduction of solid tiO_2 layer

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Transactions of Nonferrous Metals Society of China 2017年第1期27卷 134-140页

作者：肖作安汤迪勇范金航肖巍汪的华武汉大学资源与环境科学学院武汉430072

ti coating on A3 steel was successfully prepared by direct electrochemical reduction of high-velocity oxy-fuel （HVOF） thermally sprayed and room-temperature dip-coating titanium dioxide coating on A3 steel in molten CaCl2 at 850 ℃. The interfacial microstructure and mutual diffusion between coating and steel substrate were investigated using scanning electron microscopy （SEM） and energy dispersive X-ray （EDX） spectroscopy. The results show that the precursory tiO2 coating prepared by HVOF has closer contact and better adhesion with the A3 steel substrate. After electrolysis, all of the electro-generated ti coatings show intact contact with the substrates, regardless of the original contact situation between tiO2 layer and the steel substrate in the precursors. The inter-diffusion between the iron substrate and the reduced titanium takes place at the interface. The results demonstrate the possibility of the surface electrochemical metallurgy （SECM） is a promising surface engineering and additive manufacturing method.

关键词： ti coating molten salt surface metallurgy electrochemical reduction additive manufacturing

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