检索结果-南通市图书馆

thermochemical properties and thermokinetic behavior of energetic triazole ionic salts

Science China Chemistry 2011年第3期54卷 461-474页

作者： ZHAO FengQi XUE Liang XING XiaoLing HU RongZu ZHOU ZhiMing GAO HongXu YI JianHua XU SiYu PEI Qing National Key Lab of Science and Technology on Combustion and Explosion Xi'an Modern Chemistry Research Institute Xi'an 710065 China School of Chemistry and Materials Science Shaanxi Normal University Xi'an 710062. China School of Chemical Engineering and Environment Beijing Institute of Technology Beijing 100081 China

The properties of dissolution in different solvents,the specific heat capacity and thermal decomposition process under the non-isothermal conditions for energetic triazole ionic salts 1,2,4-triazolium nitrate(1a),1,2,3-triazolium nitrate(1b),3,4,5triamino-1,2,4-triazolium nitrate(2a),3,4,5-triamino-1,2,4-triazolium dinitramide(2b)were precisely measured using a Calvet *** thermochemical equation,differential enthalpies of dissolution(△difH m ),standard molar enthalpies of dissolution(△difH m ),apparent activation energy(E),pre-exponential constant(A),kinetic equation,linear relationship of specific heat capacity with temperature over the temperature range from 283 to 353 K,standard molar heat capacity(C p,m)and enthalpy,entropy and Gibbs free energy at 283–353 K,taking 298.15 K as the benchmark for 1a,1b,2a and 2b were obtained with treating experimental data and theoretical calculation *** kinetic and thermodynamic parameters of thermal decomposition reaction,critical temperature of thermal explosion(Tb),self-accelerating decomposition temperature(TSADT)and adiabatic time-to-explosion(t)of 1a,1b,2a and 2b were *** heat-resistance abilities were *** was obtained on the relation between molecular structures and properties of 1a,1b,2a and 2b.

关键词： energetic triazole ionic salts thermochemical properties thermokinetic behavior thermal safety

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

thermochemical properties of cadmium(Ⅱ) complex with 2-(2-hydroxyphenyl)benzothiazolate

Thermochemical properties of cadmium(Ⅱ) complex with 2-(2-h...

引用

中国化学会第十五届全国化学热力学和热分析学术会议

作者： Fushan Yu,Jinting Tan,Xia Li,Xuwu,Yang~* College of Chemistry and Materials Science,Northwest University,Xi’an,710069,PR China,

Some new transition metal complexes,formed from the bidentate 2-(2-hydroxyphenyl)benzothiazolate(BTZ) ligand with N and O donors,have been recently gained considerable *** this paper,the complex,Cd(BTZ),was synthesise... 详细信息

关键词： 2-(2-hydroxyphenyl)benzothiazolate complex thermochemical properties

来源： cnki会议评论

在线全文

cnki会议

学校读者我要写书评

暂无评论

Heat Capacity and Bond Dissociation Energy Calculations of Some Fluorinated Ethanol’s and its Radicals: CH3-xCH2FxOH, CH3CH2-xFxOH

引用

Open Journal of Physical Chemistry 2021年第2期11卷 13-53页

作者： Hebah M. Abdel-Wahab Joseph W. Bozzelli Department of Chemistry and Environmental Science New Jersey Institute of Technology Newark New Jersey USA

Structures and thermochemical properties of these species were determined by the gaussian M-062x/6-31 + g (d, p) calculation enthalpies of formation for 19 fluorinated ethanol and some radicals were calculated with a popular Ab initio and density functional theory methods: The gaussian M-062x/6-31 + g (d, p) via several series of isodesmic reactions. Entropies (S298°K

关键词： Thermo-Chemistry Enthalpy Fluorinated Ethanol’s thermochemical properties

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：