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FeNiS_(2)/reduced graphene oxide electrocatalysis with reconstruction to generate FeNi oxo/hydroxide as a highly-efficient water oxidation electrocatalyst

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Rare Metals 2022年第12期41卷 4127-4137页

作者： Xiao-Zhen Ren Xue-Hui Li Yu-Jie Peng Guan-Zhi Wang Jie Yin Xing-Chuan Zhao Wei Wang Xiao-Bai Wang School of Materials Science and Engineering Liaocheng UniversityLiaocheng 252000China School of Metallurgy and Chemistry Engineering Jiangxi University of Science and TechnologyGanzhou 341000China Department of Materials Application Research AVIC Manufacturing Technology InstituteBeijing 100024China

It is critical to developing electrocatalysts with highly active and cost-effective for oxygen evolution to resolve environmental pollution and energy issues,in which FeNi-based nanomaterials hold a great promise.Herein,(Fe_(0.33 )Ni_(0.67))S_(2) and(Fe_(0.33 )Ni_(0.67))S_(2)/reduced graphene oxide(rGO)-x%(x=10,20) composites,which exhibited highly efficient oxygen evolution reaction(OER)electrocatalytic activity under alkaline conditions,were synthesized via a hydrothermal approach and following thermal treatment with sulfur powders.Benefiting from the integrated structure of(Fe_(0.33 )Ni_(0.67))S_(2)and support of conductive graphene backbones,(Fe_(0.33 )Ni_(0.67))S_(2)/rGO-20%electrocatalyst showed the best OER activity with an overpotential of 172 mV at 10 mA·cm^(-2)and Tafel slopes of 45 mV·decade^(-1).The composition,phase,and surface structure of the catalyst were characterized before and after OER reaction.The results indicated that crystal phase of the catalyst was reconstructed to the amorphous crystalline features after OER,with oxidation of iron-nickel sulfide and appearance of Ni-Fe oxo/hydroxide species,which may play a crucial role in the high OER performance as the catalytic-active.Moreover,in a two-electrode system towards overall water splitting with(Fe_(0.33 )Ni_(0.67))S_(2)/rGO-20%/NF and Pt/C/NF as the anode and cathode,respectively,the catalysts exhibited excellent catalytic performance with the voltage of only 1.42 V at 10 mA·cm^(-2).

关键词： ternary nickel-iron sulfide Reduced graphene oxide(rGO) Electrocatalysts Water oxidation Self-reconstruction

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