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phase Separation in PCDTBT:PCBM Blends:from Flory-Huggins Interaction Parameters to ternary phase diagrams

Chinese Journal of Polymer Science 2020年第9期38卷 1025-1033,I0009页

作者： Monika Biernat Pawel Dabczynski Pawel Biernat Jakub Rysz Jagiellonian University Faculty of Physics Astronomy and Applied Computer Science ul.lojasiewicza 1130-348 KrakówPoland Mathematisches Institut Rheinische Friedrich-Wilhelms-Universitat BonnEndenicher Allee 6053115 BonnGermany

The substantial increase in the efficiency of organic solar cells achieved in recent years would not have been possible without work on the synthesis of new materials and understanding the relationship between the morphology and performance of organic photovoltaic *** structure of solvent-cast active layers is a result of phase separation in mixtures of donor and acceptor *** a large extent,this process depends on the interactions between the components of the ***,we present a systematic analysis of the morphology of poly[N-9'-heptadecanyl-2,7-carbazole-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)](PCDTBT)and[6,6]-phenyl-C71-butyric acid methyl ester(PC70BM)films in terms of the ternary phase *** interaction parameters between PCDTBT and four different solvents,namely chloroform,chlorobenzene,o-dichlorobenzene,and toluene,were estimated based on swelling *** on these values,ternary phase diagrams of PCDTBT:PC70BM in different solvents were *** morphology of spin-coated films with different blend ratios cast from different solvents is discussed in terms of the obtained phase diagrams.

关键词： PCDTBT ternary phase diagrams Interaction parameter Swelling

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Optimal parameter space for stabilizing the ferroelectric phase of Hf_(0.5)Zr_(0.5)O_(2) thin films under strain and electric fields

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Chinese Physics B 2024年第7期33卷 509-517页

作者：王侣锦王聪周霖蔚周谐宇潘宇浩吴幸季威 Beijing Key Laboratory of Optoelectronic Functional Materials&Micro-Nano Devices Department of PhysicsRenmin University of ChinaBeijing 100872China Key Laboratory of Quantum State Construction and Manipulation(Ministry of Education) Renmin University of ChinaBeijing 100872China In Situ Devices Center School of Integrated CircuitsEast China Normal UniversityShanghai 200241China

Hafnia-based ferroelectric materials, like Hf_(0.5)Zr_(0.5)O_(2)(HZO), have received tremendous attention owing to their potentials for building ultra-thin ferroelectric devices. The orthorhombic(O)-phase of HZO is ferroelectric but metastable in its bulk form under ambient conditions, which poses a considerable challenge to maintaining the operation performance of HZO-based ferroelectric devices. Here, we theoretically addressed this issue that provides parameter spaces for stabilizing the O-phase of HZO thin-films under various conditions. Three mechanisms were found to be capable of lowering the relative energy of the O-phase, namely, more significant surface-bulk portion of(111) surfaces, compressive c-axis strain,and positive electric fields. Considering these mechanisms, we plotted two ternary phase diagrams for HZO thin-films where the strain was applied along the in-plane uniaxial and biaxial, respectively. These diagrams indicate the O-phase could be stabilized by solely shrinking the film-thickness below 12.26 nm, ascribed to its lower surface energies. All these results shed considerable light on designing more robust and higher-performance ferroelectric devices.

关键词： Hf_(0.5)Zr_(0.5)O_(2) orthorhombic phase ferroelectric films phase stability thickness-dependent ternary phase diagrams

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CALCULATION OF NaCl-BaCl_2-SrCl_2 phase DIAGRAM

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Acta Metallurgica Sinica(English Letters) 1989年第12期2卷 380-385页

作者： LI Ruiqing Beijing General Research Institute for Non-ferrous Metals,Beijing,ChinaZHOU Guozhi University of Science and Technology Beijing,Beijing,China

The mathematical formulas are given for calculating the partial molar thermodynamic proper- ties in a ternary system from its three corresponding binary systems based on the new ternary symmetric model presented by the authors in the foregoing *** this model to NaCl-BaCl_2-SrCl_2 system,the phase diagram of which as well as some isothermal sections have been *** devations of temperature between the calculated and experimen- tal diagrams are less than five degrees.

关键词： symmetric geometry model ternary phase diagrams NaCl-BaCl_2-SrCl_2 molten salts system

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Synthesis and Characterization of <i>Citrus limonum</i>Essential Oil Based Nanoemulsion and Its Enhanced Antioxidant Activity with Stability for Transdermal Application

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Journal of Biomaterials and Nanobiotechnology 2020年第4期11卷 215-236页

作者： Harleen Kaur Pranav Pancham Ramneek Kaur Shriya Agarwal Manisha Singh Amity Institute of Biotechnology Amity University Noida U.P. India Department of Biotechnology Jaypee Institute of Information Technology (JIIT) Noida U.P. India School of Medicine Western Sydney University Campbelltown New South Wales Australia

Lemon oil (LO), also known as Citrus limonum is a highly volatile essential oil (EO) with potential therapeutic properties like anti-oxidative, anti-proliferative, anti-fungal and anti-cancerous. However, the efficacy of LO is limited due to its physiological factors such as high volatility, poor stability (particularly sensitive to sunlight) and quick degradability upon exposure. To overcome these challenges, we formulated lemon oil loaded nanoemulsion system (LO-NE) (oil-in-water), using aqueous titration method. The formulation comprised of lemon oil (LO), Tween 80 and ethanol as oil, surfactant and co-surfactant phases respectively. The existence zone of NE was established by constructing pseudo-ternary phase diagrams using different concentrations of LO, surfactant and co-surfactant (Smix). The quantitative estimation of LO was performed using a high throughput gas chromatography, revealing the presence of various compounds like Limonene, Alpha-Pinene and Linalyl acetate followed by the estimation of total phenolics and flavonoid content. The characterization of LO-NE indicated the particle size of 60 ± 2.5 nm along with the polydispersity index of 0.125 and zeta potential of −14.9 mV. The size range of the NE particles dispersed in the colloidal system was further verified by TEM micrograph which shows size range between 46.2 - 104.7 nm. All the anti-oxidant assays outcomes exhibited the higher activity of LO-NE in comparison to LO alone with lower IC50 values. The release kinetics statistical data showed that LO-NE had a sustained release and followed the Higuchi’s model in comparison to burst release of LO alone. Lastly, the stability analysis of the optimised formulation (LO-NE) and LO was estimated through antioxidant assay and subjecting them for thermodynamic stability after 6 months. The results attained, showed higher stability and anti-oxidant capability of LO-NE than LO alo

关键词： Lemon Oil Surfactants Particle Size Analysis ternary phase diagrams Release Kinetics Thermodynamic Stability

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