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Responsive switchable deep eutectic solvents:A review

Chinese Chemical Letters 2023年第5期34卷 25-37页

作者： Jingyu Zhang Shang Li Liping Yao Yuexing Yi Lingqi Shen Zuguang Li Hongdeng Qiu College of Chemical Engineering Zhejiang University of TechnologyHangzhou 310014China College of Materials Science and Engineering Zhejiang University of TechnologyHangzhou 310014China CAS key laboratory of Chemistry of Northwestern Plant Resources/Key Laboratory for Natural Medicine of Gansu Province Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou 730000China

Deep eutectic solvents(DESs)have drawn considerable attention as a new type of green solvent since they were *** studies have shown that DESs have the potential to be used as“designable”solvents,which means that the precursors of DESs with different structures and properties can be screened to customize DESs for specific *** have found that during the sample preparation process involving DESs,the specific properties of some“smart”DESs can be switched by directing external driving forces,leading to a reversible phase transition of the target ***"smart"DESs are called switchable deep eutectic solvents(SDESs).The advent of SDES simplifies the sample pretreatment steps,reduces the use of organic solvents,and makes solvents easy to recycle,which matches the concept of green and sustainable *** with the number of previous experimental studies,the reviews and summaries on SDESs are ***,this review made a summary of the concept and research progress of SDESs based on some related works in the past decade,including composition and type,characterization,switching mechanism,*** is expected to provide a certain reference and guidance for the subsequent in-depth research of SDESs in the analytical sample pretreatment.

关键词： Deep eutectic solvents switchable solvents Reversible phase transition Sample preparation Review

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