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Cancer risk assessment from exposure to trihalomethanes in tap water and swimming pool water

Journal of Environmental Sciences 2008年第3期20卷 372-378页

作者： PANYAKAPO Mallika SOONTORNCHAI Sarisak PAOPUREE Pongsri Department of Environmental Science Faculty of Science Silpakorn University Nakhon Pathom 73000 Thailand. School of Health Science Sukhothai Thammathirat Open University Nonthaburi 11120 Thailand

We investigated the concentration of trihalomethanes （THMs） in tap water and swimming pool water in the area of the Nakhon Path- om Municipality during the period April 2005-March 2006. The concentrations of total THMs, chloroform, bromodichloromethane, dibromochloromethane and bromoform in tap water were 12.70-41.74, 6.72-29.19, 1.12-11.75, 0.63-3.55 and 0.08-3.40 μg/L, respectively, whereas those in swimming pool water were 26.15-65.09, 9.50-36.97, 8.90-18.01, 5.19-22.78 and ND-6.56 μg/L, respectively. It implied that the concentration of THMs in swimming pool water was higher than those in tap water, particularly, brominated-THMs. Both tap water and swimming pool water contained concentrations of total THMs below the standards of the World Health Organization （WHO）, European Union （EU） and the United States Environmental Protection Agency （USEPA） phase Ⅰ, but 1 out of 60 tap water samples and 60 out of 72 swimming pool water samples contained those over the Standard of the USEPA phase Ⅱ. From the two cases of cancer risk assessment including Case Ⅰ Non-Swimmer and Case Ⅱ Swimmer, assessment of cancer risk of nonswimmers from exposure to THMs at the highest and the average concentrations was 4.43×10^-5 and 2.19×10^-5, respectively, which can be classified as acceptable risk according to the Standard of USEPA. Assessment of cancer risk of swimmers from exposure to THMs at the highest and the average concentrations was 1.47×10^-3 and 7.99×10^-4, respectively, which can be classified as unacceptable risk and needs to be improved. Risk of THMs exposure from swimming was 93.9%-94.2% of the total risk. Cancer risk of THMs concluded from various routes in descending order was： skin exposure while swimming, gastro-intestinal exposure from tap water intake, and skin exposure to tap water and gastro-intestinal exposure while swimming. Cancer risk from skin exposure while swimming was 94.18% of the total cancer risk.

关键词： tap water swimming pool water chlorination trihalomethanes cancer risk assessment

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Disinfection byproducts in indoor swimming pool water: Detection and human lifetime health risk assessment

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Journal of Environmental Sciences 2023年第4期126卷 378-386页

作者： Di Zhang Shengkun Dong Li Chen Rong Xiao Wenhai Chu State Key Laboratory of Pollution Control and Resources Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China Southern Laboratory of Ocean Science and Engineering Key Laboratory of Water Cycle and Water Security in Southern China of Guangdong Higher Education InstituteSun Yat-sen UniversityGuangzhou 510275China

Quantification of regulated and emerging disinfection byproducts (DBPs) in swimming pool water,as well as the assessment of their lifetime health risk are limited in *** this study,the occurrence of regulated DBPs (e.g.,trihalomethanes,haloacetic acids) and emerging DBPs (e.g.,haloacetonitriles,haloacetaldehydes) in indoor swimming pool water and the corresponding source water at a city in Eastern China were *** concentrations of DBPs in swimming pool water were 1-2 orders of magnitude higher than that in source *** cancer and non-cancer risks of DBPs stemming from swimming pool water were also *** and dermal exposure were the most significant exposure routes related to swimming pool DBP cancer and non-cancer *** the first time,buccal and aural exposure were considered,and were proven to be important routes of DBP exposure (accounting for 17.9%-38.9%of total risk).The cancer risks of DBPs for all swimmers were higher than 10^(-6)of lifetime exposure risk recommended by United States Environmental Protection Agency,and the competitive adult swimmers experienced the highest cancer risk (7.82×10^(-5)).These findings provide important information and perspectives for future efforts to lower the health risks associated with exposure to DBPs in swimming pool water.

关键词： Health risk assessment swimming pool water Disinfection byproducts Multiple exposure pathway

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Determination of Cyanuric Acid in Milk Powder and swimming pool water by Ion-pair Reversed-phase Liquid Chromatography

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Chinese Journal of Chemistry 2011年第4期29卷 783-786页

作者：侯升杰丁明玉 Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology Ministry of Education Department of Chemistry Tsinghua University Beijing 100084 China

An ion-pair reversed-phase high-performance liquid chromatographic method, using tetrabutylammonium bromide （TBAB） as ion-pair reagent, has been developed for the analysis of cyanuric acid （CA） in milk powder and swimming pool water. It was found that the effect of the concentrations of ion-pair reagent on the retention of cyanuric acid was different for standard solution and different real samples. The separation was carried out on a reversed-phase C18 column with 85 ： 15 （V/V） water-acetonitrile （ACN） containing different concentration of TBAB as mobile phase for different samples. The linear range of the calibration curve for CA was 0.1-100 mg·L^-1 The detection limits calculated at S/N=3 was 0.11 mg-L^-1 for the analysis of milk powder and 0.31 mg·L^-1 for the analysis of swimming pool water, respectively. The method was successfully applied to the analysis of CA in milk powder and swimming pool water.

关键词： ion-pair liquid chromatography cyanuric acid milk powder swimming pool water

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