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Smart Molecules 2023年第1期1卷 52-71页

作者： Fang Mei Hongyu Lin Lianrui Hu Wei-Tao Dou Hai-Bo Yang Lin Xu Shanghai Key Laboratory of Green chemistry and Chemical Processes Shanghai Frontiers Science Center of Molecule Intelligent SynthesesSchool of Chemistry and Molecular EngineeringEast China Normal UniversityShanghaiChina

Microfluidics has received extensive attention due to its ability to rapidly prepare a large number of microdroplets with controlled sizes and defined *** addition to having large surface areas and controllable confinement environments,these prepared microdroplets can be used as analytical detection devices to screen and optimize various kinetic *** review summarizes recent advances in the microfluidic control of droplet-based catalytic reactions and discusses the role of these droplets in both homogeneous and heterogeneous catalyzes and in the catalysis of macromolecular biological enzymes in water-in-oil and oil-in-oil ***,the existing problems and future development directions of droplets in catalysis are highlighted to promote the development of catalytic reactions in droplet media and provide guidance for the high-throughput screening of catalysts and the directed evolution of biological enzymes.

关键词： enzyme catalysis heterogeneous catalysis homogeneous catalysis microfluidic droplet supramolecular chemistry

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[2]Biphenyl-extended pillar[6]arene functionalized silver nanoparticles for catalysis and label-free detection

Smart Molecules

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Smart Molecules 2023年第3期1卷 113-119页

作者： Dongxia Li Gengxin Wu Xin Wang Jia-Rui Wu Ying-Wei Yang International Joint Research Laboratory of Nano-Micro Architecture chemistry College of ChemistryJilin UniversityChangchunChina Key Laboratory of Automobile Materials of Ministry of Education and School of Materials Science and Engineering Jilin UniversityChangchunChina

Synthetic macrocycles have served as principal tools for supramolecular chemistry since their establishment,and the investigation of macrocycles-aided organicinorganic hybrid nanomaterials has also attracted broad interest in chemistry and material communities during the past decade owing to their widespread applications in optical sensing,catalytic degradation,biomedicine,and other related ***,a new class of silver nanoparticles(AgNPs)modified by anionic watersoluble[2]biphenyl-extended pillar[6]arene(WBpP6),namely WBpP6-AgNPs,is designed and synthesized through a facile one-pot ***6-AgNPs with good dispersion and stability exhibit efficient catalytic properties toward the hydrogenation of a series of aromatic nitro compounds and also show good performance in label-free detection toward diquat.

关键词： catalysis host-guest chemistry macrocyclic chemistry organic-inorganic hybrid nanomaterials supramolecular chemistry

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