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Understanding sulfur redox Mechanisms in Different Electrolytes for Room-Temperature Na-S Batteries

Nano-Micro Letters 2021年第8期13卷 107-120页

作者： Hanwen Liu Wei-Hong Lai Qiuran Yang Yaojie Lei Can Wu Nana Wang Yun-Xiao Wang Shu-Lei Chou Hua Kun Liu Shi Xue Dou Institute for Superconducting and Electronic Materials Australian Institute of Innovative MaterialsUniversity of WollongongInnovation CampusSquires WayNorth WollongongNSW 2500Australia

This work reports influence of two different electrolytes,carbonate ester and ether electrolytes,on the sulfur redox reactions in room-temperature Na-S *** sulfur cathodes with different S loading ratio and status are investigated.A sulfur-rich composite with most sulfur dispersed on the surface of a carbon host can realize a high loading ratio(72%S).In contrast,a confined sulfur sample can encapsulate S into the pores of the carbon host with a low loading ratio(44%S).In carbonate ester electrolyte,only the sulfur trapped in porous structures is active via‘solid-solid’behavior during *** S cathode with high surface sulfur shows poor reversible capacity because of the severe side reactions between the surface polysulfides and the carbonate ester *** improve the capacity of the sulfur-rich cathode,ether electrolyte with NaNO_(3) additive is explored to realize a‘solid-liquid’sulfur redox process and confine the shuttle effect of the dissolved *** a result,the sulfur-rich cathode achieved high reversible capacity(483 mAh g^(−1)),corresponding to a specific energy of 362 Wh kg^(−1) after 200 cycles,shedding light on the use of ether electrolyte for high-loading sulfur cathode.

关键词： Room-temperature sodium-sulfur batteries Carbonate ester electrolyte Ether electrolyte sulfur cathode sulfur redox reactions

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Towards full demonstration of high areal loading sulfur cathode in lithium–sulfur batteries

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Journal of Energy Chemistry 2019年第12期28卷 17-22页

作者： Long Kong Qi Jin Xi-Tian Zhang Bo-Quan Li Jin-Xiu Chen Wan-Cheng Zhu Jia-Qi Huang Qiang Zhang Beijing Key Laboratory o f Green Chemical Reaction Engineering and Technology Department of Chemical Engineering Tsinghua UniversityBeijing 100084China Key Laboratory for Photonic and Electronic Bandgap Materials Ministry of EducationSchool of Physics and Electronic EngineeringHarbin Normal UniversityHarbin 150025HeilongjiangChina Department of Chemical Engineering Qufu Normal UniversityQufu 273165ShandongChina Advanced Research Institute of Multidisciplinary Science Beijing Institute of TechnologyBeijing 100081China

Lithium–sulfur(Li–S)batteries have been recognized as promising substitutes for current energy-storage technologies owing to their exceptional advantages in very high-energy density and excellent material *** cathode with high sulfur areal loading is vital for the practical applications of Li–S batteries with very high energy ***,the high sulfur loading in an electrode results in poor rate and cycling performances of batteries in most ***,we used diameters of 5.0(D5)and 13.0(D13)mm to probe the effect of electrodes with different sizes on the rate and cycling performances under a high sulfur loading(4.5 mg cm^-2).The cell with D5 sulfur cathode exhibits better rate and cycling performances comparing with a large(D13)*** the high concentration of lithium polysulfides and corrosion of lithium metal anode impede rapid kinetics of sulfur redox reactions,which results in inferior battery performance of the Li–S cell with large diameter *** work highlights the importance of rational matching of the large sulfur cathode with a high areal sulfur loading,carbon modified separators,organic electrolyte,and Li metal anode in a pouch cell,wherein the sulfur redox kinetics and lithium metal protection should be carefully considered under the flooded lithium polysulfide conditions in a working Li–S battery.

关键词： Lithium sulfur batteries High areal sulfur loading Lithium anode protection sulfur redox reactions Polysulfide interm ediates

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The formation of crystalline lithium sulfide on electrocatalytic surfaces in lithium-sulfur batteries

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Journal of Energy Chemistry 2022年第1期31卷 568-573,I0015页

作者： Yun-Wei Song Jin-Lei Qin Chang-Xin Zhao Meng Zhao Li-Peng Hou Yan-Qi Peng Hong-Jie Peng Bo-Quan Li Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology Department of Chemical EngineeringTsinghua UniversityBeijing 100084China Advanced Research Institute of Multidisciplinary Science Beijing Institute of TechnologyBeijing 100081China Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengduSichuan 611731China

Lithium-sulfur(Li-S)battery is highly regarded as a promising next-generation energy storage device but suffers from sluggish sulfur redox *** the behavior and mechanism of the sulfur species on electrocatalytic surface is the first step to rationally introduce polysulfide electrocatalysts for kinetic promotion in a working ***,crystalline lithium sulfide(Li_(2)S)is exclusively observed on electrocatalytic surface with uniform spherical morphology while Li_(2)S on non-electrocatalytic surface is amorphous and *** characterization indicates the crystalline Li_(2)S preferentially participates in the discharge/charge process to render reduced interfacial resistance,high sulfur utilization,and activated sulfur redox ***,crystalline Li_(2)S is proposed with thermodynamic and kinetic advantages to rati on alize the superior performances of Li-S *** evoluti on of solid Li_(2)S on electrocatalytic surface not only addresses the polysulfide electrocatalysis strategy,but also inspires further investigation into the chemistry of energy-related processes.

关键词： Lithium-sulfur batteries Polysulfide electrocatalysis Lithium sulfide Framework porphyrin sulfur redox reactions

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