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Felsic Igneous Rocks in the Hua'aobaote Pb-Zn-Ag Polymetallic Orefield,southern great xing'an range:Genesis,Metallogenetic and Tectonic Significance

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Acta Geologica Sinica(English Edition) 2022年第1期96卷 221-239页

作者： SHANG Zhi CHEN Yongqing GUO Xiangguo School of Earth Sciences and Resources China University of GeosciencesBeijing 100083China College of Mining Inner Mongolia University of TechnologyHohhot 010051China

The Hua’aobaote Pb-Zn-Ag Polymetallic orefield is situated in the southern section of the great xing’an range(GXAR),which has experienced extensive magmatism.Since the Paleozoic,there are two stages of magmatism in Hua’aobaote orefield occurred in the Paleozoic and Mesozoic.The Mesozoic magmatism is of great significance for the PbZn-Ag Polymetallic mineralization in Hua’aobaote orefield.In this study,new geochemical data was obtained to discuss the timing and petrogenesis of the magmatic rocks and its geodynamic and metallogenic significance.Zircon U-Pb ages reveal that the felsic igneous rocks from the Hua’aobaote orefield were formed in the Early Permian(294.8±3.2 Ma)and Early Cretaceous(132.6±1.4 Ma).Geochemically,the Early Permian granodiorite porphyrite is characterized by high Sr/Y(42-63)ratios and Mg^(#)(62.24-70.74)values and low heavy rare earth element(HREE)(5.09-6.79 ppm)contents.The granodiorite porphyrite is also characterized by depleted Sr-Nd initial isotopic signatures[ε_(Nd)(t)=5.91-7.59,(^(87)Sr/^(86)Sr)i=0.7029-0.7030],exhibiting adakitic characteristics.The Early Cretaceous granite porphyry and rhyolite are A-type felsic igneous rocks,and demonstrate high SiO_(2),Na_(2)O+K_(2)O and rare earth element(REE)contents,low CaO and MgO contents,low(^(87)Sr/^(86)Sr)i ratios(0.7044-0.7058),and positive ε_(Nd)(t)values(2.57-4.65).Whole-rock Pb isotopic compositions in granodiorite porphyrite are:206Pb/204Pb=17.631-18.149,^(207)Pb/^(204)Pb=15.422-15.450,and ^(208)Pb/^(204)Pb=37.325-37.729.The granite porphyry and rhyolite have initial ^(206)Pb/^(204)Pb,^(207)Pb/^(204)Pb,and ^(208)Pb/^(204)Pb ratios of 18.106-19.309,15.489-15.539,and 37.821-38.05,respectively.Sr-Nd-Pb isotopic evidence suggests that the Early Permian granodiorite porphyrite is likely to derive from slab melts and modified by peridotitic mantle wedge in the subduction tectonic setting of the Paleo-Asian Ocean.The Early Cretaceous A-type felsic igneous rocks were derived from juvenile lower crust,accompanied by limited crustal contaminatio

关键词： southern great xing’an range Hua’aobaote zircon U-Pb age Sr-Nd-Pb isotopes metallogenetic and tectonic significance petrogenesis

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Timing of the formation of the Baiyinnuo'er skarn Zn–Pb deposit,NE China:evidence from sulfide Rb–Sr dating

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Acta Geochimica 2022年第2期41卷 185-196页

作者： Yixin Li Qihai Shu Xudong Niu Fan Yu Qingwen Zeng Liangmin Wei Yang Xiao Xianglin Dai State Key Laboratory of Geological Processes and Mineral Resources School of Earth Sciences and ResourcesChina University of GeosciencesBeijing 100083China Chifeng Hongling Nonferrous Mining Co.Ltd.(Shandong Gold Group) Chifeng 025420Inner MongoliaChina

The Baiyinnuo’er deposit in northern China is located in the south section of the great xing’an range,and it is the largest skarn Zn–Pb deposit in the region.Skarn and Zn–Pb orebodies mainly occur between the different units of the Permian Huanggangliang Formation,or within the contact zone between the intrusive rocks and the marble.Although Baiyinnuo’er has been well investigated previously,the timing of the Zn–Pb mineralization is still controversial,largely due to the lack of appropriate ore or alteration minerals that could be directly used for isotopic dating.In this study,we report the results of Rb–Sr isotopic analysis for sphalerite and pyrite samples from the Baiyinnuo’er orebodies,which yielded two isochron ages of 137.4±3.4 and 140.0±7.8 Ma,respectively,constraining the Zn–Pb mineralization time of the deposit as the Early Cretaceous.The data are also consistent with the age of the granitoids in the mining area,indicating a potential genetic relationship between the Early Cretaceous magmatism and mineralization.Many other intrusion-related hydrothermal deposits(including the two typical skarns,Huanggang and Haobugao)in the southern great xing’an range also share similar mineralization ages(i.e.,140–130 Ma).Together,these data suggest an Early Cretaceous mineralization event in this region,and this largescale mineralization could be related to the regional tectonic regime transition from compression to extension as a result of the rollback of the subducted Paleo-Pacific plate.The initial87 Sr/86 Sr ratios of the sphalerite and pyrite samples are 0.70569 and 0.70616,respectively,implying that the ore-forming material could have a significant contribution from the mantle components.The current study shows that sulfide Rb–Sr dating could be used in deciphering the timing of skarn deposit formation.

关键词： Rb-Sr dating Sphalerite and pyrite Skarn Zn-Pb deposit Baiyinnuo’er southern great xing’an range

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Fluid inclusions,C-H-O-S-Pb isotope systematics,geochronology and geochemistry of the Budunhua Cu deposit,northeast China:Implications for ore genesis

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Geoscience Frontiers 2020年第4期11卷 1145-1161页

作者： Kaituo Shi Keyong Wang Xueli Ma Shunda Li Jian Li Rui Wang College of Earth Sciences Jilin UniversityChangchun130061China College of Geology and Mining Engineering Xinjiang UniversityUrumqi830047China MNR Key Laboratory of Mineral Resources Evaluation in Northeast Asia Changchun130061China

The Budunhua Cu deposit is located in the Tuquan ore-concentrated area of the southern great xing’an range,NE China.This deposit includes the southern Jinjiling and northern Kongqueshan ore blocks,separated by the Budunhua granitic pluton.Cu mineralization occurs mainly as stockworks or veins in the outer contact zone between tonalite porphyry and Permian metasandstone.The ore-forming process can be divided into four stages involving stage Ⅰ quartz-pyrite-arsenopyrite;stage Ⅱ quartz-pyrite-chalcopyrite-pyrrhotite;stage Ⅲ quartz--polynetallic sulfides;and stage IV quartz-calcite.Three types of fluid inclusions(FIs) can be distinguished in the Budunhua deposit:liquid-rich two-phase aqueous FIs(L-type),vapour-rich aqueous FIs(V-type),and daughter mineral-bearing multi-phase FIs(S-type).Quartz of stages Ⅰ-Ⅲ contains all types of FIs,whereas only L-type FIs are evident in stage Ⅳ veins.The coexisting V-and S-type FIs of stages Ⅰ-Ⅲ have similar homogenization temperatures but contrasting salinities,which indicates that fluid boiling occurred.The FIs of stages Ⅰ,Ⅱ,Ⅲ,and Ⅳyield homogenization temperatures of 265-396℃,245-350℃,200-300℃,and 90-228℃ with salinities of3.4-44.3 wt.%,2.9-40.2 wt.%,1.4-38.2 wt.%,and 0.9-9.2 wt.% NaCl eqv.,respectively.Ore-forming fluids of the Budunhua deposit are characterized by high temperatures,moderate salinities,and relatively oxidizing conditions typical of an H2 O-NaCl fluid system.Mineralization in the Budunhua deposit occurred at a depth of0.3-1.5 km,with fluid boiling and mixing likely being responsible for ore precipitation.C-H-O-S-Pb isotope studies indicate a predominantly magmatic origin for the ore-forming fluids and materials.LA-ICP-MS zircon U-Pb analyses indicate that ore-forming tonalite porphyry and post-ore dioritic porphyrite were formed at 151.1±1.1 Ma and 129.9±1.9 Ma,respectively.Geochemical data imply that the primary magma of the tonalite porphyry formed through partial melting of Neoproterozoic lower crust.On the basis of available evidence,we suggest that the Budun

关键词： Fluid inclusion C-H-O-S-Pb isotopes Zircon U-Pb geochronology Whole-rock geochemistry Budunhua Cu deposit southern great xing’an range

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