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source apportionment and suitability evaluation of seasonal VOCs contaminants in the soil around a typical refining-chemical integration park in China

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Journal of Environmental Sciences 2024年第3期137卷 651-663页

作者： Xu Zhao Jing Meng Qianqian Li Guijin Su Qifan Zhang Bin Shi Lingwen Dai Yong Yu Key Laboratory of Environmental Nanotechnology and Health Effects State Key Laboratory of Environmental Chemistry and EcotoxicologyResearch Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China University of Chinese Academy of Sciences Beijing 100049China State Environmental Protection Key Laboratory of Quality Control in Environmental Monitoring China National Environmental Monitoring CenterBeijing 100012China

Accurate source apportionment of volatile organic compounds(VOCs)in soil nearby petrochemical industries prevailing globally,is critical for preventing pollution.However,in the process,seasonal effect on contamination pathways and accumulation of soil VOCs is often neglected.Herein,Yanshan Refining-Chemical Integration Park,including a carpet,refining,synthetic rubber,and two synthetic resin zones,was selected for traceability.Season variations resulted in a gradual decrease of 31 VOCs in soil from winter to summer.A method of dry deposition resistance model coupling partitioning coefficient model was created,revealing that dry deposition by gas phase was the primary pathway for VOCs to enter soil in winter and spring,with 100 times higher fux than by particle phase.Source profiles for five zones were built by gas sampling with distinct substance indicators screened,which were used for positive matrix factorization factors determination.Contributions of the five zones were 14.9%,20.8%,13.6%,22.1%,and 28.6%in winter and 33.4%,12.5%,10.7%,24.9%,and 18.5%in spring,respectively.The variation in the soil sorption capacity of VOCs causes inter-seasonal differences in contribution.The better correlation between dry deposition capacity and soil storage of VOCs made root mean square and mean absolute errors decrease averagely by 8.8%and 5.5%in winter compared to spring.This study provides new perspectives and methods for the source apportionment of soil VOCs contamination in industrial sites.

关键词： Dry deposition resistance model Positive matrix factorization model Partitioning coefficient model Contamination pathway Source profile

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Size distribution and chemical characteristics of particles from crop residue open burning in North China

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Journal of Environmental Sciences 2021年第11期33卷 66-76页

作者： Tingkun Li Qili Dai Xiaohui Bi Jianhui Wu Yufen Zhang Yinchang Feng State Environmental Protection Key Laboratory of Urban Ambient Air Particulate Matter Pollution Prevention and Control College of Environmental Science and EngineeringNankai UniversityTianjin300350China.

Crop residue open burning is an important emission source of ambient particles in China.This study analyzed the particle emission characteristics of crop residue open burning through combustion experiments with a novel open combustion simulation device using three typical crop straws in north China(corn,wheat,and rice).Particle samples size ranging from 0.006–9.890μm were collected by an Electrical Low Pressure Impactor plus,a high size-resolution instrument capable of dividing particles into 14 size stages.The size distributions of organic carbon(OC),elemental carbon(EC),water-soluble ions,and elements were analyzed,and source chemical profiles were constructed for PM0.1,PM1,PM2.5,and PM10.The number concentration of particles was concentrated in the Aiken nuclei mode(0.006–0.054μm),accounting for 75%of the total number,whereas the mass concentration was concentrated in the accumulation mode(0.054–0.949μm),accounting for 85.43%of the mass loading.OC,EC,Cl−,and K(include total K and water-soluble K)were the major chemical components of the particles,whose mass percentage distributions differed from those of other components.These fivemain components exhibited a bell-shaped size distribution in the 0.006–9.890μm range,whereas the other components exhibited a U-shaped distribution.Among the chemical profiles for PM0.1–PM10,OC was the most important component at 10–30%,followed by EC at 2%–8%.The proportions of K^(+),Cl^(−),and K varied substantially in different experimental groups,ranging from 0–15%,and K+and Cl−were significantly correlated(r=0.878,α=0.000).

关键词： Crop residue Open burning Size distribution Source profile Electrical Low Pressure Impactor plus(ELPI+)

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Development of Source profiles and their application in source apportionment of PM2.5 in Xiamen, China

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Frontiers of Environmental Science & Engineering 2016年第5期10卷 177-189页

作者： Ningning Zhang Mazhan Zhuang Jie Tian Pengshan Tian Jieru Zhang Qiyuan Wang Yaqing Zhou Rujin Huang Chongshu Zhu Xuemin Zhang Junji Cao Key Laboratory of Aerosol Chemistry and Physics Institute of Earth Environment Chinese Academy of Sciences Xi'an 710061 China Xiamen Environmental Monitoring Central Station Xiamen 361012 China IER Environmental Protection Engineering Technique Co. Ltd. Shenzhen 518055 China Laboratory of Atmospheric Chemistry Paul Scherrer Institute (PSI) 5232 Villigen Switzerland Centre for Atmospheric and Environmental Studies Xiamen Huaxia University Xiamen 361024 China Institute of Global Environmental Change Xi'an Jiaotong University Xi'an 710049 China

Ambient PM2.5 samples were collected at four sites in Xiamen, including Gulangyu （GLY）. Hongwen （HW）, Huli （HL） and Jimei （JM） during January, April, July and October 2013. Local source samples were obtained from coal burning power plants, industries, motor vehicles, biomass burning, fugitive dust, and sea salt for the source apportionment studies. The highest value of PM2.5 mass concentration and species related to human activities （SO42- , NO3 , Pb, Ni, V, Cu, Cd, organic carbon （OC） andelemental carbon （EC）） were found in the ambient-samples from HL, and t-he highest and lowest loadings of PM2.5 and its components occurred in winter and summer, respectively. The reconstructed mass balance indicated that ambient PM2.5 consisted of 24% OM （organic matter）, 23% sulfate, 14% nitrate, 9% ammonium, 9% geological material, 6% sea salt, 5% EC and 10% others. For the Source profiles, the dominant components were OC for coal burning, motor vehicle, biomass burning and sea salt; SO42 for industry; and crustal elements for fugitive dust. source contributions were calculatedusing a chemical mass＇balance （CMB） model basedon ambient PM2.5 concentrations and the Source profiles. GLY was characterized by high contributions from secondary sulfate and cooking, while HL and JM were most strongly affected by motor vehicle emissions, and biomass burning and fugitivedust, respectively. The CMB results-indicated that PM2.5 from Xiamen is composed of 27.4% secondary inorganic components, 20.8% motor vehicle emissions, 11.7% fugitive dust, 9.9% sea salt, 9.3% coal burning, 5.0% biomass burning, 3.1% industry and 6.8% others.

关键词： PM2.5 Source profile source apportionment CMB Xiamen

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Source profiles of particulate organic matters emitted from cereal straw burnings

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Journal of Environmental Sciences 2007年第2期19卷 167-175页

作者： ZHANG Yuan-xun SHAO Min ZHANG Yuan-hang ZENG Li-min HE Ling-yan ZHU Bin WEI Yong-jie ZHU Xian-lei State Key Joint Laboratory of Environmental Simulation and Pollution Control College of Environmental Sciences Peking University Beijing 100871 China Shenzhen Graduate School Peking University Shenzhen 518055 China

Cereal straw is one of the most abundant biomass burned in China but its contribution to fine particulates is not adequately understood. In this study, three main kinds of cereal straws were collected from five grain producing areas in China. Fine particulate matters （PMzs） from the cereal straws subjected to control burnings, both under smoldering and flaming status, were sampled by using a custom made dilution chamber and sampling system in the laboratory. Element carbon （EC） and organic carbon （OC） was analyzed. 141 compounds of organic matters were measured by gas chromatography-mass spectrum （GC-MS）. Source profiles of particulate organic matters emitted from cereal straw burnings were obtained. The results indicated that organic matters contribute a large fraction in fine particulate matters. Levoglucosan had the highest contributions with averagely 4.5% in mass of fine particulates and can be considered as the tracer of biomass burnings. Methyloxylated phenols from lignin degradation also had high concentrations in PM2.5, and contained approximately equal amounts of guaiacyl and syringyl compounds. 13-Sitostrol also made up relatively a large fraction of PMz5 compared with the other sterols （0.18%-0.63% of the total fine particle mass）. Normal alkanes, PAHs, fatty acids, as well as normal alkanols had relatively lower concentrations compared with the compounds mentioned above. Carbon preference index （CPI） of normal alkanes and alkanoic acids showed characteristics of biogenic fuel burnings. Burning status significantly influenced the formations of EC and PAHs. The differences between the emission profiles of straw and wood combustions were displayed by the fingerprint compounds, which may be used to identify the contributions between wood and straw burnings in source apportionment researches.

关键词： biomass burning cereal straw particulate organic matter Source profile

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十一届全国气溶胶会议暨第十届海峡两岸气溶胶技术研讨会

作者： Shaofei Kong Yaqin Ji Bing Lu Xueyan Zhao Zhipeng Bai Key Laboratory for Aerosol-Cloud-Precipitation of China Meteorological Administration Nanjing University of Information Science and Technology College of Environmental Science and Engineering Nankai University Chinese Research Academy of Environmental Sciences

PM2.5, PM10 and TSP Source profiles for road dust, soil dust and re-suspended dust were established by adopting a re-suspension chamber in a coastal oilfield city-Dongying in 11/2009-4/2010. Thirty-nine elements, nine ions, organic and elemental carbon were analyzed by multiple methods. Results indicated that Ca, Si, OC, Ca2+, Al, Fe and SO42- were the most abundant species for all the three types of dust within the three fractions. OC/TC ratios were highest for dusts in Dongying when compared with literatures which may be related to the large amounts of oil exploited and consumed. Na, Mg and Na+ in soil and road dust from Dongying also exhibited higher mass percentages than others indicating the influence of sea salt as the city was more adjacent to coastal line. Enrichment factors analysis showed that Cd, Ca, Cu, Zn, Ba, Ni, Pb, Cr, Mg and As were enriched and these elements were tended to concentrate in finer fraction. Similarities of the profiles for different size fractions and different types of dust were compared by coefficient of divergence（CD）. The profiles for different types of dust were different to each other with the CD values mostly higher than 0.30;while the profiles for different size fractions of each dust were similar to each other with the CD values mostly lower or near to 0.30.

关键词： Source profile fugitive dust size-differentiated particle oilfield city

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