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Ultrasensitive determination of mercury by ICP-OES coupled with a vapor generation approach based on solution cathode glow discharge

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Chinese Chemical Letters 2022年第5期33卷 2692-2696页

作者： Zhaoqing Cai Huijun Zou Yirui Chen Zheng Wang Shanghai Institute of Ceramics Chinese Academy of SciencesShanghai 200050China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

We herein proposed a sample introduction technique based on solution cathode glow discharge(SCGD)of a portable design for inductively coupled plasma-optical emission spectrometry(ICP-OES)and its ap-plication in sensitive determination of mercury.The products from SCGD containing mercury vapor,were transported by an Ar flow to ICP spectrometer for detection.A gas liquid separator(GLS)and a dryer were used to condense and remove most of the accompanying moisture,which greatly improved both the stability and sensitivity of the signal.The detection limit(DL)acquired by this developed method was 0.22μg/L(194.1 nm),which was nearly 82 times lower than that obtained by pneumatic nebuliza-tion(PN).The relative standard deviation(RSD)was 1.4%(n=14)for a 50μg/L standard.Blank solution(HNO_(3),pH 1)can effectively elute mercury residue.Its accuracy and practicality were also demonstrated by the determination of GBW10029(fish)certified reference material,shrimp,crawfish,soil and human hair samples.The results showed good consistency with the certified values and the values obtained us-ing inductively coupled plasma−mass spectrometry.

关键词： solution cathode glow discharge Vapor generation ICP-OES Mercury Microplasma

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Systematic evaluation of advance in application and discharge mechanism of solution electrode glow discharge

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Chinese Chemical Letters 2022年第1期33卷 61-70页

作者： Xiaoxu Peng Zheng Wang Shanghai Institute of Ceramics Chinese Academy of SciencesShanghai 200050China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

As a kind of microplasma sustained in air,solution electrode glow discharge(SEGD)ignited between the liquid electrode and metal electrode is attractive to the fields of optical emission spectrometry and mass spectrometry due to its unique advantages,such as low power consumption and low carrier gas consumption.Moreover,the complex and efficient reactions in the liquid phase and plasma phase of SEGD make it considerable research potential in the fields of biology and medicine,material synthesis,electrochemistry.Considering the close relationship between the various fields on SEGD,here we are devoted to provide an overview of the development of SEGD in various fields.More importantly,a systematic discussion on the discharge mechanism is conducted based on the research process in various fields for getting deeper insight into the SEGD.

关键词： solution cathode glow discharge solution anode glow discharge Mass spectrometry Optimal emission spectroscopy discharge mechanism

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