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solid additive-Assisted Layer-by-Layer Processing for 19%Efficiency Binary Organic Solar Cells

Nano-Micro Letters 2023年第7期15卷 16-29页

作者： Guanyu Ding Tianyi Chen Mengting Wang Xinxin Xia Chengliang He Xiangjun Zheng Yaokai Li Di Zhou Xinhui Lu Lijian Zuo Zhikang Xu Hongzheng Chen State Key Laboratory of Silicon Materials Department of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027People’s Republic of China Department of Physics The Chinese University of Hong KongNew TerritoriesHong Kong 999077People’s Republic of China Zhejiang University-Hangzhou Global Scientific and Technological Innovation Center Hangzhou 310014People’s Republic of China MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027People’s Republic of China Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province Zhejiang UniversityHangzhou 310027People’s Republic of China

Morphology is of great significance to the performance of organic solar cells(OSCs),since appropriate morphology could not only promote the exciton dissociation,but also reduce the charge recombination.In this work,we have developed a solid additive-assisted layer-by-layer(SAA-LBL)processing to fabricate high-efficiency OSCs.By adding the solid additive of fatty acid(FA)into polymer donor PM6 solution,controllable pre-phase separation forms between PM6 and FA.This intermixed morphology facilitates the diffusion of acceptor Y6 into the donor PM6 during the LBL processing,due to the good miscibility and fast-solvation of the FA with chloroform solution dripping.Interestingly,this results in the desired morphology with refined phase-separated domain and vertical phase-separation structure to better balance the charge transport/collection and exciton dissociation.Consequently,the binary single junction OSCs based on PM6:Y6 blend reach champion power conversion efficiency(PCE)of 18.16%with SAA-LBL processing,which can be generally applicable to diverse systems,e.g.,the PM6:L8-BO-based devices and thick-film devices.The efficacy of SAA-LBL is confirmed in binary OSCs based on PM6:L8-BO,where record PCEs of 19.02%and 16.44%are realized for devices with 100 and 250 nm active layers,respectively.The work provides a simple but effective way to control the morphology for high-efficiency OSCs and demonstrates the SAA-LBL processing a promising methodology for boosting the industrial manufacturing of OSCs.

关键词： Organic solar cells Fatty acid solid additive Layer-by-layer Vertical phase separation

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High-efficiency organic solar cells enabled by an alcohol-washable solid additive

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Science China Chemistry 2021年第12期64卷 2161-2168页

作者： Yuanpeng Xie Hwa Sook Ryu Lili Han Yunhao Cai Xiaopeng Duan Donghui Wei Han Young Woo Yanming Sun School of Chemistry Beihang UniversityBeijing100191China Department of Chemistry College of ScienceKU-KIST Graduate School of Converging Science and TechnologyKorea UniversitySeoul136-713Korea College of Chemistry and Molecular Engineering Zhengzhou UniversityZhengzhou450001China

The solvent additive strategy has been widely utilized to boost the power conversion efficiency(PCE)of organic solar cells(OSCs).However,the residual solvent additive in the active layer tends to induce a gradual morphology degradation and further influences the long-term stability of OSCs.Here,a solid additive,1,4-diiodobenzene(DIB),was introduced to fabricate efficient OSCs.We found that the treatment of DIB can lead to optimized morphology to form a bicontinuous network with intensified intermolecular packing in the donor and acceptor phases.Notably,DIB can be easily removed from the active layer via a simple alcohol washing process and no further post-thermal annealing is needed,which is desirable for large-scale manufacturing of OSCs.As a result,high efficiencies of 17.47%for PM6:Y6 and 18.13%(certified as 17.7%)for PM6:BTP-eC9 binary OSCs are achieved,which are among the highest efficiencies reported for binary OSCs thus far.Moreover,OSCs fabricated with DIB also exhibit superior stability compared with the as-cast and traditional solvent additive processed devices.Additionally,DIB was successfully applied in different active layers,manifesting its general applicability.This work provides a feasible approach to enhance both the efficiency and stability of OSCs.

关键词： organic solar cells solid additive alcohol washing process efficiency stability

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Synergistic effect of solvent and solid additives on morphology optimization for high-performance organic solar cells

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Science China Chemistry 2021年第11期64卷 2017-2024页

作者： Chenling Fan Hang Yang Qing Zhang Sunan Bao Hongyu Fan Xianming Zhu Chaohua Cui Yongfang Li Laboratory of Advanced Optoelectronic Materials Suzhou Key Laboratory of Novel Semiconductor-Optoelectronics Materials and DevicesCollege of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhou215123China Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Organic SolidsInstitute of ChemistryChinese Academy of SciencesBeijing100190China Vacuum Interconnected Nanotech Workstation Suzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhou215123China

Controlling the photoactive layer morphology towards nanoscale bi-continuous donor/acceptor interpenetrating networks is a key issue to build high-performance organic solar cells(OSCs).Due to the distinct properties between donor and acceptor materials,casting an active layer from a single solvent solution usually results in either insufficient or excessive phase separation that reduces the device performance.In comparison to the fullerene acceptors with closed-cage structures,the currently dominant non-fullerene acceptors possess the similar anisotropicπ-πinteractions with p-type organic semiconductor donors,giving rise to the complexity of the morphology regulation.Herein,we employ 4,4′-dimethoxyoctafluorobiphenyl(OFP)with strong crystallinity as a volatile solid additive to optimize the active layer morphology of OSCs.The synergistic effect of 1-chloronaphthalene(CN)and OFP as dual additives shows supreme capability on optimizing the morphology over the conventional additive of CN,which is in favor of improving charge transport and suppressing charge recombination for higher fill factors in various systems.In particular,the PTQ10:m-BTP-C6 Ph-based device processed by the additive showed a remarkable powerconversion efficiency(PCE)of 17.74%,whereas the control device processed by CN additive yielded a relatively lower PCE of16.45%.

关键词： organic solar cells bulk-heterojunction morphology power conversion efficiency solid additive

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