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Density of states characterization of TiO_(2) films deposited by pulsed laser deposition for heterojunction solar cells

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Nano Research 2022年第5期15卷 4048-4057页

作者： Daniele Scire Roberto Macaluso Mauro Mosca Maria Pia Casaletto Olindo Isabella Miro Zeman Isodiana Crupi Department of Engineering University of PalermoViale delle ScienzeEd.9Palermo 90128Italy Institute of Nanostructured Materials(ISMN) National Research Council(CNR)Via Ugo La Malfa 153Palermo 90146Italy Photovoltaic Materials and Devices Group Delft University of TechnologyMekelweg 4Delft 2628CDthe Netherlands

The application of titanium dioxide(TiO_(2))in the photovoltaic(PV)field is gaining traction as this material can be deployed in doping-free heterojunction solar cells with the role of electron selective contact.For modeling-based optimization of such contact,knowledge of the titanium oxide defect density of states(DOS)is crucial.In this paper,we report a method to extract the defect density through nondestructive optical measures,including the contribution given by small polaron optical transitions.The presence of both related to oxygen-vacancy defects and polarons is supported by the results of optical characterizations and the evaluation of previous observations resulting in a defect band fixed at 1 eV below the conduction band edge of the oxide.solar cells employing pulsed laser deposited-TiO_(2)electron selective contacts were fabricated and characterized.The J-V curve of these cells showed,however,an S-shape,then a detailed analysis of the reasons for such behavior was carried out.We use a model involving the series of a standard cell equivalent circuit with a Schottky junction in order to explain these atypical performances.A good matching between the experimental measurements and the adopted theoretical model was obtained.The extracted parameters are listed and analyzed to shed light on the reasons behind the low-performance cells.

关键词： solar cell heterojunction photovoltaic(PV) defect density small polaron pulsed laser deposition(PLD) titanium dioxide(TiO_(2)) defects

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Enhanced charge separation by interchain hole delocalization in nonfullerene acceptor-based bulk heterojunction materials

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Carbon Energy 2023年第7期5卷 27-37页

作者： Chang-Mok Oh Sujung Park Jihoon Lee Sung Heum Park Shinuk Cho In-Wook Hwang Advanced Photonics Research Institute Gwangju Institute of Science and TechnologyGwangjuRepublic of Korea Department of Physics and Energy Harvest Storage Research Center University of UlsanUlsanRepublic of Korea Department of Physics Pukyong National UniversityBusanRepublic of Korea

Bulk heterojunction(BHJ)composites show improved power conversion efficiencies when optimized in terms of morphology using various film processing methods.A reduced carrier recombination loss in an optimized BHJ was characterized previously.However,the driving force that leads to this reduction was not clearly understood.In this study,we focus on the decreased carrier recombination loss and its driving force in optimized nonfullerene acceptor-based PTB7-Th:IEICO-4F BHJ composites.We demonstrate that the optimized BHJ shows deactivation in the sub-nanosecond nongeminate carrier recombination process.The driving force for this deactivation was determined to be the improved interchain hole delocalization between the polymers.An enhanced interchain hole delocalization was observed using steady-state photoinduced absorption(PIA)spectroscopy.In particular,increased splitting between the polaron PIA bands was noted.Moreover,improved interchain hole delocalization was observed for other state-of-the-art BHJ materials,including D18:Y6 with optimized morphologies.

关键词： bulk heterojunction interchain hole delocalization nonfullerene acceptor photoinduced absorption spectroscopy solar cell

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A-site cation engineering enables oriented Ruddlesden-Popper perovskites towards efficient solar cells

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Science China Chemistry 2022年第12期65卷 2468-2475页

作者： Rui Liu Yue Yu Chang Liu Hua Yang Xiao-Lei Shi Hua Yu Zhi-Gang Chen Institute of Photovoltaics Southwest Petroleum UniversityChengdu610500China Institute of High Energy Physics Chinese Academy of Sciences(CAS)Beijing100049China School of Chemistry and Physics Queensland University of TechnologyBrisbaneQLD4001Australia

Quasi two-dimensional(Q-2D)perovskites with favorable environment stability and satisfied device performance are attracting great attention and becoming star materials.The unique characteristics of more wide range of Goldschmidt tolerance factor endow Q-2D perovskites with exceptional composition tunability and great potential.Herein,Guanidinium(Gua)was firstly introduced into the octahedral cation site of BA_(2)MA_(3)Pb_(4)I_(13) perovskite to partially replace methylammonium(MA).With the incorporation of Gua,the XRD intensity ratio of(202)/(111)increased nearly 100%for control and 0.10Gua-mixed Q-2D perovskite,from1.49 to 2.84,indicating that the layered perovskite crystallization orientation is significantly regulated.Coupling with GIWAXS results,a preferential orientation Q-2D perovskite film was obtained.Meanwhile,the Gua-based Q-2D perovskite exhibits significantly reduced nonradiative recombination,which greatly promotes the efficient transport of carriers leading to a high efficiency of 15.41%in the BA_(2)(MA_(0.9)GA_(0.1))_(3)Pb_(4)I_(13)-based solar cell.Moreover,the solar cells display superior environmental stability at an average humidity of 35%±5%in the air for 1200 h.This work points the way to the regulation of crystal orientation for enhancing the performance of Q-2D perovskite by the A-site cation engineering.

关键词： crystallographic orientation Q-2D perovskite cation engineering solar cell

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Infrared-harvesting colloidal quantum dot inks for efficient photovoltaics: Impact of surface chemistry and device engineering

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Journal of Materials Science & Technology 2023年第16期147卷 224-240页

作者： Younghoon Kim Min-Jae Choi Jongmin Choi Department of Chemistry Kookmin UniversitySeoul02707Republic of Korea Department of Chemical and Biochemical Engineering Dongguk UniversitySeoul04620Republic of Korea Department of Energy Science and Engineering Daegu Gyeongbuk Institute of Science and Technology(DGIST)Daegu42988Republic of Korea

Colloidal quantum dots(CQDs)are promising semiconducting materials,which can be used as a photoactive layer in various optoelectronic applications,because of their size-tunable bandgap energy,solution processability,and excellent optical and optoelectronic properties.In particular,these features have generated great interest in the development of CQD solar cells and led to a rapid increase in their power conversion efficiency.These improvements were enabled by many innovative approaches in terms of CQD’s surface chemistry and device architecture optimizations.In this review,a critical overview of the research progress in CQD solar cells is presented with a focus on the strategies adopted for achieving record efficiency in CQD solar cells.These strategies include the use of organic/inorganic surface ligands,pre-and post-treatment of CQDs,and solid-state/solution-phase ligand exchange.Additionally,we provide an understanding of the research history to inspire the rational design of next-generation CQD optoelectronic devices,such as solar cells,light-emitting diodes,and photodetectors.Recent research on the development of infrared CQD solar cells as complementary platforms to other solar cell technologies is also critically discussed to provide another perspective on CQD technologies.

关键词： Quantum dot Lead sulfide Ligand exchange Colloidal ink Infrared light solar cell

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Ligand exchange engineering of FAPbI_(3) perovskite quantum dots for solar cells

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Frontiers of Optoelectronics 2022年第3期15卷 139-150页

作者： Wentao Fan Qiyuan Gao Xinyi Mei Donglin Jia Jingxuan Chen Junming Qiu Qisen Zhou Xiaoliang Zhang School of Materials Science and Engineering Beihang UniversityBeijing 100191China

Formamidinium lead triiodide(FAPbI_(3))perovskite quantum dots(PQDs)show great advantages in photovoltaic applications due to their ideal bandgap energy,high stability and solution processability.The anti-solvent used for the post-treatment of FAPbI_(3) PQD solid flms signifcantly afects the surface chemistry of the PQDs,and thus the vacancies caused by surface ligand removal inhibit the optoelectronic properties and stability of PQDs.Here,we study the efects of diferent anti-solvents with diferent polarities on FAPbI_(3) PQDs and select a series of organic molecules for surface passivation of PQDs.The results show that methyl acetate could efectively remove surface ligands from the PQD surface without destroying its crystal structure during the post-treatment.The benzamidine hydrochloride(PhFACl)applied as short ligands of PQDs during the post-treatment could fll the A-site and X-site vacancies of PQDs and thus improve the electronic coupling of PQDs.Finally,the PhFACl-based PQD solar cell(PQDSC)achieves a power conversion efciency of 6.4%,compared to that of 4.63%for the conventional PQDSC.This work provides a reference for insights into the surface passivation of PQDs and the improvement in device performance of PQDSCs.

关键词： FAPbI_(3) Perovskite quantum dot Antisolvent Surface passivation solar cell

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Multifunctional indaceno[1,2-b:5,6-b']dithiophene chloride molecule for stable high-efficiency perovskite solar cells

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Science China Chemistry 2023年第1期66卷 185-194页

作者： Yong Li Qian Zhang Lidan Liu Dapeng Wang Zhike Liu Ningyi Yuan Jianning Ding Qiang Wang Shengzhong(Frank) Liu Key Laboratory of Applied Surface and Colloid Chemistry Ministry of EducationShaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringShaanxi Normal UniversityXi'an 710119China Dalian National Laboratory for Clean Energy iChEMDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China School of Materials Science and Engineering Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering Jiangsu Province Cultivation Base for State Key Laboratory of Photovoltaic Science and Technology Changzhou UniversityChangzhou 213164China

The additive strategy has emerged as an effective approach to improving the performance of perovskite solar cells(PSCs).Herein,a small acceptor-donor-acceptor type molecule indaceno[1,2-b:5,6-b’]dithiophene chloride(IDT-Cl)is designed and synthesized to advance both the efficiency and stability of FA_(0.85)MA_(0.15)PbI_(3)PSCs.Within the IDT-Cl molecule,the S-group with high electron density promotes chemical bonding with the lead cations in the perovskite,resulting in enlarged grain size and smoother surface topography of the perovskite absorber.In addition,the undercoordinated lead ions in the perovskite layer may be passivated by the carbonyl group in the 5-chloroindolin-2-one unit,thereby reducing the number of nonradiative recombination centers.Meanwhile,the IDT-Cl adjusts the energy level mismatch between the perovskite and two adjacent carrier transport layers,leading to easy charge collection.By the multifunctional effect of the IDT-Cl molecule,the modified device yields a high power conversion efficiency(PCE)of 24.46%,8.8%higher than that of the control PSC(22.48%).More importantly,the hydrophobic alkyl side-chain of the IDT-Cl molecule further ensures enhanced humidity stability of the perovskite film and environmental,thermal,and light stabilities of the PSC devices.

关键词： non-fullerene multifunctional perovskite solar cell additive defect passivation

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In-situ photoisomerization of azobenzene to inhibit ion-migration for stable high-efficiency perovskite solar cells

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Journal of Energy Chemistry 2022年第10期31卷 556-564,I0014页

作者： Xuejiao Zuo Yiyang He Hongyu Ji Yong Li Xiuying Yang Binxun Yu Tao Wang Zhike Liu Wenliang Huang Jing Gou Ningyi Yuan Jianning Ding Shengzhong Frank Liu Shaanxi Key Laboratory for Advanced Energy Devices Shaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringShaanxi Normal UniversityXi’an 710119ShaanxiChina School of Chemistry and Chemical Engineering Shaanxi Normal UniversityXi’an 710119ShaanxiChina School of Materials Science and Engineering Jiangsu Collaborative Innovation Center of Photovoltaic Science and EngineeringJiangsu Province Cultivation Base for StateKey Laboratory of Photovoltaic Science and TechnologyChangzhou UniversityChangzhou 213164JiangsuChina

Ion migration is a notorious problem in perovskite solar cells(PSCs)that severely mutilates device performance.Herein,a strategy to inhibit ion migration in situ is developed by using photoisomerization of azobenzene(AZO)to immobilize cations in the lattice.During the nucleation process,the photoisomerized cis-AZO reacts with FA^(+),MA^(+)and Pb2+cations in the perovskite precursor by synergistic cation-πinteraction and Lewis base coordination,leading to heterogeneous nucleation to produce uniform perovskite film.Meanwhile,it accelerates conversion of intermediate yellowδ-phase to desired black aphase of FAPb I3for improved crystallinity with well-passivated grain surface.Consequently,defect density is effectively reduced for the perovskite film to demonstrate suppressed carrier recombination and enhanced carrier extraction.Subsequently,the solar cell efficiency is elevated from 21.29%to 23.58%with negligible J-V hysteresis.Long-term stability is also improved,with the bare device without any encapsulation retaining 84%of its initial efficiency after aging 744 hours in ambient.

关键词： Perovskite solar cell Photovoltaic Photoisomerization

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Solvent engineering towards scalable fabrication of high-quality perovskite films for efficient solar modules

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Journal of Energy Chemistry 2023年第5期80卷 689-710,I0015页

作者： Zhaoyi Jiang Binkai Wang Wenjun Zhang Zhichun Yang Mengjie Li Fumeng Ren Tahir Imran Zhenxing Sun Shasha Zhang Yiqiang Zhang Zhiguo Zhao Zonghao Liu Wei Chen Wuhan National Laboratory for Optoelectronics(WNLO) Huazhong University of Science and Technology(HUST)Wuhan 430074HubeiChina China-EU Institute for Clean and Renewable Energy(ICARE) Huazhong University of Science and Technology(HUST)Wuhan 430074HubeiChina State Key Lab of Quantum Optics and Quantum Optics Devices Institute of Laser SpectroscopyShanxi UniversityTaiyuan 030006ShanxiChina Collaborative Innovation Center of Extreme Optics Shanxi UniversityTaiyuan 030006ShanxiChina Huaneng Clean Energy Research Institute BeijingChina School of Materials Science and Engineering&Henan Institute of Advanced Technology Zhengzhou UniversityZhengzhou 450001HenanChina

Over the last decade,remarkable progress has been made in metal halide perovskite solar cells(PSCs),which have been a focus of emerging photovoltaic techniques and show great potential for commercialization.However,the upscaling of small-area PSCs to large-area solar modules to meet the demands of practical applications remains a significant challenge.The scalable production of high-quality perovskite films by a simple,reproducible process is crucial for resolving this issue.Furthermore,the crystallization behavior in the solution-processed fabrication of perovskite films can be strongly influenced by the physicochemical properties of the precursor inks,which are significantly affected by the employed solvents and their interactions with the solutes.Thus,a comprehensive understanding of solvent engineering for fabricating perovskite films over large areas is urgently required.In this paper,we first analyze the role of solvents in the solution-processed fabrication of large-area perovskite films based on the classical crystal nucleation and growth mechanism.Recent efforts in solvent engineering to improve the quality of perovskite films for solar modules are discussed.Finally,the basic principles and future challenges of solvent system design for scalable fabrication of high-quality perovskite films for efficient solar modules are proposed.

关键词： Solvent engineering Scalable fabrication Perovskite film solar cell Module

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Atmospheric stable and fexible Sn-based perovskite solar cells via a bioinspired antioxidative crystal template

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Journal of Energy Chemistry 2022年第3期31卷 612-618,I0016页

作者： Rui Guo Li Rao Qianjin Liu Hongyu Wang Chenxiang Gong Baojin Fan Zhi Xing Xiangchuan Meng Xiaotian Hu School of Materials Science and Engineering Nanchang University999 Xuefu AvenueNanchang 330031JiangxiChina School of Future Technology Nanchang University999 Xuefu AvenueNanchang 330031JiangxiChina Institute of Polymers and Energy Chemistry Nanchang University999 Xuefu AvenueNanchang 330031JiangxiChina

Sn-based perovskite solar cells(PSCs)demonstrate a potential development in eco-friendly devices due to their hypotoxicity.However,poor stability and crystalline quality are still the challenges for achieving high-performance and long-term operating devices.In this work,inspired by biological protein,nickelporphyrin(Ni-P)with electron cloud on conjugate ring is applied into Sn-based perovskite to prevent perovskite from being eroded.The synergistic effect of water and oxygen is broken in grain boundaries and surface so that the stability of PSCs can be improved obviously,despite there is hardly any barrier for water to erode.Simultaneously,the electron-rich molecules can passivate the defects of perovskite such as iodine vacancy.Moreover,the ester group in Ni-P molecule can bind with SnI;to form complex and then restrain nucleation.Combining with the template effect of 2D molecular,the crystallization of perovskite films is optimized.Therefore,the Sn-based PSCs with Ni-P achieve a stabilized power conversion efficiency(PCE)of 7.79%with negligible hysteresis in fexible devices,respectively.Moreover,the PSCs can maintain 80%of the pristine PCE after 300 h under air environment.

关键词： Lead-free solar cell Flexible devices Molecular bionics Crystallization control

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A comprehensive review of optical wireless power transfer technology

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Frontiers of Information Technology & Electronic Engineering 2023年第6期24卷 767-800页

作者： Syed Agha Hassnain MOHSAN Haoze QIAN Hussain AMJAD Optical Communication Laboratory Ocean CollegeZhejiang UniversityZhoushan 316021China School of Electronic Engineering Beijing University of Posts and TelecommunicationsBeijing 100876China Satellite Communication and Networking Laboratory Ocean CollegeZhejiang UniversityZhoushan 316021China

Ground-breaking optical wireless power transfer(OWPT)techniques have gained significant attention from both academia and industry in recent decades.Powering remote systems through laser diodes(LDs)to either operate devices or recharge batteries offers several benefits.Remote LDs can remove the burden of carrying extra batteries and can reduce mission time by removing battery swap-time and charging.Apart from its appealing benefits,laser power transfer(LPT)is still a challenging task due to its low transfer efficiency.In this paper,we discuss the necessity and feasibility of OWPT and discuss several projects,working principle,system design,and components.In addition,we show that OWPT is an essential element to supply power to Internet-of-Things(IoT)terminals.We also highlight the impacts of dynamic OWPT.We outline several OWPT techniques including optical beamforming,distributed laser charging(DLC),adaptive-DLC(ADLC),simultaneous lightwave information and power transfer(SLIPT),Thing-to-Thing(T2T)OWPT,and high intensity laser power beaming(HILPB).We also deal with laser selection,hazard analysis,and received photovoltaic(PV)cell selection for OWPT systems.Finally,we discuss a range of open challenges and counter measures.We believe that this review will be helpful in integrating research and eliminating technical uncertainties,thereby promoting progress and innovation in the development of OWPT technologies.

关键词： Wireless power transmission Optical wireless power transfer Distributed laser charging Laser diode solar cell

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