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Polyethylene interfacial dielectric layer for organic semiconductor single crystal based field-effect transistors

Chinese Chemical Letters 2024年第4期35卷 431-435页

作者： Min Chen Boyu Peng Xuyun Guo Ye Zhu Hanying Li Department of Polymer Science and Engineering MOE Key Laboratory of Macromolecular Synthesis and FunctionalizationInternational Research Center for X PolymersShanxi-Zheda Institute of Advanced Materials and Chemical EngineeringZhejiang UniversityHangzhou 310027China Department of Applied Physics Research Institute for Smart EnergyThe Hong Kong Polytechnic UniversityHong Kong 999077China

Organic semiconductor single crystals(OSSCs) have shown their promising potential in high-performance organic field-effect transistors(OFETs). The interfacial dielectric layers are critical in these OFETs as they not only govern the key semiconductor/dielectric interface quality but also determine the growth of OSSCs by their wetting properties. However, reported interfacial dielectric layers either need rigorous preparation processes, rely on certain surface chemistry reactions, or exhibit poor solvent resistance, which limits their applications in low-cost, large-area, monolithic fabrication of OSSC-based OFETs. In this work, polyethylene(PE) thin films and lamellar single crystals are utilized as the interfacial dielectric layers, providing solvent resistive but wettable surfaces that facilitate the crystallization of 6,13-bis(tri-isopropylsilylethynyl)pentacene(TIPS-PEN) and 6,13-bis(triisopropylsilylethynyl)-5,7,12,14-tetraazapentacene(TIPS-TAP). As evidenced by the presence of ambipolar behavior in TIPS-PEN single crystals and the high electron mobility(2.3 ± 0.34 cm^(2)V^(-1)s^(-1)) in TIPS-TAP single crystals, a general improvement on electron transport with PE interfacial dielectric layers is revealed, which likely associates with the chemically inertness of the saturated C-H bonds. With the advantages in both processing and device operation, the PE interfacial dielectric layer potentially offers a monolithic way for the enhancement of electron transport in solution-processed OSSC-based OFETs.

关键词： Polyethylene Interfacial dielectric layer Organic semiconductor single crystal Organic field-effect transistors

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single crystal growth and electrochemical studies of garnet-type fast Li-ion conductors

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Tungsten 2022年第4期4卷 263-268页

作者： Yi-Tian Wang Xi Chen Department of Electrical and Computer Engineering University of CaliforniaRiversideCA92521USA

All-solid-state batteries have attracted much attention due to their improved safety and higher energy density as compared to the conventional batteries.Owing to the excellent chemical stability against lithium metal and relatively high ionic conductivity at room-temperature,garnet-type fast lithium ion conductors with three-dimensional lithium ion transport channels are promising solid electrolytes for all-solid-state batteries.In order to better understand the intrinsic lithium-ion transport mechanisms and prevent lithium dendrite formation,it is desired to investigate single-crystal solid electrolytes.In this perspective,we review several methods reported to grow single crystals of garnet-type electrolytes.Pros and cons of different growth methods are discussed.Furthermore,we introduce some case studies on electrochemical properties of garnet-type single crystals.In addition,we provide some perspectives about potential research directions of single-crystal solid electrolytes for all-solid-state batteries.

关键词： Solid electrolyte single crystal Garnet-type lithium-ion conductor All-solid-state battery crystal growth

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single-crystal Nickel-Based Cathodes:Fundamentals and Recent Advances

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Electrochemical Energy Reviews 2022年第4期5卷 63-103页

作者： Shi-jie Lu Lin-bo Tang Han-xin Wei Ying-de Huang Cheng Yan Zhen-jiang He Yun-jiao Li Jing Mao Kehua Dai Jun-chao Zheng School of Metallurgy and Environment Central South UniversityChangsha 410083HunanChina National Engineering Laboratory for High Efficiency Recovery of Refractory Nonferrous Metals Central South UniversityChangsha 410083HunanChina Engineering Research Center of the Ministry of Education for Advanced Battery Materials Central South UniversityChangsha 410083HunanChina School of Mechanical Medical and Process EngineeringQueensland University of TechnologyBrisbaneQLD 4001Australia School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001HenanChina College of Chemistry Tianjin Normal UniversityTianjin 300387China

Lithium-ion batteries(LIBs)represent the most promising choice for meeting the ever-growing demand of society for various electric applications,such as electric transportation,portable electronics,and grid storage.Nickel-rich layered oxides have largely replaced LiCoO_(2)in commercial batteries because of their low cost,high energy density,and good reliability.Traditional nickel-based oxide particles,usually called polycrystal materials,are composed of microsized primary particles.However,polycrystal particles tend to suffer from pulverization and severe side reactions along grain boundaries during cycling.These phenomena accelerate cell degradation.single-crystal materials,which exhibit robust mechanical strength and a high surface area,have great potential to address the challenges that hinder their polycrystal counterparts.A comprehensive understanding of the growing body of research related to single-crystal materials is imperative to improve the performance of cathodes in LIBs.This review highlights origins,recent developments,challenges,and opportunities for single-crystal layered oxide cathodes.The synthesis science behind single-crystal materials and comparative studies between single-crystal and polycrystal materials are discussed in detail.Industrial techniques and facilities are also reviewed in combination with our group’s experiences in single-crystal research.Future development should focus on facile production with strong control of the particle size and distribution,structural defects,and impurities to fully reap the benefits of single-crystal materials.

关键词： Lithium-ion battery Cathode materials single crystal Nickel-based layered oxides

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A self-power photodetector based on controlled growth of single crystal MAPbBr_(3)/WO_(3) heterojunction

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中国科学:技术科学英文版 2023年第9期66卷 2660-2668页

作者： YAO JianFeng ZHANG Hu LU JunZheng YANG LiangPan LIU DuanWangDe HU YaLi ZENG Wei GUI PengBin CHEN ZhiLiang REN XinGang Information Materials and Intelligent Sensing Laboratory of Anhui Province Anhui UniversityHefei 230039China Anhui Province Key Laboratory of Target Recognition and Feature Extraction Lu’an 237009China Hefei Comprehensive National Science Center Hefei 230601China School of Physics and Electronic Engineering Hubei University of Arts and ScienceXiangyang 441053China

Compared with polycrystalline films, perovskite single crystal is considered as a promising photoelectric material due to its unique advantages in quantum efficiency and carrier diffusion length. In this work, the micron-thickness MAPbBr_(3) single crystal was prepared through a highly repeatable process based on the crystal seed dissolution-growth method. A heterojunction of MAPbBr_(3)/WO_(3) single crystal was realized through a simple thermal evaporation process, and the integrated C/MAPbBr_(3)/WO_(3)/C device demonstrated self-powered characteristics and high photoelectric performance, which showed good responsivity of about 111 mA/W, detectivity of 9.64×10^(11) Jones and fast response speed(0.11/0.56 ms). Meanwhile, the device exhibited good rectification performance(ratio of 125 at ±2 V) and reduced dark current due to the built-in electric field formed in the heterojunction. This study provides a facile, flexible, and highly repeatable method for the preparation of high-performance photodetectors based on MAPbBr_(3) single crystals with micrometer thickness.

关键词： perovskite single crystal heterojunction self-powered photodetectors

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A Comparative Investigation of single crystal and Polycrystalline Ni-Rich NCMs as Cathodes for Lithium-Ion Batteries

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Energy & Environmental Materials 2023年第3期6卷 1-7页

作者： Xianming Deng Rui Zhang Kai Zhou Ziyao Gao Wei He Lihan Zhang Cuiping Han Feiyu Kang Baohua Li Shenzhen Key Laboratory of Power Battery Safety and Shenzhen Geim Graphene Center Tsinghua Shenzhen International Graduate SchoolTsinghua UniversityShenzhen 518055China School of Materials Science and Engineering Tsinghua UniversityBeijing 100084China EVE Energy Co. Ltd.No.38Hui Feng 7th RoadZhongkai Hi-Tech ZoneHuiZhou Guangdong 516006China Shenzhen Key Laboratory of Energy Materials for Carbon Neutrality and Faculty of Materials Science and Engineering Shenzhen Institutes of Advanced TechnologyChinese Academy of SciencesShenzhen 518055China

Nickel-rich LiNi_(1-x-y)Co_(x)Mn_(y)O_(2)(NCM,1-x-y≥0.6)is known as a promising cathode material for lithium-ion batteries since its superiority of high voltage and large capacity.However,polycrystalline Ni-rich NCMs suffer from poor cycle stability,limiting its further application.Herein,single crystal and polycrystalline LiNi_(0.84)Co_(0.07)Mn_(0.09)O_(2)cathode materials are compared to figure out the relation of the morphology and the electrochemical storage performance.According to the Li^(+)diffusion coefficient,the lower capacity of single crystal samples is mainly ascribed to the limited Li+diffusion in the large bulk.In situ XRD illustrates that the polycrystalline and single crystal NCMs show a virtually identical manner and magnitude in lattice contraction and expansion during cycling.Also,the electrochemically active surface area(ECSA)measurement is employed in lithium-ion battery study for the first time,and these two cathodes show huge discrepancy in the ECSA after the initial cycle.These results suggest that the single crystal sample exhibits reduced cracking,surface side reaction,and Ni/Li mixing but suffers the lower Li^(+)diffusion kinetics.This work offers a view of how the morphology of Ni-rich NCM effects the electrochemical performance,which is instructive for developing a promising strategy to achieve good rate performance and excellent cycling stability.

关键词： cathodes electrochemically active surface area Li^(+)diffusion coefficient lithium-ion batteries single crystal

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Enhanced cycling stability of single-crystal LiNi_(0.83)Co_(0.07)Mn_(0.10)O_(2)by Li-reactive coating with H_(3)BO_(3)

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稀有金属:英文版 2023年第8期42卷 2612-2621页

作者： Wen-Hui Hu Ya Yin Ya Sun Guo-Xue Liu Shun-Yi Yang You-Yuan Huang Bo Wang BTR New Material Group Co. LtdShenzhen 518000China Key Laboratory of Cluster Science Ministry of EducationSchool of Chemistry and Chemical EngineeringBeijing Instituteof Technology Beijing 100081China BTR Nano Tech Co. LtdShenzhen 518000China College of Chemistry and Environmental Engineering Wuhan Polytechnic UniversityWuhan 430023China

Ni-rich cathode materials will be primarily used as next-generation high-specific energy cathode materials in lithium-ion batteries.However,residual Li formation and cracking considerably restrict the wide application of these materials.To address the issues related to cracking,micro-sized single-crystal cathode materials without internal grain boundaries are proposed.In this study,we constructed a thin LiBO_(2)layer on the single-crystal LiNi_(0.83)Co_(0.07)Mn_(0.10)O_(2)particles by solvent-free H_(3)BO_(3)modification.The residual Li on the material surface decreased by 14%through the reaction of LiOH/Li_(2)CO_(3)and H_(3)BO_(3).The coated materials exhibited higher initial Coulombic efficiency(88.44%),higher reversible capacity(213.4 mAh·g^(-1)at 0.1 C),and better cycling performance(91.31%retention over 50 cycles within 3.0-4.3 V at 1.0C)than the unmodified materials.Using the galvanostatic intermittent titration technique,electrochemical impedance spectroscopy(EIS),and inductively coupled plasma-optical emission spectroscopy(ICP-OES),we reveal the mechanism by which the electrochemical properties are improved upon H_(3)BO_(3)modification.The superior electrochemical performances are associated with increased Li+conductivity,lower charge transfer impedance,and suppressed transition metal dissolution.Therefore,this study demonstrates the importance of surface modification in obtaining Ni-rich single-crystal materials with enhanced performance.

关键词： Ni-rich cathode Residual Li Cycling stability Li-reactive coating single crystal

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Effects of temperature on critical resolved shear stresses of slip and twining in Mg single crystal via experimental and crystal plasticity modeling

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镁合金学报(英文) 2023年第6期11卷 2027-2041页

作者： Kwang Seon Shin Lifei Wang Mingzhe Bian Shihoon Choi Alexander Komissarov Viacheslav Bazhenov Magnesium Technology Innovation Center Department of Materials Science and EngineeringSeoul National University1 Gwanak-roGwanak-guSeoul 08826Republic of Korea Laboratory of Medical Bioresorption and Bioresistance Moscow State University of Medicine and DentistryDelegatskaya 20/1Moscow127473 Russia Shanxi Key Laboratory of Advanced Magnesium-Based Materials College of Materials Science and EngineeringTaiyuan University of TechnologyTaiyuan 030024China Departments of Advanced Components and Materials Engineering Sunchon National UniversitySuncheonJeonnam57922Republic of Korea Laboratory of Hybrid Nanostructured Materials National University of Science and Technology"MISiS"Leninskiy pr.4Moscow119049 Russia Casting Department National University of Science and Technology"MISiS"Leninskiy pr.4Moscow119049 Russia

Magnesium(Mg)single crystal specimens with three different orientations were prepared and tested from room temperature to 733 K in order to systematically evaluate effects of temperature on the critical resolved shear stress(CRSS)of slips and twinning in Mg single crystals.The duplex non-basal slip took place in the temperature range from 613 to 733 K when the single crystal samples were stretched along thedirection.In contrast,the single basal slip and prismatic slip were mainly activated in the temperature range from RT to 733 K when the tensile directions were inclined at an angle of 45°with the basal and the prismatic plane,respectively.Viscoplastic self-consistent(VPSC)crystal modeling simulations with genetic algorithm code(GA-code)were carried out to obtain the best fitted CRSSs of major deformation modes,such as basal slip,prismatic slip,pyramidalⅡ,{1012}tensile twinning and{1011}compressive twinning when duplex slips accommodated deformation.Additionally,CRSSs of the basal and the prismatic slip were derived using the Schmid factor(SF)criterion when the single slip mainly accommodated deformation.From the CRSSs of major deformation modes obtained by the VPSC simulations and the SF calculations,the CRSSs for basal slip and{1012}tensile twinning were found to show a weak temperature dependence,whereas those for prismatic,slip and{1011}compressive twinning exhibited a strong temperature dependence.From the comparison of previous results,VPSC-GA modeling was proved to be an effective method to obtain the CRSSs of various deformation modes of Mg and its alloys.

关键词： Magnesium single crystal Critical resolve shear stress Slip Twinning

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Efficient visible-light-driven water oxidation by single-crystal Ta_(3)N_(5)nanoparticles

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Nano Research 2023年第4期16卷 4562-4567页

作者： Zheng Wang Jeongsuk Seo Takashi Hisatomi Mamiko Nakabayashi Jiadong Xiao Shanshan Chen Lihua Lin Zhenhua Pan Mary Krause Nick Yin Gordon Smith Naoya Shibata Tsuyoshi Takata Kazunari Domen Research Initiative for Supra-Materials Interdisciplinary Cluster for Cutting Edge ResearchShinshu University4-17-1 WakasatoNagano-shiNagano 380-8553Japan Research Center for Eco-Environmental Sciences Chinese Academy of SciencesBeijing 100085China Institute of Engineering Innovation The University of Tokyo2-11-16 YayoiBunkyo-kuTokyo 113-8656Japan Global Advanced Metals Inc. 1223 County Line RoadBoyertownPA 19512USA Office of University Professors The University of Tokyo2-11-16 YayoiBunkyo-kuTokyo 113-8656Japan

Ta3N5 is regarded as a promising photocatalyst for solar water splitting because of its excellent visible light absorption characteristics and simple composition.Conventional Ta3N5 photocatalysts prepared from oxide precursors typically comprise aggregated polycrystalline particles with defects and grain boundaries that reduce the water oxidation activity of the material.In the present work,well-dispersed Ta3N5 nanoparticulate single crystals were synthesized via a mild nitridation process using pure Ta metal nanopowder or Ta nanopowder mixed with NaCl.The resulting high-quality Ta3N5 nanoparticles,after loading with an oxygen evolution cocatalyst,exhibited impressively high photocatalytic performance during O_(2)evolution from a sacrificial AgNO3 solution,with an apparent quantum yield of 9.4%at 420 nm.Our findings suggest a new approach to the facile fabrication of nanostructured single-crystal photocatalysts for efficient solar water splitting,based on the use of metal nanopowders.

关键词： Ta3N5 photocatalyst nanoparticle single crystal O_(2)evolution metallic Ta precursor

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Low-temperature strategy to synthesize single-crystal LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) with enhanced cycling performances as cathode material for lithium-ion batteries

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Nano Research 2022年第3期15卷 2052-2059页

作者： Fangya Guo Yongfan Xie Youxiang Zhang College of Chemistry and Molecular Sciences Wuhan UniversityWuhan 430072China

With high reversible capacities of more than 200 mAh/g,Ni-rich layered oxides Li[Ni_(x)Co_(y)Mn_(1–x–y)]O_(2)(x≥0.6)serve as the most promising cathode materials for lithium-ion batteries(LIBs).However,the anisotropic lattice volume changes linked to theirα-NaFeO_(2)structured crystal grains bring about poor cycle performances for conventionally produced NCM materials.To deal with these issue,single-crystalµm-sized LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)rods was synthesized by a hydrothermal method.Compared with conventional synthesis methods,these LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)rods were calcined at a low temperature with excessive lithium sources,which not only reduces the sintering temperature but also ensures the mono-dispersed micrometer-scaled particle distribution.When used as the cathode material for LIBs,the as-prepared LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2),with ordered layered-structure and low degree of cation mixing,shows excellent electrochemical performances.When sintered at 750°C with 50%Li-excess,the cathode material delivered an initial discharge capacity of 226.9 mAh/g with Coulombic efficiency of 91.2%at 0.1 C(1 C=200 mA/g)in the voltage range of 2.8‒4.3 V.When charge-discharged at 1 C for 100 cycles,discharge capacity of 178.1 mAh/g with the capacity retention of 95.1%are still obtained.The cycling stability at high cut-off voltage is also outstanding.These superior electrochemical properties should be related to the monodispersed micron scaled morphology which not only decreases the contact area between electrode and electrolyte but also mitigates the formation of microcracks.This low-temperature strategy of synthesizing single-crystal LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)rods should be able to provide a feasible method for synthesizing other single-crystal Ni-rich cathode materials with excellent electrochemical performances for LIB.

关键词： lithium ions batteries cathode excessive lithium single crystal LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)

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Effect of competitive crystal growth on microstructural characteristics of directionally solidified nickel-based single crystal superalloy

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China Foundry 2022年第2期19卷 109-116页

作者： Mang Xu Xiao-qi Geng Xiang-long Zhang Guo-huai Liu Ye Wang Zhao-dong Wang Jing-jie Guo State Key Laboratory of Rolling and Automation Northeastern UniversityShenyang 110819China School of Materials Science and Engineering Harbin University of Science and TechnologyHarbin 150040China School of Materials Science and Engineering Harbin Institute of TechnologyHarbin 150001China

Directionally solidified single crystal superalloy test bars were prepared by the spiral grain selection method.The microstructural evolution and orientation characteristics of the starter block and spiral part were studied,and the influence of the competitive growth of crystals on the microstructural characteristics was analyzed.The results show that the divergent grain groups,with small size and randomly oriented grains,appear at the bottom of the start block due to the chilling effect,which is an important area for competitive growth.As the height of the starter block increases,the primary dendrite spacing increases,and the grain density decreases;furthermore,the proportion of grains with an orientation deflection angle less than 10°gradually increases.Thetexture gradually becomes stronger as the height of the starter block increases,which indicates that the competitive growth of crystals gradually weakens.At the initial stage of the crystal selection in the spiral part,the obstacle of adjacent grains and spiral passage is the main working mechanism.The grains located at the inner side of the front edge of the spiral passage have the growth advantage.The single crystal screening process is achieved at about two-thirds of the spiral height,and the single crystal with the orientation deviation angle of 6.7°from the casting axis is prepared.

关键词： directional solidification Ni-based superalloy microstructural evolution spiral grain selector single crystal

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