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Effects of seed aerosols on the growth of secondary organic aerosols from the photooxidation of toluene

Journal of Environmental Sciences 2007年第6期19卷 704-708页

作者： HAO Li-qing WANG Zhen-ya HUANG Ming-qiang FANG Li ZHANG Wei-jun Laboratory of Environmental Spectroscopy Anhui Institute of Optics and Fine Mechanics Chinese Academy of Sciences Hefei 230031 China

Hydroxyl radical （.OH）-initiated photooxidation reaction of toluene was carried out in a self-made smog chamber. Four individual seed aerosols such as ammonium sulfate, ammonium nitrate, sodium silicate and calcium chloride, were introduced into the chamber to assess their influence on the growth of secondary organic aerosols （SOA）. It was found that the low concentration of seed aerosols might lead to high concentration of SOA particles. seed aerosols would promote rates of SOA formation at the start of the reaction and inhibit its formation rate with prolonging the reaction time. In the case of ca. 9000 pt/cm^3 seed aerosol load, the addition of sodium silicate induced a same effect on the SOA formation as ammonium nitrate. The influence of the four individual seed aerosols on the generation of SOA decreased in the order of calcium chloride〉sodium silicate and ammonium nitrate〉ammonium sulfate.

关键词： toluene photooxidation secondary organic aerosol seed aerosol

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Effect of relative humidity and the presence of aerosol particles on the α-pinene ozonolysis

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Journal of Environmental Sciences 2018年第9期30卷 99-107页

作者： Guoqiang Zhang Hongbo Fu Jianmin Chen Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention(LAP^(3)) Department of Environmental Science and EngineeringInstitute of Atmospheric SciencesFudan UniversityShanghai 200433China

The α-pinene ozonolysis under the different environmental conditions were observed in a smog chamber. The second-order rate constant （k） was determined to be （7.25 ± 0.06） x 10^-17 cm^3/（molecule.sec） under 20% of relative humidity （RH） and room temperature. RH showed a marked influence on the α-pinene ozonolysis. The value of k increased with KH increase, which was 1.6 times faster at RH = 80% than that at RH = 20%. Additionally, the value of k apparently changed in the presence of the aerosol particles. The diesel soot increased the k value. The fly ash prohibited the reaction, however, H2SO4-treated fly ash promoted the reaction. The information of products gained using FT-IR and SPAMS showed that pinonic acid, 10-hydroxy-pinonic acid and pinic acid could be generated during the α- pinene ozonolysis. Water molecules could take part in the formation of the products, and play a vital role in the degradation of α-pinene. The atmospheric residence time calculation showed that the ozonolysis in the atmosphere is an important way of the α-pinene consumption as compared to that reacted with OH during daytime. The results suggested that the degradation of α-pinene via the ozonization in the atmosphere may be affected greatly by RH, as well as the presence of aerosol particles. The ozonolysis reaction may be an important way of the a-pinene consumption during daytime.

关键词： α-Pinene Ozonolysis RH% seed aerosol Rate constant

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