检索结果-南通市图书馆

Isolation and Identification of Pseudo Seven-Coordinate ru(Ⅲ)Intermediate Completing the Catalytic Cycle of ru-bda Type of Water Oxidation Catalysts

引用

CCS Chemistry 2022年第7期4卷 2481-2490页

作者： Tianqi Liu Ge Li Nannan Shen Linqin Wang Brian J.J.Timmer Shengyang Zhou Biaobiao Zhang Alexander Kravchenko Bo Xu Marten S.G.Ahlquist Licheng Sun Department of Chemistry School of Engineering Sciences in ChemistryBiotechnologyand HealthKTH Royal Institute of TechnologyStockholm 10044 Department of Theoretical Chemistry and Biology School of Engineering Sciences in ChemistryBiotechnologyand HealthKTH Royal Institute of TechnologyStockholm 10691 State Key Laboratory of Radiation Medicine and Protection School for Radiological and Interdisciplinary Sciences(RAD-X)Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education InstitutionsSoochow UniversitySuzhou 215123 Center of Artificial Photosynthesis for Solar Fuels School of ScienceWestlake UniversityHangzhou 310024 Nanotechnology and Functional Materials Department of Materials Sciences and EngineeringThe Angstrom LaboratoryUppsala UniversityUppsala 75103 Institute of Artificial Photosynthesis(IAP) State Key Laboratory of Fine ChemicalsDalian University of Technology(DUT)Dalian 116024

Isolation of ruⅢ-bda(17-electron specie)complex with an aqua ligand(2-electron donor)is challenging due to violation of the 18-electron *** considerable efforts have been dedicated to mechanistic studies of water oxidation by the ru-bda family,the structure and initial formation of the ru^(Ⅲ)-bda aqua complex are still ***,we challenge this often overlooked step by designing a pocketshape ru-based complex *** computational studies showed that 1 possesses the crucial hydrophobicity at the ru^(V)(O)state as well as similar probability of access of terminal O to solvent water molecules when compared with classic ru-bda *** characterization of single-crystal structures at the ru^(Ⅱ) and ru^(Ⅲ) states,a pseudo seven-coordinate“ready-togo”aqua ligand with ru^(Ⅲ)…O distance of 3.62A was *** aqua ligand was also found to be part of a formed hydrogen-bonding network,providing a good indication of how the ru^(Ⅲ)-OH_(2)complex is formed.

关键词： ru-bda water oxidation pseudo seven-coordinate ru^(Ⅲ)-OH_(2)intermediate water preorganization

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：