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Unlocking the potential of thin-film composite reverse osmosis membrane performance:Insights from mass transfer modeling

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Chinese Chemical Letters 2024年第5期35卷 66-76页

作者： Kexin Yuan Yulei Liu Haoran Feng Yi Liu Jun Cheng Beiyang Luo Qinglian Wu Xinyu Zhang Ying Wang Xian Bao Wanqian Guo Jun Ma State Key Laboratory of Urban Water Resource and Environment School of EnvironmentHarbin Institute of TechnologyHarbin 150090China College of Architecture and Environment Sichuan UniversityChengdu 610065China School of Municipal and Environmental Engineering Shandong Jianzhu UniversityJi’nan 250101China College of Water Conservancy and Hydropower Engineering Sichuan Agricultural UniversityYaan 625014China

Thin-film composite(TFC)reverse osmosis(RO)membranes have attracted considerable attention in water treatment and desalination processes due to their specific separation advantages.Nevertheless,the trade-off effect between water flux and salt rejection poses huge challenges to further improvement in TFC RO membrane performance.Numerous research works have been dedicated to optimizing membrane fabrication and modification for addressing this issue.In the meantime,several reviews summarized these approaches.However,the existing reviews seldom analyzed these methods from a theoretical perspective and thus failed to offer effective optimization directions for the RO process from the root cause.In this review,we first propose a mass transfer model to facilitate a better understanding of the entire process of how water and solute permeate through RO membranes in detail,namely the migration process outside the membrane,the dissolution process on the membrane surface,and the diffusion process within the membrane.Thereafter,the water and salt mass transfer behaviors obtained from model deduction are comprehensively analyzed to provide potential guidelines for alleviating the trade-off effect between water flux and salt rejection in the RO process.Finally,inspired by the theoretical analysis and the accurate identification of existing bottlenecks,several promising strategies for both regulating RO membranes and optimizing operational conditions are proposed to further exploit the potential of RO membrane performance.This review is expected to guide the development of high-performance RO membranes from a mass transfer theory standpoint.

关键词： reverse osmosis Mass transfer model Trade-off effect Membrane performance Optimization strategies

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Impacts of Climate Change on Seawater Temperature and Total Dissolved Solids: Challenges and Sustainable Solutions for reverse osmosis Desalination in the Arabian Gulf Region

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Computational Water, Energy, and Environmental Engineering 2024年第1期13卷 86-93页

作者： Ahmed Al Kubaish Jamal Salama Water Quality Section Saline Water Conversion Corporation Al-Khobar Saudi Arabia

This article examines the influence of seawater temperature and total dissolved solids (TDS) on reverse osmosis (RO) desalination in the Arabian Gulf region, with a focus on the impact of climate change. The study highlights the changes in seawater temperature and TDS levels over the years and discusses their effects on the efficiency and productivity of RO desalination plants. It emphasizes the importance of monitoring TDS levels and controlling seawater temperature to optimize water production. The article also suggests various solutions, including intensive pre-treatment, development of high-performance membranes, exploration of alternative water sources, and regulation of discharges into the Gulf, to ensure sustainable water supply in the face of rising TDS levels and seawater temperature. Further research and comprehensive monitoring are recommended to understand the implications of these findings and develop effective strategies for the management of marine resources in the Arabian Gulf.

关键词： Climate Change Temperature reverse osmosis Seawater Total Dissolved Solids Desalination

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Surface-tailoring chlorine resistant materials and strategies for polyamide thin film composite reverse osmosis membranes

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Frontiers of Chemical Science and Engineering 2022年第5期16卷 564-591页

作者： Pei Sean Goh Kar Chun Wong Tuck Whye Wong Ahmad Fauzi Ismail Advanced Membrane Technology Research Centre(AMTEC) School of Chemical and Energy EngineeringFaculty of EngineeringUniversiti Teknologi Malaysia81310 Johor BahruMalaysia

Polyamide thin film composite membranes have dominated current reverse osmosis market on account of their excellent separation performances compared to the integrally skinned counterparts.Despite their very promising separation performance,chlorine-induced degradation resulted from the susceptibility of polyamide toward chlorine attack has been regarded as the Achilles’s heel of polyamide thin film composite.The free chlorine species present during chlorine treatment can impair membrane performance through chlorination and depolymerization of the polyamide selective layer.From material point of view,a chemically stable membrane is crucial for the sustainable application of membrane separation process as it warrants a longer membrane lifespan and reduces the cost involved in membrane replacement.Various strategies,particularly those involved membrane material optimization and surface modifications,have been established to address this issue.This review discusses membrane degradation by free chlorine attack and its correlation with the surface chemistry of polyamide.The advancement in the development of chlorine resistant polyamide thin film composite membranes is reviewed based on the state-of-the-art surface modifications and tailoring approaches which include the in situ and postfabrication membrane modifications using a broad range of functional materials.The challenges and future directions in this field are also highlighted.

关键词： reverse osmosis polyamide thin film composite membranes chlorine resistance surface modification

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Highly permeable reverse osmosis membranes incorporated with hydrophilic polymers of intrinsic microporosity via interfacial polymerization

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Chinese Journal of Chemical Engineering 2022年第5期35卷 194-202页

作者： Jing Dou Shuo Han Saisai Lin Zhikan Yao Lian Hou Lin Zhang Engineering Research Center of Membrane and Water Treatment of MOE College of Chemical&Biological EngineeringZhejiang UniversityHangzhou 310027China Research Institute of Ningbo Zhejiang UniversityNingbo 315100China Xi’an High-Tech Institute Xi’an 710025China

Enhancing the water permeation while maintaining high salt rejection of existing reverse osmosis(RO)membranes remains a considerable challenge.Herein,we proposed to introduce polymer of intrinsic microporosity,PIM-1,into the selective layer of reverse osmosis membranes to break the trade-off effect between permeability and selectivity.A water-soluble a-LPIM-1 of low-molecular-weight and hydroxyl terminals was synthesized.These designed characteristics endowed it with high solubility and reactivity.Then it was mixed with m-phenylenediamine and together served as aqueous monomer to react with organic monomer of trimesoyl chloride via interfacial polymerization.The characterization results exhibited that more“nodule”rather than“leaf”structure formed on RO membrane surface,which indicated that the introduction of the high free-volume of a-LPIM-1 with three dimensional twisted and folded structure into the selective layer effectively caused the frustrated packing between polymer chains.In virtue of this effect,even with reduced surface roughness and unchanged layer thickness,the water permeability of prepared reverse osmosis membranes increased 2.1 times to 62.8 L·m^(-2)·h^(-1) with acceptable Na Cl rejection of 97.6%.This attempt developed a new strategy to break the trade-off effect faced by traditional polyamide reverse osmosis membranes.

关键词： PIM-1 Intrinsic microporosity reverse osmosis Interfacial polymerization Trade-off

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Self-healing polyamide reverse osmosis membranes with temperature-responsive intelligent nanocontainers for chlorine resistance

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化学科学与工程前沿:英文版 2023年第9期17卷 1183-1195页

作者： Qian Yang Lin Zhang Xiao Xie Qiong Sun Jianguang Feng Hongzhou Dong Na Song Liyan Yu Lifeng Dong College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao266042China Qingdao University of Science&Technology Analytical&Testing Center Qingdao266042China Department of Physics Hamline UniversitySt.Paul55104USA

Improving the performance of reverse osmosis membranes remains great challenge to ensure excellent NaCl rejection while maintaining high water permeability and chlorine resistance. Herein, temperature-responsive intelligent nanocontainers are designed and constructed to improve water permeability and chlorine resistance of polyamide membranes. The nanocontainer is synthesized by layer-by-layer self-assembly with silver nanoparticles as the core, sodium alginate and chitosan as the repair materials, and polyvinyl alcohol as the shell. When the polyamide layer is damaged by chlorine attack, the polyvinyl alcohol shell layer dissolves under temperature stimulation of 37 ℃, releasing inner sodium alginate and chitosan to repair broken amide bonds. The polyvinyl alcohol shell responds to temperature in line with actual operating environment, which can effectively synchronize the chlorination of membranes with temperature response and release inner materials to achieve self-healing properties. With adding temperature-responsive intelligent nanocontainers, the NaCl rejection of thin film composite membrane decreased by 15.64%, while that of thin film nanocomposite membrane decreased by only 8.35% after 9 chlorination cycles. Effective repair treatment and outstanding chlorine resistance as well as satisfactory stability suggest that temperature-responsive intelligent nanocontainer has great potential as membrane-doping material for the targeted repair of polyamide reverse osmosis membranes.

关键词： reverse osmosis nanocontainer self-healing chlorine resistance water permeability

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Recent advances in nanofiltration,reverse osmosis membranes and their applications in biomedical separation field

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Chinese Journal of Chemical Engineering 2022年第9期35卷 76-99页

作者： Kai Zhang Huan-Huan Wu Hui-Qian Huo Yan-Li Ji Yong Zhou Cong-Jie Gao Center for Membrane and Water Science&Technology Zhejiang University of TechnologyHangzhou 310014China

In the face of human society's great requirements for health industry,and the much stricter safety and quality standards in the biomedical industry,the demand for advanced membrane separation technologies continues to rapidly grow in the world.Nanofiltration(NF)and reverse osmosis(RO)as the highefficient,low energy consumption,and environmental friendly membrane separation techniques,show great promise in the application of biomedical separation field.The chemical compositions,microstructures and surface properties of NF/RO membranes determine the separation accuracy,efficiency and operation cost in their applications.Accordingly,recent studies have focused on tuning the structures and tailoring the performance of NF/RO membranes via the design and synthesis of various advanced membrane materials,and exploring universal and convenient membrane preparation strategies,with the objective of promoting the better and faster development of NF/RO membrane separation technology in the biomedical separation field.This paper reviews the recent studies on the NF/RO membranes constructed with various materials,including the polymeric materials,different dimensional inorganic/organic nanomaterials,porous polymeric materials and metal coordination polymers,etc.Moreover,the influence of membrane chemical compositions,interior microstructures,and surface characteristics on the separation performance of NF/RO membranes,are comprehensively discussed.Subsequently,the applications of NF/RO membranes in biomedical separation field are systematically reported.Finally,the perspective for future challenges of NF/RO membrane separation techniques in this field is discussed.

关键词： Nanofiltration reverse osmosis Membrane Separation Biomedical

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One-Step reverse osmosis Based on Riverbank Filtration for Future Drinking Water Purification

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Engineering 2022年第2期8卷 27-34页

作者： Yujia Zhai Gang Liu Walter G.J.van der Meer Oasen Drinkwater Gouda 2800 ACNetherlands Faculty of Science and Technology University of TwenteEnschede 7500 AENetherlands Key Laboratory of Drinking Water Science and Technology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China Sanitary Engineering Research Group Department of Water ManagementFaculty of Civil Engineering and GeosciencesDelft University of TechnologyDelft 2600 GANetherlands

The presence of newly emerging pollutants in the aquatic environment poses great challenges for drink-ing water treatment plants.Due to their low concentrations and unknown characteristics,emerging pol-lutants cannot be efficiently removed by conventional water treatment processes,making technically,economically,and environmentally friendly water purification technologies increasingly important.This article introduces a one-step reverse osmosis(OSRO)concept consisting of riverbank filtration(RBF)and reverse osmosis(RO)for drinking water treatment.The OSRO concept combines the relatively low-cost natural pretreatment of river water with an advanced engineered purification system.RBF pro-vides a continuous natural source of water with stable water quality and a robust barrier for contami-nants.With the pre-removal of particles,organic matter,organic micro-pollutants(OMPs),and microbes,RBF becomes an ideal source for a purification system based on RO membranes,in comparison with the direct intake of surface water.OSRO treatment removes almost 99.9%of the particles,pathogens,viruses,and OMPs,as well as the vast majority of nutrients,and thus meets the requirements for the chlorine-free delivery of drinking water with high biostability.The OSRO treatment is cost effective com-pared with the standard conventional series of purification steps involving sprinkling filters,softening,and activated carbon.Artificial bank filtration(ABF),which functions as an artificial recharge in combi-nation with a sand filtration system,is proposed as an alternative for RBF in the OSRO concept to supply drinking water from locally available resources.It is also suggested that the OSRO concept be imple-mented with wind power as an alternative energy source in order to be more sustainable and renewable.An OSRO-based decentralized water system is proposed for water reclaiming and reuse.It is suggested that future water treatment focus on the combination of natural and engineered systems to provide drinking water through technically efficien

关键词： Drinking water treatment River bank filtration reverse osmosis Artificial bank filtration Water reclamation and reuse

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Simulations of Tapered Channel in Multilayer Graphene as reverse osmosis Membrane for Desalination

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Journal of Wuhan University of Technology(Materials Science) 2022年第3期37卷 314-323页

作者：王天振 CHEN Bo SHAO Xingyu ZHENG Huai 胡雪蛟江海峰 Key Laboratory of Hydraulic Machinery Transients(Wuhan University) Ministry of EducationSchool of Power and Mechanical EngineeringWuhan UniversityWuhan 430072China Research Institute of Tsinghua University in Shenzhen Shenzhen 518071China

Pressure-driven reverse osmosis membrane has important application in seawater desalination.Inspired by the structure of aquaporin,we established and studied the mechanism of the structure of multilayer graphene with tapered channels as reverse osmosis.The water flux of multilayer graphene with tapered channels was about 20%higher than that of parallel graphene channel.The flow resistance model was established,and the relationship between flow resistance and opening angles was clarified.The relationship between flow resistance and outlet size was also described.By means of molecular dynamics simulation,slip coefficients of multilayer graphene with tapered channel were obtained and verified by the contact angle of water.Results show that the permeability of graphene with tapered channel is about three orders of magnitude higher than that of commercial reverse osmosis membrane and the desalination rate is 100%.Temperature difference between the two sides of the tapered channel will promote the water flux positively.

关键词： multilayer graphene molecular dynamics tapered channel opening angles reverse osmosis

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STUDIES ON reverse osmosis SEPARATION OF AQUEOUS ORGANIC SOLUTIONS BY PAA/PSF COMPOSITE MEMBRANE

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Chinese Journal of Polymer Science 2000年第2期18卷 115-122页

作者： Jun Fang De-min Jia Ji-cai Huang Qun-hui Guo Feng-lian Wu South-China University of Technology, Guangzhou 510641, China Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650, China 华南理工大学广东广州中科院广州化学所广东广州

The reverse osmosis (RO) separation of aqueous organic solutions, such as alcohols, amines, aldehydes, acids, ketones, and esters etc., by PAA (polyacrylic acid)/PSF (polysulfone) composite membrane has been studied. It was found that the separation results for aliphatic alcohols, amines and aldehydes are satisfactory, the solute rejection (R-a) and the volume fluxes of solutions (J(V)) for 1000 ppm ethanol, ethylamine and ethyl aldehyde are 66.2%, 61.0%, 84.0% and 0.90 x 10(-6), 0.35 x 10(-6), 0.40 X 10(-6) m(3)/m(2) . s, respectively, at 5.0 MPa and 30 degrees C. R-a increased with increasing molecular weights of alcohols, amines and aldehydes, and the R-a for n-amyl alcohol, n-butylamine and n-butyl aldehyde reached 94.3%, 88.6% and 96.0%, respectively. Satisfactory separation results (R-a > 70%) for ketones, esters, phenols and polyols have been obtained with the PAA/PSF composite membrane. The effect of operating pressure on the properties of reverse osmosis has also been investigated. Analysis of experimental data with Spiegler-Kedem's transport model has been carried out and the membrane constants such as reflection coefficient sigma, solute and hydraulic permeabilities omega and L-p for several organic solutes have been obtained.

关键词： PAA/PSF composite membrane reverse osmosis separation of aqueous organic solution

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Study of reverse osmosis membranes fouling by inorganic salts and colloidal particles during seawater desalination

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Chinese Journal of Chemical Engineering 2020年第3期28卷 733-742页

作者： Santiago Gutiérrez Ruiz Juan Antonio López-Ramírez Mohammed Hassani Zerrouk Agata Egea-Corbacho Lopera JoséMaría Quiroga Alonso Department of Environmental Technologies Faculty of Marine and Environmental SciencesUniversity of Cadiz11510Puerto RealCadizSpain

Fouling phenomenon is considered among the major reasons that cause significant increase of operating cost of desalination plants equipped with reverse osmosis(RO)membranes.This phenomenon is studied in the present work in the case of RO polyamide aromatic membranes using model seawater containing inorganic salts and colloidal compounds.Different solubility conditions of CaCO3 and CaSO4 were applied to study RO performances with and without colloid presence.During experiments,the membrane permeate fluxes were continuously monitored.Moreover,studies of chemical composition,structure,and morphology of the materials deposited on the membrane surface were conducted using energy dispersive microanalysis(EDS)X-ray diffraction and scanning electronic microscopy(SEM).Results show that in conditions of calcium carbonate oversaturation there is a reduction in the permeate flow of 11.2%due to fouling of the membrane by the precipitation of this compound.While in the same conditions of calcium sulphate oversaturation the reduction of the flow is 5%,so we can conclude that in conditions of oversaturation of both salts,calcium carbonate produces a greater fouling of the membrane that in its view causes greater decrease in the flow of permeate.All this based on the results of the test with both salts in oversaturated conditions.Resulting in the formation of calcite and gypsum crystals onto the membranes as XRD analyses stated.Additional presence of colloidal silica in those conditions intensifies strongly the fouling,leading until to 24.1%of permeate flux decrease.

关键词： reverse osmosis Desalination Fouling Seawater Scaling

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