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The Effect of recombination zone Positon on the Color Temperature Performance in the Color-Tunable White Organic Light-Emitting Diode

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Optics and Photonics Journal 2022年第4期12卷 78-87页

作者： Zhixiu Ma Ce Bian Zeyuan Gao College of Science University of Shanghai for Science and Technology Shanghai China

Using a color-tunable organic light-emitting diode (CT-OLED) can accord with the circadian cycle of humans and realize healthy lighting. The variation range of the correlated color temperature (CCT) is an important parameter to measure the performance of CT-OLEDs. In this paper, the effect of changing the utilization of phosphorescent materials and the position of the recombination zone (RZ) in the device are investigated by changing the thickness of the emissive layer (EML) and the doping ratio of the host and guest materials. The results show that reducing the red phosphorescent material and improving the blue phosphorescent material can affect the change direction of CCT, but it is not enough to expand the span of CCT (ΔCCT). It is more conducive to improving ΔCCT by more reasonable regulation of the position of the main RZ in EML and the energy transfer from the blue sub-EML to the red sub-EML. Device D obtains the best electro-optic and spectral characteristics, in which the maximum ΔCCT is 5746 K (2661 - 8407 K) as the voltage changes from 3.75 V to 9.75 V, the maximum current efficiency and luminance reach 18.34 cd·A-1 and 12,100 cd·m-2, respectively.

关键词： Optical Devices Organic Light-Emitting Diode Color-Tunable recombination zone Color Temperature

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The Study on the Relationship between Dynamic Balance Energy Distribution and Spectral Stability with Voltage Change in White Organic Light Emitting Diode

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Optics and Photonics Journal 2023年第3期13卷 35-46页

作者： Xinyu Zhu Zhiqi Kou Yanbo Wang Zhixiu Ma College of Science University of Shanghai for Science and Technology Shanghai China

The stable spectrum can be obtained when the voltage changes, which is a necessary condition for the white organic light emitting diode (WOLED) device to be widely used in the field of solid-state lighting. However, with the increase of voltage, the movement of the recombination zone (RZ) is inevitable because the perfect bipolar host material is difficult to obtain, which will redistribute the energy in the light emitting layer (EML) and affect the stability of the spectrum. We fabricate a series of ternary hybrid WOLEDs with a simple structure by inserting ultra-thin PO-T2T into the blue exciplex (TCTA:TPBi) to form the green interface exciplex. Without considering the movement of RZ, device B2 realizes the dynamic balance energy distribution in EML and stable spectrum by controlling two processes of the Dexter energy transfer and exciton capture. By modifying the doping ratio of the host material, we also find that the broadened RZ is helpful to further improve the spectral stability of the device. When the voltage changes from 3 V to 7 V, the change range of color coordinates is only (0.026, 0.025).

关键词： WOLED Spectral Stability Exciplex Energy Transfer recombination zone

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