检索结果-南通市图书馆

pyridine-triphenylamine hole transport material for inverted perovskite solar cells

Journal of Energy Chemistry 2021年第3期30卷 395-402页

作者： Shuang Ma Xianfu Zhang Xuepeng Liu Rahim Ghadari Molang Cai Yong Ding Muhammad Mateen Songyuan Dai Beijing Key Laboratory of Novel Thin-Film Solar Cells North China Electric Power UniversityBeijing 102206China State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources North China Electric Power UniversityBeijing 102206China Computational Chemistry Laboratory Department of Organic and BiochemistryFaculty of ChemistryUniversity of TabrizTabriz ***Iran

In the light of superior interaction between pyridine unit and perovskite,a facile star-shaped triphenylamine-based hole transport material(HTM)incorporating pyridine core(coded as H-Pyr)is designed and synthesized.A reference HTM with benzene core,coded as H-Ben,is also prepared for a comparative *** effects of varying core on HTMs are investigated by comparing the photophysical,electrochemical and hole mobility *** is found that pyridine core exhibits better conjunction and decreased dihedral angles with triphenylamine side arms than that of benzene,leading to obviously better hole mobility and well-matched work *** perovskite film prepared on H-Pyr also shows improved crystallization than on *** and electrochemical impedance studies indicate improved charge extraction and reduced recombination in the H-Pyr-based perovskite solar ***,H-Pyr-based device exhibits higher efficiency than H-Ben-based *** doping with a Lewis acid,tris(pentafluorophenyl)borane,H-Pyr-based device delivers a champion efficiency of 17.09%,which is much higher compared with 12.14% of the device employing conventional poly(3,4-ethy lenedioxythiophene)polystyrene sulfonate(PEDOT:PSS)as ***,the H-Pyr-based device displays good long-term stability that the power conversion efficiency remains over 80% of the initial value after storage in ambient(relative humidity=50±5%)for 20 days.

关键词： Perovskite solar cell Hole transport material pyridine-triphenylamine small molecule

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：