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Effect of thermal pretreatment on the surface structure of ptsn/sio2 catalyst and its performance in acetic acid hydrogenation

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Frontiers of Chemical Science and Engineering 2016年第3期10卷 417-424页

作者： Guozhen Xu Jian Zhang Shengping Wang Yujun Zhao Xinbin Ma Key Laboratory for Green Chemical Technology of Ministry of Education Collaborative Innovation Centre of Chemical Science and Engineering School of Chemical Engineering and Technology Tianjin University Tianjin 300072 China

The effect of thermal pretreatment on the active sites and catalytic performances of ptsn/sio2 catalyst in acetic acid （AcOH） hydrogenation was investigated in this article. The catalysts were characterized by N2 physical adsorption, X-ray diffraction, transmission electron microscopy, pyridine Fourier-transform infrared spectra, and H2-O2 titration on its physicochemical properties. The results showed that Pt species were formed primarily in crystalline structure and no ptsnx alloy was observed. Meanwhile, with the increment of thermal pretreatrnent temperature, Pt dispersion showed a decreas- ing trend due to the aggregation of Pt particles. Simultaneously, the amount of Lewis acid sites was remarkably influenced by such thermal pretreatment owning to the consequent physicochemical property variation of Sn species. Interestingly, the catalytic activity showed the similar variation trend with that of Lewis acid sites, confirming the important roles of Lewis acid sites in AcOH hydrogenation. Moreover, a balancing effect between exposed Pt and Lewis acid sites was obtained, resulting in the superior catalytic performance in AcOH hydrogenation.

关键词： thermal pretreatment acetic acid hydrogenation ethanol ptsn/sio2

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