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Geochemical characteristics of natural gases and source rocks in Obayied sub-basin,north Western Desert,Egypt:implications for gas-source correlation

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Acta Geochimica 2023年第2期42卷 241-255页

作者： Mostafa Hassan Mahmoud Leila Mohammed Ahmed Ghalib Issa Omar Hegab Geology Department Faculty of ScienceMansoura UniversityMansoura 35516Egypt Egyptian General Petroleum Corporation CairoEgypt

Western Desert represents a major oil and gas province in Egypt producing more than 50%of the country’s oil production.Oil and gas blend occurs in most producing fields,however,the genetic link between gas and liquid hydrocarbon phases are not well-constrained.Obayied sub-basin in the Western Desert where oil and gas phases coexist in the Middle Jurassic sandstones of the Khatatba Formation provides an ideal place to investigate the link between oil and gas generation.Geochemical analyses on rock samples(Rock–Eval pyrolysis,vitrinite reflectance,R_(o))and gases(molecular and isotopic composition)were conducted in order to identify the genetic characteristics of the hydrocarbon phases produced.Maturity-relevant parameters(Rock–Eval T_(max),vitrinite reflectance R_(o))elucidate that only Middle Jurassic Khatatba organofacies capable of generating wet and dry hydrocarbon gases.Additionally,the enrichment of C_(7)normal alkanes,mono-branched alkanes relative to polybranched components in the Obayied gases reflect their generation via cracking of oil.Basin modelling results confirm gas generation through both primary and secondary cracking.However,secondary cracking of liquid hydrocarbon phases is volumetrically more significant.primary cracking of the Khatatba organofacies likely predate and catalyze the secondary cracking of the liquid phases and therefore the volume of generated gas increases incrementally eastward where both processes coexist.The present study highlights the significant role of secondary cracking in the generation and accumulation of huge gas accumulations in the basins containing oil-prone source intervals.

关键词： primary and secondary cracking Gas geochemistry Jurassic Khatatba Obayied Western Desert

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