检索结果-南通市图书馆

Small but mighty:Empowering sodium/potassium-ion battery performance with S-doped SnO2 quantum dots embedded in N,S codoped carbon fiber network

引用

Carbon Energy 2024年第5期6卷 186-200页

作者： Shengnan He Hui Wu Shuang Li Ke Liu Yaxiong Yang Hongge Pan Xuebin Yu Institute of Science and Technology for New Energy Xi'an Technological UniversityXi'anChina Department of Materials Science Fudan UniversityShanghaiChina Wanxiang A123 Systems Corporation HangzhouChina School of Material Science and Engineering Shanghai UniversityShanghaiChina

SnO_(2) has been extensively investigated as an anode material for sodium-ion batteries(SIBs)and potassium-ion batteries(PIBs)due to its high Na/K storage capacity,high abundance,and low toxicity.However,the sluggish reaction kinetics,low electronic conductivity,and large volume changes during charge and discharge hinder the practical applications of SnO_(2)-based electrodes for SIBs and PIBs.Engineering rational structures with fast charge/ion transfer and robust stability is important to overcoming these challenges.Herein,S-doped SnO_(2)(S-SnO_(2))quantum dots(QDs)(≈3 nm)encapsulated in an N,S codoped carbon fiber networks(S-SnO_(2)-CFN)are rationally fabricated using a sequential freeze-drying,calcination,and S-doping strategy.Experimental analysis and density functional theory calculations reveal that the integration of S-SnO_(2) QDs with N,S codoped carbon fiber network remarkably decreases the adsorption energies of Na/K atoms in the interlayer of SnO_(2)-CFN,and the S doping can increase the conductivity of SnO_(2),thereby enhancing the ion transfer kinetics.The synergistic interaction between S-SnO_(2) QDs and N,S codoped carbon fiber network results in a composite with fast Na+/K+storage and extraordinary long-term cyclability.Specifically,the S-SnO_(2)-CFN delivers high rate capacities of 141.0 mAh g^(−1) at 20 A g^(−1) in SIBs and 102.8 mAh g^(−1) at 10 A g^(−1) in PIBs.Impressively,it delivers ultra-stable sodium storage up to 10,000 cycles at 5 A g^(−1) and potassium storage up to 5000 cycles at 2 A g^(−1).This study provides insights into constructing metal oxide-based carbon fiber network structures for high-performance electrochemical energy storage and conversion devices.

关键词： carbon fiber network heteroatom doping potassium-ion battery sodium-ion battery S-SnO2 quantum dot

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

The homogenous growth of Co-based coordination compound on graphene nanosheet for high-performance K-organic battery and its reaction mechanism

引用

Rare Metals 2024年第4期43卷 1622-1634页

作者： Qian-Qian Peng Yi-Ting Wang Shuo Qi Yao Xiao Yong Wang Shuang-Qiang Chen School of Environmental and Chemical Engineering Shanghai University School of Chemistry and Materials Engineering Wenzhou University

Metal coordination compounds（MCCs） are gaining popularity for potassium-ion batteries（PIBs）owing to their tuneable structure,multiple reaction sites,low cost and unique morphology.However,they are generally subjected to intrinsic features of the sluggish ionic diffusion coefficient,low electronic conductivity and slow kinetics.Herein,a new MCC material of cobalt-1,3,5-trioxy-2,4,6-triamino-benzo（Co-TB） coordination compound was synthesized and homogenously grown on the surface of graphene nanosheets（GNS）,forming a Co-TB@GNS composite with enhanced electronic conductivity and flexible capability.Benefiting from the overall enhanced conductivity,high surface area and abundant activated K-storage sites,Co-TB@GNS electrodes have exhibited superior cycling performance with high reversible capacities(312 mAh·g-1after 100 cycles at 100 mA·g-1,224 mAh·g-1after 500 cycles at 1 A·g-1) and better rate performances compared with the pure Co-TB compound when served as PIB's anodes.Furthermore,multiple in-situ measurement techniques have jointly confirmed that the organic functional groups（C=O,C=N and C=C of benzene rings） and Co2+in Co-TB are the main reversible K-storage sites,including in-situ Fourier transform infrared spectroscopy（FTIR） and X-ray diffraction（XRD）,and partial capacity contribution is originated from GNS by the apparent K-storage behavior in the in-situ XRD pattern,proving the possibility of K-storage for metal-organic materials.

关键词： Metal coordination compounds potassium-ion battery Cobalt coordination compound K-storage mechanism

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Rational design of Sn_(4)P_(3)/Ti_(3)C_(2)Tx composite anode with enhanced performance for potassium-ion battery

引用

Rare Metals 2022年第7期41卷 2259-2267页

作者： Jie Zhao Chao-Lin Li Gang Chen Fei Ji Yi-Yong Shen Juan Peng Wen-Hui Wang School of Civil and Environmental Engineering Harbin Institute of TechnologyShenzhen 518055China Shenzhen Environmental Technology Group Co.Ltd. Shenzhen 518049China State Key Laboratory of Urban Water Resource and Environment School of EnvironmentHarbin Institute of TechnologyHarbin 150090China

The potential application of high-capacity Sn_(4)P_(3)anode for potassium-ion batteries(PIBs)is hindered by the poor cycle stability mainly rooted from the huge volume changes upon cycling and low electronic conduc-tivity.To address the above issues,sandwich-like struc-tured Sn_(4)P_(3)/Ti_(3)C_(2)T_(x)was designed and synthesized as anode material for PIBs.As a result,Sn_(4)P_(3)/Ti_(3)C_(2)T_(x)pre-sents superior cycle stability(retains a capacity of 103.2 mAh·g^(-1)even after 300 cycles at 1000 mA·g^(-1))and rate capability(delivers 60.7 mAh·g^(-1)at high current density of 2000 mA·g^(-1)).The excellent electrochemical perfor-mance of sandwich-like structured Sn_(4)P_(3)/Ti_(3)C_(2)Tx is orig-inated from the synergistic effect between Sn_(4)P_(3)and Ti_(3)C_(2)T_(x),where Ti_(3)C_(2)T_(x)acts as a conductive matrix to facilitate electron transfer and buffer the volume change of Sn_(4)P_(3)particles upon cycling,while Sn_(4)P_(3)serves as pillars to prevent the collapse and stacking of Ti_(3)C_(2)T_(x)sheets.Moreover,significant capacitive contribution is demonstrated as a major contributor to the excellent rate capability.

关键词： Sn_(4)P_(3) Ti_(3)C_(2) TxAnode material potassium-ion battery

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Interconnected carbon nanocapsules with high N/S co-doping as stable and high-capacity potassium-ion battery anode

引用

Journal of Energy Chemistry 2022年第3期31卷 195-204,I0007页

作者： Honghui Bi Xiaojun He Lei Yang Hongqiang Li Biyu Jin Jieshan Qiu School of Chemistry and Chemical Engineering Anhui Key Laboratory of Coal Clean Conversion and High Valued UtilizationKey Lab of Metallurgical Emission Reduction&Resources RecyclingMinistry of EducationAnhui University of TechnologyMaanshan 243002AnhuiChina College of Chemical Engineering Beijing University of Chemical TechnologyBeijing 100029China

Carbonaceous materials have drawn much attention in potassium-ion batteries (PIBs) due to their low price and superior physicochemical properties. However, the application of carbonaceous materials in PIB anodes is hindered by sluggish kinetics and large volume expansion. Herein, N/S co-doped carbon nanocapsule (NSCN) is constructed for superior K+ storage. The NSCN possesses 3D nanocapsule framework with abundant meso/macropores, which guarantees structural robustness and accelerates ions/electrons transportation. The high-level N/S co-doping in carbon matrix not only generates ample defects and active sites for K+ adsorption, but also expands interlayer distance for facile K+ intercalation/deintercalation. As a result, the NSCN electrode delivers a high reversible capacity (408 mAh g^(−1) at 0.05 A g^(−1)), outstanding rate capability (149 mAh g^(−1) at 5 A g^(−1)) and favorable cycle stability (150m Ah g^(−1) at 2 A g^(−1) after 2000 cycles). Ex situ TEM, Raman and XPS measurements demonstrate the excellent stability and reversibility of NSCN electrode during potassiation/depotassiation process. This work provides inspiration for the optimization of energy storage materials by structure and doping engineering.

关键词： 3D Carbon nanocapsules N/S co-doping Carbon anode potassium-ion battery

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Fluorinated soft carbon as an ultra-high energy density potassium-ion battery cathode enabled by a ternary phase K_(x)FC

引用

Journal of Energy Chemistry 2023年第2期77卷 38-44,I0002页

作者： Pengyu Chen Bojun Wang Zhenrui Wu Xiaobin Niu Chuying Ouyang Hong Li Liping Wang School of Materials and Energy University of Electronic Science and Technology of ChinaChengdu 611731SichuanChina School of Engineering The University of British ColumbiaKelowna V1V 1V7Canada C Innovation Laboratory Contemporary Amperex Technology Ltd.(21C LAB)Ningde 352100FujianChina Key Laboratory for Renewable Energy Institute of PhysicsChinese Academy of SciencesBeijing 100190China

Fluorinated carbons(CFx)have been widely applied as lithium primary batteries due to their ultra-high energy density.It will be a great promise if CFx can be rechargeable.In this study,we rationally tune the C-F bond strength for the alkaline intercalated CFx via importing an electronegative weaker element K instead of Li.It forms a ternary phase K_(x)FC instead of two phases(LiF+C)in lithium-ion batteries.Meanwhile,we choose a large layer distance and more defects CFx,namely fluorinated soft carbon,to accommodate K.Thus,we enable CFx rechargeable as a potassium-ion battery cathode.In detail fluorinated soft carbon CF_(1.01) presents a reversible specific capacity of 339 mA h g^(-1)(797 Wh kg^(-1))in the 2nd cycle and maintains 330 mA h g^(-1)(726 Wh kg^(-1))in the 15th cycle.This study reveals the importance of tuning chemical bond stability using different alkaline ions to endow batteries with rechargeability.This work provides good references for focusing on developing reversible electrode materials from popular primary cell configurations.

关键词： Fluorinated carbon High energy density battery potassium-ion battery Conversion reaction K-free cathode

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

N/S co-doped carbon nanosheet bundles as high-capacity anode for potassium-ion battery

引用

Nano Research 2022年第3期15卷 2040-2046页

作者： Jinhui Cao Jiang Zhong Hanjiao Xu Shengyang Li Hongli Deng Tao Wang Ling Fan Xinghui Wang Lei Wang Jian Zhu Bingan Lu Xidong Duan Hunan Key Laboratory of Two-Dimensional Materials State Key Laboratory for Chemo/Biosensing and ChemometricsCollege of Chemistry and Chemical EngineeringHunan UniversityChangsha 410082China School of Physics and Electronics Hunan UniversityChangsha 410082China College of Physics and Information Engineering Institute of Micro-Nano Devices and Solar CellsFuzhou UniversityFuzhou 350108China

potassium-ion batteries(PIBs)are of academic and economic significance,but still limited by the lack of highly active electrode materials for de-/intercalation of large-radius K ions.Herein,an interconnected nitrogen/sulfur co-doped carbon nanosheep bundle(N/S-CSB)was proposed as the potassium ions storage material.The rich co-doping of nitrogen/sulfur of N/S-CNB with three-dimensional hierarchical bundled array structure yields distensible interlayer spaces to buffer the volume expansion during K+insertion/extraction,offers more electrochemical active sites to obtain a high specific capacity,and provides efficient channels for fast ion/electron transports.Therefore,the N/S-CSB anode achieved high reversible specific capacity of 365 mAh/g obtained at 50 mA/g after 200 cycles with a coulombic efficiency(CE)close to 100%,high rate performance and long cycle stability.Moreover,the in-situ Raman spectra indicated outstanding reaction kinetics of as-prepared N/S-CSB anode.

关键词： potassium-ion battery anode carbon nanosheet bundles N/S co-doping high capacity long cycle

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Single-crystalline Mn-based oxide as a high-rate and long-life cathode material for potassium-ion battery

引用

eScience 2023年第1期3卷 80-88页

作者： Jiarui Lv Bin Wang Jiaxin Hao Hongbo Ding Ling Fan Renqian Tao Hongguan Yang Jiang Zhou Bingan Lu School of Physics and Electronics Hunan UniversityChangsha410082PR China School of Physics and Electronic Engineering Xinxiang UniversityXinxiang45300PR China School of Physical Science and Technology Lanzhou UniversityLanzhou730000PR China School of Materials Science and Engineering Central South UniversityChangsha410083PR China

Mn-based oxides are promising cathode materials for potassium-ion batteries due to their high theoretical ca-pacity and abundant raw materials.However,the anisotropic properties of their conventional polycrystalline structures lead to insufficient rate capability and cycle life.Here,a single-crystal Mn-based layered oxide,P3′-type K_(0.35)Mn_(0.8)Fe_(0.1)Cu_(0.1)O_(2)(KMFCO),is designed and synthesized through a bimetallic co-induction effect and used as a cathode for potassium-ion battery.Benefiting from a unique single-crystal structure that is devoid of grain boundaries,it achieves a higher Kþtransport rate and a reduced volume change during the Kþintercalation/deintercalation process.Accordingly,the single-crystal P3′-type KMFCO delivers superior rate capability(52.9 mAh g^(-1) at 1000 mA g^(-1))and excellent cycling stability(91.1%capacity retention after 500 cycles at 500 mA g^(-1)).A full cell assembled with the P3′-type KMFCO cathode and a graphite anode also exhibits a high reversible capacity(81.2 mAh g^(-1) at 100 mA g^(-1))and excellent cycling performance(97%capacity retention after 300 cycles).The strategy of developing single-crystal materials may offer a new pathway for maintaining structural stability and improving the rate capability of layered manganese oxide cathodes and beyond.

关键词： potassium-ion battery Cathode Single-crystal Mn-based layered oxide

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Heteroatom tuning in agarose derived carbon aerogel for enhanced potassium ion multiple energy storage

引用

Carbon Energy 2024年第3期6卷 239-254页

作者： Kaijun Xie Xin Liu Haolin Li Long Fang Kai Xia Dongjiang Yang Yihui Zou Xiaodong Zhang State Key Laboratory of Bio-fibers and Eco-textiles Shandong Collaborative Innovation Center of Marine Biobased Fibers and Ecological TextilesInstitute of Marine Biobased MaterialsCollege of Chemistry and Chemical EngineeringCollege of Environmental Science and EngineeringQingdao UniversityQingdaoChina

The incorporation of heteroatoms into carbon aerogels(CAs)can lead to structural distortions and changes in active sites due to their smaller size and electronegativity compared to pure carbon.However,the evolution of the electronic structure from single-atom doping to heteroatom codoping in CAs has not yet been thoroughly investigated,and the impact of codoping on potassium ion(K+)storage and diffusion pathways as electrode material remains unclear.In this study,experimental and theoretical simulations were conducted to demonstrate that heteroatom codoping,composed of multiple heteroatoms(O/N/B)with different properties,has the potential to improve the electrical properties and stability of CAs compared to single-atom doping.Electronic states near the Fermi level have revealed that doping with O/N/B generates a greater number of active centers on adjacent carbon atoms than doping with O and O/N atoms.As a result of synergy with enhanced wetting ability(contact angle of 9.26°)derived from amino groups and hierarchical porous structure,ON-CA has the most optimized adsorption capacity(−1.62 eV)and diffusion barrier(0.12 eV)of K^(+).The optimal pathway of K^(+)in ON-CA is along the carbon ring with N or O doping.As K^(+)storage material for supercapacitors and ion batteries,it shows an outstanding specific capacity and capacitance,electrochemical stability,and rate performance.Especially,the assembled symmetrical K^(+)supercapacitor demonstrates an energy density of 51.8 Wh kg^(−1),an ultrahigh power density of 443Wkg^(−1),and outstanding cycling stability(maintaining 83.3%after 10,000 cycles in 1M KPF6 organic electrolyte).This research provides valuable insights into the design of highperformance potassium ion storage materials.

关键词： agarose carbon aerogels O/N/B codoping potassium-ion battery potassium-ion supercapacitor

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Coupling Sb_(2)WO_(6)microflowers and conductive polypyrrole for efficient potassium storage by enhanced conductivity and K^(+) diffusivity

引用

Journal of Energy Chemistry 2024年第2期89卷 250-258,I0007页

作者： Ruiqi Tian Hehe Zhang Zeyu Yuan Yuehua Man Jianlu Sun Jianchun Bao Ming-Sheng Wang Xiaosi Zhou School of Chemistry and Materials Science Nanjing Normal UniversityNanjing 210023JiangsuChina State Key Lab of Physical Chemistry of Solid Surfaces College of MaterialsXiamen UniversityXiamen 361005FujianChina

Although metal oxide compounds are considered as desirable anode materials for potassium-ion batteries(PIBs)due to their high theoretical capacity,the large volume variation remains a key issue in realizing metal oxide anodes with long cycle life and excellent rate property.In this study,polypyrroleencapsulated Sb_(2)WO_(6)(denoted Sb_(2)WO_(6)@PPy)microflowers are synthesized by a one-step hydrothermal method followed by in-situ polymerization and coating by pyrrole.Leveraging the nanosheet-stacked Sb_(2)WO_(6)microflower structure,the improved electronic conductivity,and the architectural protection offered by the PPy coating,Sb_(2)WO_(6)@PPy exhibits boosted potassium storage properties,thereby demonstrating an outstanding rate property of 110.3 m A h g^(-1)at 5 A g^(-1)and delivering a long-period cycling stability with a reversible capacity of 197.2 m A h g^(-1)after 500 cycles at 1 A g^(-1).In addition,the conversion and alloying processes of Sb_(2)WO_(6)@PPy in PIBs with the generation of intermediates,K_(2)WO_(4)and K_(3)Sb,is determined by X-ray photoelectron spectroscopy,transmission electron microscopy,and exsitu X-ray diffraction during potassiation/depotassiation.Density functional theory calculations demonstrate that the robust coupling between PPy and Sb_(2)WO_(6)endues it with a much stronger total density of states and a built-in electric field,thereby increasing the electronic conductivity,and thus effectively reduces the K^(+)diffusion barrier.

关键词： Sb_(2)WO_(6) Polypyrrole coating Anode potassium-ion battery In-situ TEM observation

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Facile synthesis of KVPO_(4)F/reduced graphene oxide hybrid as a high-performance cathode material for potassium-ion batteries

引用

Journal of Energy Chemistry 2022年第5期31卷 284-292页

作者： Jianzhi Xu Jiaying Liao Yifan Xu Jianbo Li Chuannan Zhu Jun Lin Xiaosi Zhou Jiangsu Key Laboratory of New Power Batteries Jiangsu Collaborative Innovation Center of Biomedical Functional MaterialsSchool of Chemistry and Materials ScienceNanjing Normal UniversityNanjing 210023JiangsuChina

potassium-ion batteries(PIBs) as a substitute for lithium-ion batteries have aroused widespread attention and have been rapidly developed. In the positive electrode materials, polyanionic compound has a high working voltage and large reversible capacity on account of its distinct framework and the strong inducing effect of the anionic group. Herein, a KVPO_(4)F/reduced graphene oxide(KVPF/r GO) hybrid was fabricated via a simple multi-step approach as the polyanionic cathode material for PIBs. Profiting from the small size of KVPF nanoparticles and their uniform distribution in the r GO framework, the assynthesized KVPF/r GO hybrid manifests a large discharge capacity of 103.2 mAh g^(-1) with an outstanding energy density of 436.5 Wh kg^(-1). Through r GO decoration, the hybrid also demonstrates remarkable rate and cycling properties. By employing ex-situ X-ray diffraction(XRD) and X-ray photoelectron spectroscopy(XPS) techniques, the potassium storage mechanism of KVPF was clearly revealed. The facile preparation procedure and superior properties endow it great application prospects in large-scale energy storage.

关键词： KVPO_(4)F potassium-ion battery Cathode Reduced graphene oxide Ex-situ XRD

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：