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Intramolecular carbon isotope of propane from coal-derived gas reservoirs of sedimentary basins:Implications for source,generation and post-generation of hydrocarbons

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Geoscience Frontiers 2024年第4期15卷 230-244页

作者： Xiaofeng Wang Peng Liu Wenhui Liu Changjie Liu Ying Lin Dongdong Zhang State Key Laboratory of Continental Dynamics Department of GeologyNorthwest UniversityXi’an 710069China College of Safety Science and Engineering Xi’an University of Science and TechnologyXi’an 710054China State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development Petroleum Exploration and Production Research InstituteSINOPECBeijing 100083China Northwest Institute of Eco-Environment and Resources Chinese Academy of SciencesLanzhou 730000China Department of Earth and Planetary Sciences University of CaliforniaRiversideRiversideCA 92521USA

An intramolecular isotopic study was conducted on natural gases collected from coal-derived gas reser-voirs in sedimentary basins of China to determine their position-specific isotope *** propane from the Turpan-Hami Basin exhibited negativeΔc-T(δ13Ccentral-δ13Cterminal)values ranging from-3.9‰to-0.3‰,with an average of-2.1‰.Propane from the Ordos Basin,Sichuan Basin,and Tarim Basin showed positiveΔC-T values,with averages of 1.3‰,5.4‰and 7.6‰,*** carbon isotope compositions reveal the precursors and the propane generation pathways in the petroliferous *** formed from the thermal cracking of TypeⅢkerogen has largerδ13Ccentral andδ13Cterminal values than propane from TypeⅠ/Ⅱ*** precursor for natural gases collected in this study is identified to be TypeⅢ*** our data to calculated results for thermal cracking of TypeⅢkerogen,we found that propane from the low-maturity gas reservoir in the Turpan Basin was generated via the i-propyl radical pathway,whereas propane from the Sulige tight gas reservoir in the Ordos Basin was formed via the n-propyl radical pathway.δ13Cterminal values covered a narrow range across basins,in contrast toδ*** terminal carbon position in propane is less impacted by microbial oxidation and more relevant to maturity levels and ***,δ13Cterminal has a good potential to infer the origin and maturity level of natural *** examining post-generation processes,we proposed an improved identification strategy for microbial oxidation of natural gases,based on the position-specific carbon isotope distributions of *** from the Liaohe Depression of the Bohai Bay Basin and the Sichuan Basin were detected of post-generation microbial ***,position-specific carbon isotope composition of propane provides new insights into the generation mechanism and post-generation processes of natural gas in the geological period at the atomic level.

关键词： Intramolecular isotope position-specific isotope Kinetic isotope effects Microbial anaerobic oxidation

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