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An integrated strategy towards the facile synthesis of core-shell SiC-derived carbon@N-doped carbon for high-performance supercapacitors

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Journal of Energy Chemistry 2021年第5期30卷 512-521页

作者： Zhongya Pang Guangshi Li Xingli Zou Chenteng Sun Conghui Hu Wei Tang Li Ji Hsien-Yi Hsu Qian Xu Xionggang Lu State Key Laboratory of Advanced Special Steel&Shanghai Key Laboratory of Advanced Ferrometallurgy&School of Materials Science and Engineering Shanghai UniversityShanghai 200444China State Key Laboratory of ASIC and System School of MicroelectronicsFudan UniversityShanghai 200433China School of Energy and Environment&Department of Materials Science and Engineering City University of Hong KongKowloon Tong 999077Hong KongChina Shenzhen Research Institute of City University of Hong Kong Shenzhen 518057GuangdongChina

porous active core-shell carbon material with excellent synergistic effect has been regarded as a prospective material for ***,we report an integrated method for the facile synthesis of carbide-derived carbon(CDC)encapsulated with porous N-doped carbon(CDC@NC)towards highperformance ***(PDA)as nitrogen and carbon sources was simply coated on SiC nanospheres to form SiC@PDA,which was then directly transformed into CDC@NC via a onestep molten salt electro-etching/in-situ doping *** synthesized CDC@NC with hierarchically porous structure has a high specific surface area of 1191 m^(2) g^(-1).The CDC core and NC shell are typical amorphous carbon and more ordered N-doped carbon,*** from its unique dual porous structures,the CDC@NC demonstrates high specific capacitances of 255 and 193 F g^(-1) at 0.5 and20 A g^(-1),*** reaction mechanism of the electro-etching/in-situ doping process has also been investigated through experimental characterizations and theoretical density functional theory *** is suggested that the molten salt electro-etching/in-situ doping strategy is promising for the synthesis of active core-shell porous carbon materials with synergistic properties for supercapacitors without the need for additional doping/activation processes.

关键词： Molten salt Electrochemical etching Core-shell structure porous carbon In-situ nitrogen doping Supercapacitors

High-performance oxygen reduction and evolution carbon catalysis： From mechanistic studies to device integration

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Nano Research 2017年第4期10卷 1163-1177页

作者： John W. F. To Jia Wei Desmond Ng Samira Siahrostami Ai Leen Koh Yangjin Lee Zhihua Chen Kara D. Fong Shucheng Chen Jiajun He Won-Gyu Bae Jennifer Wilcox Hu Young Jeong Kwanpyo Kim Felix Studt Jens K. Nфrskov Thomas F. Jaramillo Zhenan Bao Department of Chemical Engineering Stan ford University Stanford CA 94305 USA Institute of Chemical and Engineering Sciences Agency for Science Technology and Research Jurong Island 627833 Singapore Stanford Nano Shared Facilities Stanford University Stanford CA 94305 USA Department of Physics Ulsan National Institute of Science and Technology (UNIST) Ulsan 689-798 Republic of Korea Department of Chemical and Biological Engineering Colorado School of Mines Golden CO 80401 USA UNIST Central Research Facilities (UCRF) Ulsan National Institute of Science and Technology (UNIST) Ulsan 689-798 Republic of Korea SUNCAT Center for Interface Science and Catalysis SLAC National Accelerator Laboratory 2575 Sand Hill Road Menlo Park CA 94025 USA Institute of Catalysis Research and Technology Karlsruhe Institute of Technology Hermann-von-Helmholtz Platz 1 76344 Eggenstein-Leopoldshafen Germany Institute for Chemical Technology and Polymer Chemistry Karlsruhe Institute of Technology Engesserstr. 18 76131 Karlsruhe Germany

The development of high-performance and low-cost oxygen reduction and evolution catalysts that can be easily integrated into existing devices is crucial for the wide deployment of energy storage systems that utilize O2-H2O chemistries, such as regenerative fuel cells and metal-air batteries. Herein, we report an NHB-activated N-doped hierarchical carbon （NHC） catalyst synthesized via a scalable route, and demonstrate its device integration. The NHC catalyst exhibited good performance for both the oxygen reduction reaction （ORR） and the oxygen evolution reaction （OER）, as demonstrated by means of electrochemical studies and evaluation when integrated into the oxygen electrode of a regenerative fuel cell. The activities observed for both the ORR and the OER were comparable to those achieved by state-of-the-art Pt and Ir catalysts in alkaline environments. We have further identified the critical role of carbon defects as active sites for electrochemical activity through density functional theory calculations and high-resolution TEM visualization. This work highlights the potential of NHC to replace commercial precious metals in regenerative fuel cells and possibly metal-air batteries for cost-effective storage of intermittent renewable energy.

关键词： electrocatalysis porous carbon density functional theory

Molten salt assisted self-activated carbon with controllable architecture for aqueous supercapacitor

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Journal of Materials Science & Technology 2023年第25期156卷 107-117页

作者： Wei Zhang Wenxian Li Sean Li School of Materials Science and Engineering The University of New South WalesKensingtonNew South Wales 2052Australia UNSW Materials and Manufacturing Futures Institute The University of New South WalesKensingtonNew South Wales 2052Australia

Activated carbons have been widely employed as electrode materials of aqueous supercapacitors but the use of hazardous and corrosive activating agents challenges conventional activation ***,using a unique molten salt assisted self-activation technique,we have devised an eco-friendly and simple method to synthesize oxygen-rich hierarchical porous carbon with controllable *** of sodium carboxymethylcellulose and NaCl was pyrolyzed in one step,creating in-situ produced Na_(2)CO_(3)-NaCl molten salt that carried out the activation ***2 CO3 acts as the activating agent in the reaction media of NaCl during the self-activation *** obtained carbon exhibited a remarkable specific capacitance of 278 F g^(−1) at 0.5 A g^(−1) and retained 76%capacitance at 50 A g^(−1) in a three-electrode *** fabricated aqueous coin cell achieved 81%capacitance retention at 50 A g^(−1) and the highest specific energy density of 12.8 Wh kg^(−1) at 214.6 W kg^(−1),which are superior compared to the commercial activated carbon(64%at 50 A g^(−1) and 8.4 Wh kg^(−1) at 194.8 W kg^(−1)).Moreover,capacitance fading was not observed after 10000 cycles at 5 A g^(−1).Considering the species diversity and low cost of self-salt polymers on the market,this strategy will expect to become a scalable approach for synthesizing high-performance capacitive carbons.

关键词： Molten salt Self-template porous carbon Controllable architecture Aqueous supercapacitors

Surface functionalized N-C-TiO_(2)/C nanocomposites derived from metal-organic framework in water vapour for enhanced photocatalytic H generation

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Journal of Energy Chemistry 2021年第6期30卷 485-495,I0012页

作者： Mian Zahid Hussain Zhuxian Yang Bart van der Linden Zheng Huang Quanli Jia Erik Cerrato Roland A.Fischer Freek Kapteijn Yanqiu Zhu Yongde Xia College of Engineering Mathematics and Physical SciencesUniversity of ExeterExeter EX44QFUnited Kingdom Department of Chemistry and Catalysis Research Center Technical University of MunichGarching 85748Germany Catalysis Engineering Chemical Engineering DepartmentDelft University of Technologyvan der Maasweg92629 HZ DelftNetherlands Henan Key Laboratory of High Temperature Functional Ceramics Zhengzhou UniversityZhengzhou 450052HenanChina Department of Chemistry University of TurinVia P.Giuria710125 TurinItaly

Surface-functionalized nitrogen/carbon co-doped polymorphic TiO_(2) phase junction nanoparticles uniformly distributed in porous carbon matrix were synthesized by a simple one-step pyrolysis of titanium based metal-organic framework(MOF),NH_(2)-MIL^(-1)25(Ti) at 700℃ under water vapour *** water vapour during the pyrolysis of NH_(2)-MIL^(-1)25(Ti) not only functionalizes the derived porous carbon matrix with carboxyl groups but also forms additional oxygen-rich N like interstitial/intraband states lying above the valence band of TiO2 along with the self-doped carbo n,which further narrows the energy band gaps of polymorphic TiO2 nanoparticles that enhance photocatalytic charge transfer *** co-catalyst,sample N-C-TiO2/CArW demonstrates H_(2) evolution activity of 426 μmol gcat-1h^(-1),which remarkably outperforms commercial TiO_(2)(P-25) and N-C-TiO_(2)/CAr with a 5-fold and 3-fold H_(2) generation,*** study clearly shows that water vapour atmosphere during the pyrolysis increases the hydrophilicity of the Ti-MOF derived composites by functionalizing porous carbon matrix with carboxylic groups,as well as enhancing the electrical conductivity and charge transfer efficiency due to the formation of additional localized oxygen-rich N like interstitial/intraband *** work also demonstrates that by optimizing the anatase-rutile phase composition of the TiO2 polymorphs,tuning the energy band gaps by N/C co-doping and functionalizing the porous carbon matrix in the N-C-TiO2/C nanocomposites,the photocatalytic H_(2) generation activity can be further enhanced.

关键词： Metal-organic framework TiO_(2) porous carbon Nanocomposite Photocatalysis Hydrogen generation

Photothermal materials for efficient solar powered steam generation

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Frontiers of Chemical Science and Engineering 2019年第4期13卷 636-653页

作者： Fenghua Liu Yijian Lai Binyuan Zhao Robert Bradley Weiping Wu State Key Laboratory of Metal Matrix Composites School o f Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai 200240China Department of Materials University of OxfordOxfordOX13PHUK MatSurf Technology Ltd. CumbriaCA101NWUK Department of Electrical and Electronic Engineering School of MathematicsComputer Science and EngineeringCityUniversity of LondonNorthampton SquareLondonEC 1V OHBUK

Solar powered steam generation is an emerging area in the field o f energy harvest and sustainable *** nano-structured photothermal materials are able to harvest energy from the full solar spectrum and convert it to heat with high ***,the materials and structures for heat management as well as the mass transportation are also brought to the *** groups have reported their materials and structures as solutions for high performance devices,a few creatively coupled other physical fields with solar energy to achieve even better *** paper provides a systematic review on the recent developments in photothermal nanomaterial discovery,material selection,structural design and mass/heat management,as well as their applications in seawater desalination and fresh water production from waste water with free solar *** also discusses current technical challenges and likely future *** article will help to stimulate novel ideas and new designs for the photothermal materials,towards efficient,low cost practical solar-driven clean water production.

关键词： solar stream generation plasmonics porous carbon photothermal materials solar energy conversion efficiency water vapor generation rate

Spacing graphene and Ni-Co layered double hydroxides with polypyrrole for high-performance supercapacitors

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Journal of Materials Science & Technology 2020年第20期52卷 190-197页

作者： Jing Liang Cuili Xiang Yongjin Zou Xuebu Hu Hailiang Chu Shujun Qiu Fen Xu Lixian Sun Guangxi Key Laboratory of Information Materials Guilin University of Electronic TechnologyGuilin 541004China Chongqing University of Technology College of Chemistry&Chemical EngineeringChongqing 400054China

The urgent need of high-performance of energy storage devices triggers us to design newly class of ***,the materials feature with high conductivity,abundant pore s and excellent ***,a sandwiched hybrid composite containing reduced graphene oxide,polypyrrole and Ni-Co layered double hydroxides(RGO/PPy/NiCo-LDH) was prepared in a facile *** polypyrrole was incorporated in the two dimensional(2D) nanosheets,which not only serve as the spacer to increase the surface area,but also enhance the conductivity of the *** obtained architecture was employed as an advanced electrode in a *** electrode shows an ultrahigh specific capacitance(2534 F g^-1 at 1 A g^-1) and good cycling efficiency(78 % after 5000 cycles).Moreover,an asymmetric cell based RGO/PPy/NiCo-LDH composite demonstrates excellent electrochemical properties and good prospect of practical use.

关键词： Graphene Ni-Co layered double hydroxides Polypyrrole Supercapacitor porous carbon

FeCo alloy catalysts promoting polysulfide conversion for advanced lithium-sulfur batteries

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Journal of Energy Chemistry 2020年第10期29卷 339-347页

作者： Hongyi Li Linfeng Fei Rong Zhang Shenglan Yu Yongyi Zhang Longlong Shu Yong Li Yu Wang School of Materials Science and Engineering Nanchang UniversityNanchang 330031JiangxiChina Division of Nanomaterials and Jiangxi Key Lab of carbonene Materials Suzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesNanchang 330200JiangxiChina College of Chemistry Biology and Material ScienceEast China University of TechnologyNanchang 330013JiangxiChina

Lithium sulfur batteries(LSBs)draw extensive interest because of the ultra-high capacity and low material ***,the sluggish lithium polysulfides(LIPSs)conversion processes are detrimental to cycle stability and rate capability,inhibiting the commercial application of *** we present the well-designed Fe Co alloy catalysts anchored on porous carbon(FeCo-C)as sulfur host to improve the electrochemical performance by accelerating the conversion *** FeCo alloy demonstrates high catalytic effect and strong adsorption capability of LIPSs,in which potential polarization can be greatly decreased and"shuttle effects"can be largely *** a result,the obtained S/Fe Co-C composites show an initial specific capacity of 791.9 m Ah g^-1 at a large current density of 2 C and maintain 502.5 mAh g^-1 even after 500 ***,720 m Ah g^-1(corresponding to 70%retention)can be achieved after 100 cycles at 0.2 C with a high sulfur content of 80 wt%,enabling high sulfur *** work not only provides a new insight to investigate the conversion kinetics of Li PSs,but also opens up a new avenue for advanced lithium sulfur batteries.

关键词： Lithium sulfur batteries FeCo alloys Catalysts Adsorption porous carbon

Metal-organic framework derived multi-functionalized and co-doped TiO_(2)/C nanocomposites for excellent visible-light photocatalysis

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Journal of Materials Science & Technology 2022年第6期101卷 49-59页

作者： Mian Zahid Hussain Zhuxian Yang Ahmed M.E.Khalil Shahzad Hussain Saif Ullah Awan Quanli Jia Roland A.Fischer Yanqiu Zhu Yongde Xia College of Engineering Mathematics and Physical SciencesUniversity of ExeterExeter EX44QFUnited Kingdom Department of Chemistry and Catalysis Research Centre Technical University of MunichGarching85748Germany Department of Chemical Engineering Faculty of EngineeringCairo UniversityGiza 12613Egypt Department of Physics COMSATS University Islamabad45550 Pakistan Department of Electrical Engineering National University of Sciences and TechnologyIslamabadPakistan Henan Key Laboratory of High Temperature Functional Ceramics Zhengzhou UniversityZhengzhou 450052China

Multi-functionalized and co-doped TiO_(2)/C nanocomposites were derived from the pyrolysis of Ti-MOFs at 800℃under different gaseous atmospheres and their photocatalytic performance were *** gaseous atmosphere during pyrolysis plays a critical role in determining the structural,textural,optical and physicochemical properties of the derived TiO_(2)/C composites due to the synergistic effect of nitrogen-containing species,carboxylate and sulfur functionalized porous carbon as well as N/S co-doped TiO_(2)*** the Ti-MOFs derived TiO_(2)/C composites exclusively possess homogeneously distributed TiO_(2)nanoparticles in a functionalized disc-like porous carbon matrix and demonstrate much enhanced adsorption and photodegradation performance than commercial TiO_(2)under the same *** adsorption of methylene blue(MB)in dark on these TiO_(2)/C composites are dominated with pseudo second-order kinetic model and the high adsorption capacity of MB in dark on composite TiO_(2)/C derived from MIL-125(Ti)in argon is due to its high surface area with predominant mesoporous carbon matrix in the *** composite N-O-TiO_(2)/C derived from NH2-MIL-125(Ti)in water vapor exhibited the highest photodegradation activity with 99.7%MB removal in 3 h under visible light due to the optimal anatase/rutile phasejunction,together with the formation of photoactive oxygen-rich N-O like interstitial/intraband states above the valence band of TiO_(2),as well as the presence of N-containing species and-OH/-COOH multi-functional groups with superhydrophilic nature of the *** simple one-step and easily modifiable approach can be further employed to modulate homogeneously dispersed multi-functionalized and co-doped metal oxide/carbon nanocomposites for various environment and energy-related applications.

关键词： Nanocomposite MOF derivative TiO_(2) porous carbon Photocatalysis

Recent Advances of porous Solids for Ultradilute CO_(2) Capture

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Chemical Research in Chinese Universities 2022年第1期38卷 18-30页

作者： LIU Ru-Shuai XU Shuang HAO Guang-Ping LU An-Hui State Key Laboratory of Fine Chemicals Liaoning Key Laboratory for Catalytic Conversion Carbon ResourcesSchool of Chemical EngineeringDalian University of TechnologyDalian 116024P.R.China

The urgency of dealing with global climate change caused by greenhouse gas(GHG) emissions is increasing as the carbon dioxide(CO_(2)) concentration in the atmosphere has reached a record high value of 416 ppm(parts per million). Technologies that remove CO_(2) from the surrounding air(direct air capture, DAC) could result in negative carbon emissions, and thus attracts increasing attention. The steady technical progress in adsorption-based CO_(2) separation greatly advanced the DAC, which largely relies on advanced sorbent materials. This review focuses on the latest development of porous solids for air capture;first discussed the main types of sorbents for air capture, which include porous carbons, zeolites, silica materials, and metal-organic frameworks(MOFs), particularly their modified counterparts. Then, we evaluated their performances, including uptake and selectivity under dry and humid CO_(2) streams for practical DAC application. Finally, a brief outlook on remaining challenges and potential directions for future DAC development is given.

关键词： Direct air capture porous carbon CO_(2)capture porous solid Adsorption