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polyzwitterionic cross-linked double network hydrogel electrolyte enabling high-stable Zn anode

Nano Research 2024年第6期17卷 5278-5287页

作者： Mengyu Shi Junlong Zhang Guochuan Tang Ben Wang Sen Wang Xiaoxian Ren Guojie Li Weihua Chen Chuntai Liu Changyu Shen State Key Laboratory of Structural Analysis Optimization and CAE Software for Industrial EquipmentNational Engineering Research Center for Advanced Polymer Processing TechnologyZhengzhou UniversityZhengzhou 450002China College of Chemistry and Green Catalysis Center Zhengzhou UniversityZhengzhou 450001China Research Institute of Interdisciplinary Science and School of Materials Science and Engineering Dongguan University of TechnologyDongguan 523808China

Zn metal anode suffers from dendrite issues and passive byproducts,which severely plagues the practical application of aqueous Zn metal ***,a polyzwitterionic cross-linked double network hydrogel electrolyte composed of physical crosslinking(hyaluronic acid)and chemical crosslinking(synthetic zwitterionic monomer copolymerized with acrylamide)is introduced to overcome these *** the one hand,highly hydrophilic physical network provides an energy dissipation channel to buffer stress and builds a H_(2)O-poor interface to avoid side *** the other hand,the charged groups(sulfonic and imidazolyl)in chemical crosslinking structure build anion/cation transport channels to boost ions’kinetics migration and regulate the typical solvent structure[Zn(H_(2)O)_(6)]^(2+)to R-SO_(3)^(−)[Zn(H_(2)O)_(4)]^(2+),with uniform electric field distribution and significant resistance to dendrites and parasitic *** on the above functions,the symmetric zinc cell exhibits superior cycle stability for more than 420 h at a high current density of 5 mA·cm^(−2),and Zn||MnO_(2)full cell has a reversible specific capacity of 150 mAh·g^(−1)after 1000 cycles at 2 C with this hydrogel ***,the pouch cell delivers impressive flexibility and cyclability for energy-storage applications.

关键词： Zn anode dendrites parasitic reactions polyzwitterion double network hydrogel electrolyte

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Molecular Dynamics Simulation of Antipolyelectrolyte Effect and Solubility of polyzwitterions

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Chemical Research in Chinese Universities 2017年第2期33卷 261-267页

作者： YANG Shengchun ZHU Youliang QIAN Hujun LU Zhongyuan State Key Laboratory of Supramoleeular Structure and Materials Institute of Theoretical Chemistry Jilin University Changehun 130021 P R. China School of Information Engineering Northeast Electric Power University Jilin 132012 R R. China State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun 130022 P. R. China

In this work, by using coarse-grained molecular dynamics simulations, we found that poly（2-metha-cryloyloxyethyl phosphorylcholine）（PMPC） showed a strong solubility and a so-called antipolyelectrolyte effect（APE）in water. In contrast, obvious aggregations but no APE were found in n-butyl-substituted choline phosphatepolymers（PMBP） solutions. The underlying mechanisms for different solution behaviors of PMPC and PMBP wereinvestigated in detail. Our results indicate that the presence of butyl groups in PMBP enhances both the electrostaticinteractions and the hydrophobicity of PMBP molecules in the system. Both factors were found to contribute to theformations of aggregates in the PMBP system. Further researches revealed that hydrophobicity arising from the butylgroup plays a more important role than electrostatic interactions in inducing the PMBP aggregation. In addition, thestrong hydrophobicity in PMBP was found to be responsible for the absence of APE. These results are expected tocontribute to a better understanding and a better design of the solution properties of polyzwitterions.

关键词： polyzwitterion Antipolyelectrolyte Solubility Dissipative particle dynamics(DPD)

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The Anion Binding Affinity Determines the Strength of Anion Specificities of Thermosensitive Polymers

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Chinese Journal of Polymer Science 2021年第11期39卷 1351-1356页

作者： Lei-Lei Lian Si-Yuan Xu Hai-Yang Yuan Guang-Ming Liu Hefei National Laboratory for Physical Sciences at the Microscale Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education InstitutesDepartment of Chemical PhysicsUniversity of Science and Technology of ChinaHefei 230026China

In this work,we demonstrate that the strength of anion specificities of thermosensitive polymers is determined by the affinity of direct anion binding to the *** have prepared a series of thermosensitive statistical copolymers with distinct thermoresponsive *** anions can specifically interact with the different types of thermosensitive polymers in very different strengths.A similar strength of specific anion effects on thermoresponsive behaviors can be observed at very different salt concentrations for the different types of thermosensitive polymers.A stronger anion binding to the thermosensitive polymers gives rise to a more obvious anion specificity and vice *** work presented here opens up opportunities for the application of ion binding affinity to modulate the strength of ion specificities of thermosensitive polymers.

关键词： Specific ion effect polyzwitterion Ion-polymer interaction Thermosensitivity Ion-pairing

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