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Graphitized Cu-β-cyclodextrin polymer driving an efficient dual-reaction-center Fenton-like process by utilizing electrons of pollutants for water purification

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Journal of Environmental Sciences 2023年第4期126卷 565-574页

作者： Weixiang Liao Lai Lyu DiWang Chun Hu Tong Li Key Laboratory for Water Quality and Conservation of the Pearl River Delta Ministry of EducationInstitute of Environmental Research at Greater BayGuangzhou UniversityGuangzhou 510006China School of Energy and Environmental Engineering University of Science and Technology BeijingBeijing 100083China

Excessive consumption of energy and resources is a major challenge in wastewater treatment.Here,a novel heterogeneous Fenton-like catalyst consisting of Cu-doped graphenelike catalysts (Cu-GCD NSs) was first synthesized by an enhanced carbothermal reduction of β-cyclodextrin (β-CD).The catalyst exhibits excellent Fenton-like catalytic activity for the degradation of various pollutants under neutral conditions,accompanied by low H_(2)O_(2)consumption.The results of structural characterization and theoretical calculations confirmed that the dual reaction centers (DRCs) were constructed on Cu-GCD NSs surface through C-O-Cu bonds supported on zero-valent copper species,which play a significant role in the high-performance Fenton-like reaction.The pollutants that served as electron donors were decomposed in the electron-poor carbon centers,whereas H_(2)O_(2)and dissolved oxygen obtained these electrons in the electron-rich Cu centers through C-O-Cu bonds,thereby producing more active species.This study demonstrates that the electrons of pollutants can be efficiently utilized in Fenton-like reactions by DRCs on the catalyst surface,which provides an effective strategy to improve Fenton-like reactivity and reduce H_(2)O_(2)consumption.

关键词： Fenton-like Dual reaction centers Graphene-like carbon Nanoscale zero-valent copper pollutants degradation

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Uncovering mechanism of photocatalytic performance enhancement induced by multivariate defects on SnS_(2)

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Nano Research 2023年第2期16卷 2102-2110页

作者： Sheng-Qi Guo Bo Yang Zhenzhong Hu Mengmeng Zhen Bingchuan Gu Boxiong Shen Tianjin Key Laboratory of Clean Energy and Pollutant Control School of Energy and Environmental EngineeringHebei University of TechnologyTianjin 300401China Anhui Province Key Laboratory of Pollutant Sensitive Materials and Environmental Remediation Huaibei Normal UniversityHuaibei 235000China State Key Laboratory of Particle Detection and Electronics University of Science&Technology of ChinaHefei 230026China

Defect engineering is recognized as an effective route to obtain highly active photocatalytic materials.However,the current understanding of defects is mainly limited to isolated atomic vacancy defects,ignoring the exploration of the functions of multivariate defects formed by the deletion of several adjacent atoms in photocatalytic system.Here,we prepared SnS2 nanostructures with the same morphology but different dominant defects,and by testing their photocatalytic performance,it was found that the multivariate defects can significantly improve the photocatalytic performance than isolated S vacancies.Combining experiments and theoretical calculations,we confirmed that the promotion of multivariate defects,especially“S-Sn-S”vacancy associates,on the photocatalytic performance is reflected in many aspects,such as the regulation of the energy band structure,the improvement of the charge separation efficiency,and the promotion of the adsorption and activation of guest molecules.SnS2 with“S-Sn-S”vacancy associates exhibits excellent photocatalytic water purification ability.Under the induction of“S-Sn-S”vacancy associates,phenol was thoroughly photocatalytically decomposed,further confirming its excellent functionality.This work not only provides new insights into identifying advantage defects in the catalyst structure,but also offers new ideas for constructing highly active photocatalysts based on defect engineering.

关键词： SnS2 multivariate defects photocatalysis pollutants degradation reaction mechanism

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