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Rapid synthesis of highly active Pt/C catalysts with various metal loadings from single batch platinum colloid

Journal of Energy Chemistry 2020年第8期29卷 138-145,I0005页

作者： Yuxin Li Xiang Zhu Yawen Chen Shiqiao Zhang Jia Li Jianguo Liu Jiangsu Key Laboratory for Nano Technology National Laboratory of Solid State MicrostructuresCollege of Engineering and Applied Sciencesand Collaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing 210093JiangsuChina Kunshan Innovation Institute of Nanjing University Kunshan Sunlaite New Energy Co.Ltd.Suzhou 215347JiangsuChina

A series of Pt/C catalysts for proton exchange membrane fuel cells(PEMFCs) with various metal loadings is synthesized by a microwave-assisted polyol process via mixing an extremely stable platinum colloid(> 3 months’ shelf life) from single batch preparation with activated carbon ethylene glycol suspension.21 wt%, 42 wt% and 61 wt% Pt loadings are employed to showcase the advantages of the improved polyol process. The ultraviolet(UV)–visible spectra and ζ-potential measurements are conducted to monitor the wet chemistry process during catalyst preparation. The powder X-ray diffraction(XRD), transmission electron microscopy(TEM) and thermogravimetric analysis(TGA) characterizations are carried out on catalysts. The catalyst activities are investigated using electrochemical and single cell tests. The stability of Pt nanoparticle colloid is explored by ORR, cyclic voltammetry(CV) and ζ-potential measurements. The TEM results show the Pt particle sizes of the colloid, and the sizes of the 21 wt%, 42 wt% and 61 wt%Pt/C samples are 2.1–3.9 nm. Because of the high Pt dispersion, the Pt/C catalysts exhibit superior electroactivity toward ORR. In addition, four 61 wt% Pt/C catalysts made from the Pt colloid with 0–3 months’ shelf life show almost the same performance, which exhibits superior stability of the Pt colloid system without surfactant protection.

关键词： PEMFC Pt/C catalyst Microwave irradiation Modified polyol process platinum nanocolloid Oxygen reduction reaction

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